Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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Synthesis of ruthenium complexes bearing CAAC ligands and their use in metathesis reactions

2017/27/B/ST5/02563

Keywords:

olefin metathesis ethenolysis CAAC ligands ruthenium complexes

Descriptors:

  • ST5_18:
  • ST5_23:
  • ST5_24:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Warszawski, Centrum Nauk Biologiczno-Chemicznych

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Anna Kajetanowicz 

Number of co-investigators in the project: 3

Call: OPUS 14 - announced on 2017-09-15

Amount awarded: 746 600 PLN

Project start date (Y-m-d): 2018-07-31

Project end date (Y-m-d): 2022-02-27

Project duration:: 43 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. monitor Dell.
  2. Pompa próżniowa rotacyjna łopatkowa z miernikiem próżni (20 000 PLN)
  3. komputer stacjonarny Dell.

Information in the final report

  • Publication in academic press/journals (4)
  1. A tunable family of CAAC-ruthenium olefin metathesis catalysts modularly derived from a large-scale produced ibuprofen intermediate
    Authors:
    Adrian Sytniczuk, Filip Struzik, Karol Grela, Anna Kajetanowicz
    Academic press:
    Chemical Science (rok: 2023, tom: 14, strony: 10744-10755), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d3sc03849a - link to the publication
  2. Inverted" cyclic(alkyl)(amino)carbene ligands allow olefin metathesis with ethylene at parts-per-billion catalyst loading
    Authors:
    Adrian Sytniczuk, Anna Kajetanowicz, Karol Grela
    Academic press:
    Chem Catalysis (rok: 2023, tom: 3, strony: 100713), Wydawca: Cell Press
    Status:
    Published
    DOI:
    10.1016/j.checat.2023.100713 - link to the publication
  3. Aza-Claisen rearrangement as a key step in synthesis of specialised anilines used in the production of efficient ethenolysis catalysts
    Authors:
    Adrian Sytniczuk, Filip Struzik, Vishal Purohit, Karol Grela, Anna Kajetanowicz
    Academic press:
    Catalysis Science&Technology (rok: 2023, tom: 13, strony: 3682-3688), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d3cy00395g - link to the publication
  4. Non‐Glovebox Ethenolysis of Ethyl Oleate and FAME at Larger Scale Utilizing a Cyclic (Alkyl)(Amino)Carbene Ruthenium Catalyst
    Authors:
    Kajetanowicz, A.; Chwalba, M.; Gawin, A.; Tracz, A.; Grela, K.
    Academic press:
    European Journal of Lipid Science and Technology (rok: 2020, tom: 122 (1), strony: 1900263), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejlt.201900263 - link to the publication

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