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Stabilization of metallacyclopentadiene in the porphyrinoid environment – access to atypical metal-metal interactions

2020/37/B/ST4/00869

Keywords:

metallacyclopentadiene porphyrin aromaticity

Descriptors:

  • ST4_11: Coordination and supramolecular chemistry

Panel:

ST4 - Chemistry: physical chemistry/chemical physics, theoretical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, method development

Host institution :

Uniwersytet Wrocławski, Wydział Chemii

woj.

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Ewa Dudziak 

Number of co-investigators in the project: 8

Call: OPUS 19 - announced on 2020-03-16

Amount awarded: 978 720 PLN

Project start date (Y-m-d): 2021-02-01

Project end date (Y-m-d): 2025-01-31

Project duration:: 48 months (the same as in the proposal)

Project status: Project completed

Project description

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Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Information in the final report

  • Publication in academic press/journals (5)
  1. Two Rhodium(III) Ions Confined in a [18]Porphyrin Frame: 5,10,15,20-Tetraaryl-21,23-Dirhodaporphyrin
    Authors:
    Grzegorz Vetter, Agata Białońska, Paulina Krzyszowska, Sebastian Koniarz, Ewa Pacholska-Dudziak
    Academic press:
    Chemistry - A European Journal (rok: 2022, tom: 28, strony: e202201513(1-9)), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.202201513 - link to the publication
  2. Metalation of Tellurophene: Reactivity of 21,23-Ditelluraporphodimethene toward Palladium(II), Platinum(II), and Rhodium(I)
    Authors:
    Grzegorz Vetter, Agata Białońska, Ewa Pacholska-Dudziak
    Academic press:
    Inorganic Chemistry (rok: 2023, tom: 62, strony: 3056–3066), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.2c03777 - link to the publication
  3. Two Rhodium(III) Ions Confined in a [18]Porphyrin Frame: 5,10,15,20-Tetraaryl-21,23-Dirhodaporphyrin
    Authors:
    Grzegorz Vetter, Agata Białońska, Paulina Krzyszowska, Sebastian Koniarz, Ewa Pacholska-Dudziak
    Academic press:
    Chemistry - A European Journal (rok: 2022, tom: 28, strony: e202201513(1-9)), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.202201513 - link to the publication
  4. Heterobimetallic 21,23-dimetallaporphyrin: activation of metal–metal interactions within the porphyrinoid macrocycle
    Authors:
    Grzegorz Vetter, Agata Białońska, Aneta Jezierska, Jarosław J. Panek, Ewa Pacholska-Dudziak
    Academic press:
    Chemical Communications (rok: 2023, tom: 59, strony: 6841-6844), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D3CC01367G - link to the publication
  5. Metalation of Tellurophene: Reactivity of 21,23-Ditelluraporphodimethene toward Palladium(II), Platinum(II), and Rhodium(I)
    Authors:
    Grzegorz Vetter, Agata Białońska, Ewa Pacholska-Dudziak
    Academic press:
    Inorganic Chemistry (rok: 2023, tom: 62, strony: 3056–3066), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.2c03777 - link to the publication

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