Projects funded by the NCN


Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

Delete all

Making the Impossible Possible: Macrocyclisation of UnbiasedDienes at High Concentration by Ring-Closing Metathesis

2019/33/B/ST4/00874

Keywords:

macrocyclisation macrocyclic compounds olefin metathesis ruthenium catalysts unsymmetrical N-heterocyclic carbenes (uNHC) stereoisomers depolymerisation

Descriptors:

  • ST4_14: Catalysis
  • ST4_8: Organic chemistry

Panel:

ST4 - Chemistry: physical chemistry/chemical physics, theoretical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, method development

Host institution :

Uniwersytet Warszawski, Centrum Nauk Biologiczno-Chemicznych

woj.

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Karol Lesław Grela 

Number of co-investigators in the project: 9

Call: OPUS 17 - announced on 2019-03-15

Amount awarded: 1 896 500 PLN

Project start date (Y-m-d): 2020-02-27

Project end date (Y-m-d): 2023-10-26

Project duration:: 44 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Information in the final report

  • Publication in academic press/journals (7)
  1. Preserving Precise Choreography of Bonds in Stereoretentive Olefin Metathesis: New Type of Ligand Allows High Z-Selectivity Even at High Temperature
    Authors:
    Łukasz Grzesiński, Mariana Nadirova, Jannick Guschlbauer, Artur Brotons Rufes, Albert Poater Teixidor, Anna Kajetanowicz, Karol Grela
    Academic press:
    Nature Communications (rok: 2024, tom: 15, strony: 8981), Wydawca: Springer Nature Group
    Status:
    Published
    DOI:
    10.1038/S41467-024-52876-4 - link to the publication
  2. Ruthenium Olefin Metathesis Catalysts Bearing Two Bulky and Unsymmetrical NHC Ligands
    Authors:
    Adrian Sytniczuk, Paweł Małecki, Anna Kajetanowicz, Karol Grela
    Academic press:
    Applied Organometallic Chemistry (rok: 2024, tom: 38, strony: e6780), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/aoc.6780 - link to the publication
  3. Unexpected Latency of Z-Stereoretentive Ruthenium Olefin Metathesis Catalysts Bearing Unsymmetrical N-heterocyclic Carbene or Cyclic(alkyl)(amino)carbene Ligands
    Authors:
    Łukasz Grzesiński, Mariusz Milewski, Maryana Nadirova, Anna Kajetanowicz, Karol Grela
    Academic press:
    Organometallics (rok: 2022, tom: 42, strony: 2453–2459), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.organomet.2c00428 - link to the publication
  4. Schrock molybdenum alkylidene catalyst enables selective formation of macrocyclic unsaturated lactones by ring-closing metathesis at high-concentration
    Authors:
    Adrian Sytniczuk, Mariusz Milewski, Michał Dąbrowski, Karol Grela, Anna Kajetanowicz
    Academic press:
    Green Chemistry (rok: 2023, tom: 25, strony: 2299–2304), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D2GC02988J - link to the publication
  5. Schrock molybdenum alkylidene catalyst enables selective formation of macrocyclic unsaturated lactones by ring-closing metathesis at high-concentration
    Authors:
    Adrian Sytniczuk, Mariusz Milewski, Michał Dąbrowski, Karol Grela, Anna Kajetanowicz
    Academic press:
    Green Chemistry (rok: 2023, tom: n/a, strony: n/a-n/a), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D2GC02988J - link to the publication
  6. Ruthenium Olefin Metathesis Catalysts Bearing Two Bulky and Unsymmetrical NHC Ligands
    Authors:
    Adrian Sytniczuk, Paweł Małecki, Anna Kajetanowicz, Karol Grela
    Academic press:
    Applied Organometallic Chemistry (rok: 2022, tom: n/a, strony: n/a-n/a), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/aoc.6780 - link to the publication
  7. On the Unexpected Latency of Z-Stereoretentive Ruthenium Olefin Metathesis Catalysts Bearing Unsymmetrical N-Heterocyclic Carbene or Cyclic(Alkyl)(Amino)Carbene Ligands
    Authors:
    Łukasz Grzesiński, Mariusz Milewski, Maryana Nadirova, Anna Kajetanowicz, Karol Grela
    Academic press:
    Organometallics (rok: 2022, tom: n/a, strony: n/a-n/a), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.organomet.2c00428 - link to the publication