Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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New variants and applications of nucleophilic substitution of hydrogen in electrophilic arenes

2014/15/B/ST5/02180

Keywords:

nitroarenes nucleophiles enamines carbanions nucleophilic substitution

Descriptors:

  • ST5_23:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Instytut Chemii Organicznej PAN

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Mieczysław Mąkosza 

Number of co-investigators in the project: 6

Call: OPUS 8 - announced on 2014-09-15

Amount awarded: 694 600 PLN

Project start date (Y-m-d): 2015-08-03

Project end date (Y-m-d): 2019-01-02

Project duration:: 41 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. Chłodnica imersyjna (35 000 PLN)

Information in the final report

  • Publication in academic press/journals (7)
  1. Transition Metal Free Nucleophilic Benzylation of Nitroarenes. Umpolung of the Friedel Crafts Reaction
    Authors:
    Kacper Kisiel, Jakub Brześkiewicz, Rafał Loska, Mieczysław Mąkosza
    Academic press:
    Advanced Synthesis & Catalysis (rok: 2019, tom: 361, strony: 1641-1646), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/adsc.201801715 - link to the publication
  2. Direct synthesis of nitroaryl acetylenes from acetylenes and nitroarenes via oxidative nucleophilic substitution of hydrogen
    Authors:
    Bujok, Robert; Mąkosza, Mieczysław
    Academic press:
    Chemical Communications (rok: 2016, tom: 52, strony: 12650-12652), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C6CC07475H - link to the publication
  3. Simple Synthesis of Aryl p-Nitroarylacetonitriles by Vicarious Nucleophilic Substitution with Carbanions of Protected Cyanohydrins
    Authors:
    Nazar Rad, Mieczysław Mąkosza
    Academic press:
    European Journal of Organic Chemistry (rok: 2018, tom: 2018, strony: 376-380), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejoc.201701507. - link to the publication
  4. Synthesis of a-Fluoro-a-nitroarylacetates via Vicarious Nucleophilic Substitution of Hydrogen
    Authors:
    Czaban-Jóźwiak, Justyna; Loska, Rafał; Mąkosza, Mieczysław
    Academic press:
    Journal of Organic Chemistry (rok: 2016, tom: 81, strony: 11751-11757), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.joc.6b02219 - link to the publication
  5. How Does Nucleophilic Aromatic Substitution in Nitroarenes Really Proceed: General Mechanism
    Authors:
    Mieczysław Mąkosza
    Academic press:
    Synthesis (rok: 2017, tom: 49, strony: 3247-3254), Wydawca: Thieme
    Status:
    Published
    DOI:
    10.1055/s-0036-1588444 - link to the publication
  6. NUCLEOPHILIC SUBSTITUTION IN NITROARENES. GENERAL MECHANISM
    Authors:
    M. Mąkosza
    Academic press:
    Chemical Journal of Armenia (rok: 2018, tom: 71, strony: 90-106), Wydawca: NATIONAL ACADEMY OF SCIENCES OF THE REPUBLIC OF ARMENIA
    Status:
    Published
    DOI:
    brak - link to the publication
  7. alpha-Chlorobenzylation of Nitroarenes via Vicarious Nucleophilic Substitution with Benzylidene Dichloride: Umpolung of the Friedel-Crafts Reaction
    Authors:
    J. Brześkiewicz, R. Loska, M. Mąkosza
    Academic press:
    Journal of Organic Chemistry (rok: 2018, tom: 83, strony: 8499-8508), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.joc.8b01091 - link to the publication

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