Projects funded by the NCN


Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Heterometallic alkoxides and aryloxides as precursors of catalytic systems for the synthesis of organic molecules of special applications.

2017/26/D/ST5/01123

Keywords:

heterometallic complexes alkoxy metal compounds organometallic compounds

Descriptors:

  • ST5_14: Other related subjects
  • ST5_24:
  • ST5_18:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Politechnika Wrocławska

woj. dolnośląskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Rafał Petrus 

Number of co-investigators in the project: 6

Call: SONATA 13 - announced on 2017-06-14

Amount awarded: 750 200 PLN

Project start date (Y-m-d): 2018-04-09

Project end date (Y-m-d): 2022-04-08

Project duration:: 48 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. polarymetr automatyczny.
  2. płaszcz grzewczy z mieszadłem magnetycznym (629 PLN)
  3. dwustopniowa olejowa pompa próżniowa.
  4. piec laboratoryjny.
  5. reaktor ciśnieniowy ze szklanym naczyniem reakcyjnym (14 000 PLN)
  6. czasze grzejne.
  7. mieszadło magnetyczne z ceramiczną płytą grzejną i zewnętrznym kontrolerem temperatury (4 szt.) (31 200 PLN)
  8. ognioodporna szafa bezpieczeństwa na odczynniki (16 000 PLN)
  9. urządzenie wielofunkcyjne (skaner, drukarka, ksero).
  10. mini reaktor wysokociśnieniowy (25 000 PLN)
  11. rotacyjna pompa olejowa (12 000 PLN)
  12. zbiornik Dewara do przechowywania ciekłego azotu (8 000 PLN)

Information in the final report

  • Publication in academic press/journals (10)
  1. Solvothermal Alcoholysis Method for Recycling High-Consistency Silicone Rubber Waste
    Authors:
    Rafał Petrus, Józef Utko, Radosław Gniłka, Mariusz G. Fleszar, Tadeusz Lis, Piotr Sobota
    Academic press:
    Macromolecules (rok: 2021, tom: 54, strony: 2449–2465), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.macromol.0c02773 - link to the publication
  2. Use of heterometallic alkali metal-magnesium aryloxides in ring-opening polymerization of cyclic esters
    Authors:
    Rafał Petrus, Tadeusz Lis, Adrian Kowaliński
    Academic press:
    Dalton Transactions (rok: 2022, tom: 51, strony: 9144 - 9158), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/D2DT00731B - link to the publication
  3. Magnesium and zinc alkoxides and aryloxides supported by commercially available ligands as promoters of chemical transformations of lactic acid derivatives to industrially important fine chemicals.
    Authors:
    Rafał Petrus, Piotr Sobota
    Academic press:
    Coordination Chemistry Reviews (rok: 2019, tom: 396, strony: 72-88), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.ccr.2019.06.002 - link to the publication
  4. A new, simple, and efficient strategy for the preparation of active antifungal biodegradable materials via ring-opening polymerization of L-lactide with zinc aryloxides
    Authors:
    Rafał Petrus, Piotr Sobota
    Academic press:
    Dalton Transactions (rok: 2019, tom: 48, strony: 8193-8208), Wydawca: Royal Society of Chemistry.
    Status:
    Published
    DOI:
    10.1039/C9DT00627C - link to the publication
  5. Heterometallic group 4–lanthanide oxo-alkoxide precursors for synthesis of binary oxide nanomaterials.
    Authors:
    Rafał Petrus, Katarzyna Chomiak, Józef Utko, Alina Bieńko, Tadeusz Lis, Piotr Sobota
    Academic press:
    Inorganic Chemistry (rok: 2020, tom: 59, strony: 16545-16556), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c02478 - link to the publication
  6. Convenient route to heterometallic group 4-zinc precursors for binary oxide nanomaterials
    Authors:
    Rafał Petrus, Katarzyna E. Chomiak, Józef Utko, Magdalena M. Wilk-Kozubek, Tadeusz LiS, Joanna Cybińska, Piotr Sobota
    Academic press:
    Inorganic Chemistry (rok: 2020, tom: 59, strony: 8108-8120), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c00399 - link to the publication
  7. Structural analysis and catalytic activity of tetranuclear metal carboxylate clusters with [KZn3(μ3-OH)(OOCCPh3)6] or [Zn4(μ4-O)(OOCCPh3)6] central motif.
    Authors:
    Rafał Petrus, Józef Utko, Piotr Sobota
    Academic press:
    New Journal of Chemistry (rok: 2020, tom: 2020, strony: 13771-13780.), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/D0NJ02540B - link to the publication
  8. Struktura i reaktywność związków alkoksy-cynkowych jako inicjatorów/katalizatorów polimeryzacji estrów cyklicznych
    Authors:
    Rafał Petrus, Józef Utko, Piotr Sobota
    Academic press:
    Wiadomości Chemiczne (rok: 2021, tom: 75, 3-4, strony: 343-373), Wydawca: PTCHEM
    Status:
    Published
  9. Use of group 13 aryloxides for the synthesis of green chemicals and oxide materials
    Authors:
    Rafał Petrus, Józef Utko, Joanna Petrus, Mohammad Awashra, Tadeusz Lis
    Academic press:
    Dalton Transactions (rok: 2022, tom: 51, strony: 4135-4152), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/D1DT03777C - link to the publication
  10. Use of lithium aryloxides as promoters for preparation of α-hydroxy acid esters
    Authors:
    Rafał Petrus, Patryk Fałat, Piotr Sobota
    Academic press:
    Dalton Transactions (rok: 2020, tom: 49, strony: 866-876), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C9DT03631H - link to the publication