Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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Phase transition mechanisms and physicochemical properties of selected perovskite-type metal-organic frameworks

2017/25/B/ST5/00160

Keywords:

metal-organic frameworks ferroics phase transitions IR and Raman spectroscopy

Descriptors:

  • ST5_8: Metals, alloys
  • ST4_3: Molecular architecture and structure
  • ST3_18:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Instytut Niskich Temperatur i Badań Strukturalnych im. Włodzimierza Trzebiatowskiego Polskiej Akademii Nauk

woj. dolnośląskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Mirosław Mączka 

Number of co-investigators in the project: 9

Call: OPUS 13 - announced on 2017-03-15

Amount awarded: 973 600 PLN

Project start date (Y-m-d): 2018-02-09

Project end date (Y-m-d): 2021-02-08

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. mieszadło magnetyczne (4 649 PLN)
  2. mineralizator mikrofalowy ERTEC, Magnum II (35 000 PLN)
  3. stół optyczny (21 601 PLN)
  4. spektrometr terahercowy Toptica TeraFlash (490 000 PLN)
  5. inkubator (5 649 PLN)
  6. mikroskop polaryzacyjny, Primotech (Carl Zeiss) (58 000 PLN)

Information in the final report

  • Publication in academic press/journals (15)
  1. Phase transition in the extreme: a cubic-to-triclinic symmetry change in dielectrically switchable cyanide perovskites
    Authors:
    Monika Trzebiatowska, Anna Gągor, Lucyna Macalik, Paulina Peksa and Adam Sieradzki
    Academic press:
    Dalton Transactions (rok: 2019, tom: 48, strony: 15830-15840), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c9dt03250a - link to the publication
  2. Temperature-dependent studies of a new two-dimensional cadmium dicyanamide framework exhibiting an unusual temperature-induced irreversible phase transition into a three-dimensional perovskite-like framework
    Authors:
    Mirosław Mączka, Anna Gągor, Maciej Ptak, Dagmara Stefańska, Adam Sieradzki
    Academic press:
    Physical Chemistry Chemical Physics (rok: 2018, tom: 20, strony: 29951-29958), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c8cp06190d - link to the publication
  3. Comparative studies of vibrational properties and phase transitions in perovskite‐like frameworks of [(C3H7)4N] [M(N(CN)2)3] with M=Mn, Co, Ni
    Authors:
    Aneta Ciupa‐Litwa, Maciej Ptak, Jerzy Hanuza, Edyta Kucharska, Krzysztof Beć
    Academic press:
    Journal of Raman Spectroscopy (rok: 2019, tom: 50, strony: 1561-1571), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/jrs.5627 - link to the publication
  4. Temperature- and pressure-dependent studies of a highly flexible and compressible perovskite-like cadmium dicyanamide framework templated with protonated tetrapropylamine
    Authors:
    Mirosław Mączka, Maciej Ptak, Anna Gągor, Adam Sieradzki, Paulina Peksa, Gediminas Usevicius, Mantas Simenas, Fabio Furtado Leite, Waldeci Paraguassu
    Academic press:
    Journal of Materials Chemistry C (rok: 2019, tom: 7, strony: 2408-2420), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c8tc06401f - link to the publication
  5. Pyrrolidinium-Based Cyanides: Unusual Architecture and Dielectric Switchability Triggered by Order−Disorder Process
    Authors:
    Monika Trzebiatowska,Mirosław Mączka, Anna Gagor, Adam Sieradzki
    Academic press:
    Inorganic Chemistry (rok: 2020, tom: 59, strony: 8855-8863), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c00637 - link to the publication
  6. Spectroscopic Study of Structural Phase Transition and Dynamic Effects in a [(CH3)2NH2][Cd(N3)3] Hybrid Perovskite Framework
    Authors:
    Monika Trzebiatowska, Mirosław Mączka, Maciej Ptak, Laisvydas Giriunas, Sergejus Balciunas, Mantas Simenas, Daniel Klose and Juras Banys
    Academic press:
    Journal of Physical Chemistry C (rok: 2019, tom: 123, strony: 11840-11849), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpcc.9b01121 - link to the publication
  7. Structural, phonon, magnetic and optical properties of novel perovskite-like frameworks of TriBuMe[M(dca)3] (TriBuMe = tributylmethylammonium; dca = dicyanamide; M = Mn2+, Fe2+, Co2+, Ni2+)
    Authors:
    Mirosław Mączka, Anna Gągor, Maciej Ptak, Dagmara Stefańska, Lucyna Macalik, Adam Pikul and Adam Sieradzki
    Academic press:
    Dalton Transactions (rok: 2019, tom: 48, strony: 13006-13016), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c9dt02924a - link to the publication
  8. THz, Raman, IR and DFT studies of noncentrosymmetric metal dicyanamide frameworks comprising benzyltrimethylammonium cations
    Authors:
    M. Mączka, M. Ptak, M. Trzebiatowska, E. Kucharska, J. Hanuza, N. Pałka, E. Czerwińska
    Academic press:
    Spectrochimica Acta A (rok: 2021, tom: 251, strony: 119416), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.saa.2020.119416 - link to the publication
  9. The mechanism of phase transitions and luminescence properties of azide perovskites
    Authors:
    M.Trzebiatowska, K. Hermanowicz
    Academic press:
    Spectrochimica Acta A (rok: 2021, tom: 255, strony: 119716), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.saa.2021.119716 - link to the publication
  10. Raman and single-crystal X-ray diffraction evidence of pressure-induced phase transitions in a perovskite-like framework of [(C3H7)4N] [Mn(N(CN)2)3]
    Authors:
    Mirosław Mączka, Ines E. Collings, Fabio Furtado Leite and Waldeci Paraguassu
    Academic press:
    Dalton Transactions (rok: 2019, tom: 48, strony: 9072-9078), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c9dt01648a - link to the publication
  11. The mechanism of phase transitions in azide perovskites probed by vibrational spectroscopy
    Authors:
    M. Trzebiatowska, M. Ptak
    Academic press:
    Spectrochimica Acta A (rok: 2019, tom: 214, strony: 184-191), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.saa.2019.02.027 - link to the publication
  12. The spectroscopic study of phase transitions in the series of cyanide perovskites
    Authors:
    Monika Trzebiatowska
    Academic press:
    Spectrochimica Acta a (rok: 2021, tom: 245, strony: 118957), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.saa.2020.118957 - link to the publication
  13. Two-dimensional metal dicyanamide frameworks of BeTriMe[M(dca)3(H2O)] (BeTriMe = benzyltrimethylammonium; dca = dicyanamide; M = Mn2+, Co2+, Ni2+): coexistence of polar and magnetic orders and nonlinear optical threshold temperature sensing
    Authors:
    Mirosław Mączka, Anna Gągor, Alessandro Stroppa, Joao Nuno Gonçalves, Jan K. Zaręba, Dagmara Stefańska, Adam Pikul, Marek Drozd, Adam Sieradzki
    Academic press:
    Journal of Materials Chemistry C (rok: 2020, tom: 8, strony: 11735-11747), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d0tc02794d - link to the publication
  14. Cyano-bridged perovskite [(CH3)3NOH]2[KM(CN)6], [M: Fe(III), and Co(III)] for high-temperature multi-axial ferroelectric applications with enhanced thermal and nonlinear optical performance
    Authors:
    Magdalena Rok, Agnieszka Ciżman, Bartosz Zarychta, Jan K. Zaręba, Monika Trzebiatowska, Mirosław Mączka, Alessandro Stroppa, Shurong Yuan, Anthony E. Phillips. Grażyna Bator
    Academic press:
    Journal of Materials Chemistry C (rok: 2020, tom: 8, strony: 17491-17501), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d0tc04527f - link to the publication
  15. Temperature-dependent luminescence and second-harmonic generation of perovskite-type manganese and cadmium dicyanamide frameworks templated by tetrapropylammonium cations
    Authors:
    Mirosław Mączka, Dagmara Stefańska, Jan K. Zaręba, Marcin Nyk, Adam Sieradzki
    Academic press:
    Journal of Alloys and Compounds (rok: 2020, tom: 821, strony: 153464), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jallcom.2019.153464 - link to the publication

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