Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Synthesis and physicochemical properties of novel functional metal-organic compounds based on hypophosphite ligands

2018/31/B/ST5/00455

Keywords:

metal-organic frameworks ferroics phase transitions vibrational spectroscopy X-ray diffraction

Descriptors:

  • ST5_8: Metals, alloys
  • ST4_3: Molecular architecture and structure
  • ST3_18:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Instytut Niskich Temperatur i Badań Strukturalnych im. Włodzimierza Trzebiatowskiego Polskiej Akademii Nauk

woj. dolnośląskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Mirosław Mączka 

Number of co-investigators in the project: 6

Call: OPUS 16 - announced on 2018-09-14

Amount awarded: 860 000 PLN

Project start date (Y-m-d): 2019-06-13

Project end date (Y-m-d): 2022-12-12

Project duration:: 42 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Analizator elementarny CHN/O FlashSmart (260 000 PLN)
  2. Optyczne DSC450 (105 000 PLN)
  3. Wertykalna przystawka temperaturowa FTIRSP600 (42 000 PLN)
  4. Dygestorium (17 800 PLN)
  5. Kompresor tłokowy bezolejowy ES480/100 (11000 szt.) (11 000 PLN)
  6. dygestorium (14 139 PLN)
  7. komputer dell (1 300 PLN)

Information in the final report

  • Publication in academic press/journals (10)
  1. Evidence of Pressure-Induced Phase Transitions and Negative Linear Compressibility in Formamidinium Manganese-Hypophosphite Hybrid Perovskite
    Authors:
    Mirosław Ma̧czka, Mikołaj Kryś, Szymon Sobczak, Daniel Linhares Militão Vasconcelos, Paulo Tarso Cavalcante Freire, Andrzej Katrusiak
    Academic press:
    Journal of Physical Chemistry C (rok: 2021, tom: 125, strony: 26958-26966), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpcc.1c08387 - link to the publication
  2. Mechanism of Pressure-Induced Phase Transitions and Structure− Property Relations in Methylhydrazinium Manganese Hypophosphite Perovskites
    Authors:
    Mirosław Mączka, Szymon Sobczak, Mikołaj Kryś, Fabio Furtado Leite, Waldeci Paraguassu, Andrzej Katrusiak
    Academic press:
    Journal of Physical Chemistry C (rok: 2021, tom: 125, strony: 10121-10129), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpcc.1c01998 - link to the publication
  3. Cadmium and manganese hypophosphite perovskites templated by formamidinium cations: dielectric, optical and magnetic properties
    Authors:
    Mirosław Mączka, Dagmara Stefańska, Maciej Ptak, Anna Gągor, Adam Piku, Adam Sieradzki
    Academic press:
    Dalton Transactions (rok: 2021, tom: 50, strony: 2639-2647), Wydawca: Royal Chemical Society
    Status:
    Published
    DOI:
    10.1039/d0dt03995k - link to the publication
  4. The cation-dependent structural, magnetic and optical properties of a family of hypophosphite hybrid perovskites
    Authors:
    Mirosław Mączka, Dagmara Stefańska, Anna Gągor, Adam Pikul
    Academic press:
    Dalton Transactions (rok: 2022, tom: 51, strony: 352-360), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d1dt03382d - link to the publication
  5. Raman study of pressure-induced phase transitions in imidazolium manganesehypophosphite hybrid perovskite
    Authors:
    M. Mączkaa,, D. L. M. Vasconcelos, P. T. C. Freire
    Academic press:
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY , Wydawca: Elsevier
    Status:
    Submitted
    DOI:
    brak - link to the publication
  6. Phonon properties and mechanism of order-disorder phase transition in formamidinium manganese hypophosphite single crystal
    Authors:
    Maciej Ptak, Mirosław Mączka
    Academic press:
    Spectrochimica Acta A (rok: 2020, tom: 230, strony: 118010), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.saa.2019.118010 - link to the publication
  7. Effect of Organic Cation on Optical Properties of [A]Mn(H2POO)3 Hybrid Perovskites
    Authors:
    Dagmara Stefańska
    Academic press:
    Molecules (rok: 2022, tom: 27, strony: 8953), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules27248953 - link to the publication
  8. Novel hypophosphite hybrid perovskites of [CH3NH2NH2][Mn(H2POO)3] and [CH3NH2NH2] [Mn(H2POO)2.83(HCOO)0.17] exhibiting antiferromagnetic order and red photoluminescence
    Authors:
    Mirosław Mączka, Anna Gągor, Adam Pikul, Dagmara Stefańska
    Academic press:
    RSC Advances (rok: 2020, tom: 10, strony: 19020-19026), Wydawca: Royal Chemical Society
    Status:
    Published
    DOI:
    10.1039/d0ra03397a - link to the publication
  9. Structural, magnetic and photoluminescence properties of new hybrid hypophosphites: discovery of the first noncentrosymmetric and two cobalt-based members
    Authors:
    Mirosław Mączka, Anna Gągor, Dagmara Stefańska, Jan K. Zaręba, Adam Pikul
    Academic press:
    Dalton Transactions (rok: 2022, tom: 51, strony: 9094-9102), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d2dt01212j - link to the publication
  10. Vibrational Properties and DFT Calculations of Perovskite-Type Methylhydrazinium Manganese Hypophosphite
    Authors:
    Aneta Ciupa-Litwa, Maciej Ptak, Edyta Kucharska, Jerzy Hanuza, Mirosław Mączka
    Academic press:
    Molecules (rok: 2020, tom: 25, strony: 5215), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules25215215 - link to the publication

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