Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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Towards New Metal Alkoxides and Alkylperoxides: Contrasting Oxygenation vs Protonolysis Reactions of the Respective Organometallics.

2017/27/B/ST5/02329

Keywords:

dioxygen metal alkyls mechanism alkylperoxides alkoxides radical reactions magnesium zinc aluminum catalysis

Descriptors:

  • ST5_14: Other related subjects
  • ST5_24:
  • ST5_20:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Politechnika Warszawska, Wydział Chemiczny

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Janusz Lewiński 

Number of co-investigators in the project: 5

Call: OPUS 14 - announced on 2017-09-15

Amount awarded: 1 158 600 PLN

Project start date (Y-m-d): 2018-06-08

Project end date (Y-m-d): 2020-10-07

Project duration:: 28 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Komputer (5 000 PLN)
  2. Kompaktowy Spektrometr Mas z przystawką do badania próbek wrażliwych na powietrze. (420 000 PLN)
  3. Laboratoryjna chłodziarko-zamrażarka.

Information in the final report

  • Publication in academic press/journals (6)
  1. Reaching Milestones in the Oxygenation Chemistry of Magnesium Alkyls: towards Intimate States of O2 Activation and the First Monomeric Well‐Defined Magnesium Alkylperoxide
    Authors:
    Tomasz Pietrzak Dr. Iwona Justyniak, Jiwon Victoria Park, Michał Terlecki, Łukasz Kapuśniak, Janusz Lewiński
    Academic press:
    Chemistry – A European Journal (rok: 2019, tom: 25, strony: 2503 – 2510), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201805180 - link to the publication
  2. Unveiling Complexity of the Oxygenation of Aluminum Alkyls by the Isolation of Unique Alkylperoxide and Oxoalkoxide Compounds
    Authors:
    A. Rola-Noworyta, T. Pietrzak, V. Szejko, I. Justyniak, J. Lewiński
    Academic press:
    Inorganic Chemistry (rok: 2020, tom: 59, strony: 13807−13811), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c01962 - link to the publication
  3. Effectiveness of oxygenation over classical protonolysis reactions involving alkylzinc complexes incorporating aminoalcoholates
    Authors:
    Karolina Zelga, Tomasz Pietrzak, Tomasz Han, Iwona Justyniak, Elżbieta Chwojnowska, Piotr Sobota, Janusz Lewiński
    Academic press:
    Chemical Communications (rok: 2021, tom: -, strony: -), Wydawca: Royal Society of Chemistry
    Status:
    Submitted
    DOI:
    brak - link to the publication
  4. An In‐Depth Look at the Reactivity of Non‐Redox‐Metal Alkylperoxides
    Authors:
    Tomasz Pietrzak, Iwona Justyniak, Marcin Kubisiak, Emil Bojarski, Janusz Lewiński
    Academic press:
    Angewandte Chemie International Edition (rok: 2019, tom: 58, strony: 8526-8530), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/anie.201904380 - link to the publication
  5. Unravelling structural mysteries of simple organozinc alkoxides
    Authors:
    Ł. Mąkolski, V. Szejko, K. Zelga, A. Tulewicz, P. Bernatowicz, I. Justyniak, J. Lewiński
    Academic press:
    Chemistry – A European Journal (rok: 2020, tom: -, strony: -), Wydawca: Wiley-VCH
    Status:
    Accepted for publication
    DOI:
    10.1002/chem.202004222 - link to the publication
  6. An unexpected ligand redistribution of a dimeric magnesium alkylperoxide to an unique spiro-type, tetranuclear alkylperoxide
    Authors:
    Tomasz Pietrzak, Iwona Justyniak, Karolina Zelga, Zbigniew Ochal, Krzysztof Nowak, Janusz Lewiński
    Academic press:
    Inorganic Chemistry (rok: 2021, tom: -, strony: -), Wydawca: ACS Publications
    Status:
    Submitted
    DOI:
    brak - link to the publication

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