Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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New catalytic systems for selective alkynes semi-hydrogenation.

2017/25/B/ST5/01274

Keywords:

transfer hydrogenation triple C-C bond alkynes

Descriptors:

  • ST5_18:
  • ST5_23:
  • ST5_24:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Instytut Chemii Organicznej Polskiej Akademii Nauk

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Karol Grela 

Number of co-investigators in the project: 7

Call: OPUS 13 - announced on 2017-03-15

Amount awarded: 1 113 000 PLN

Project start date (Y-m-d): 2018-01-30

Project end date (Y-m-d): 2022-01-29

Project duration:: 48 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Zestaw do syntezy równoległej 'karuzela' (50 000 PLN)
  2. Łaźnia ultradźwiękowa (5 000 PLN)
  3. Lampa rtęciowa z oprzyrządowaniem (8 000 PLN)

Information in the final report

  • Publication in academic press/journals (4)
  1. Ligand-Free (Z)-Selective Transfer Semihydrogenation of Alkynes Catalyzed by in Situ Generat-ed Oxidizable Copper Nanoparticles
    Authors:
    Rafał Kusy, Karol Grela
    Academic press:
    Green Chemistry (rok: 2021, tom: 23, strony: 5494–5502), Wydawca: Royal Chemical Society
    Status:
    Published
    DOI:
    10.1039/D1GC01206A - link to the publication
  2. Recent advances in the application of nanoparticles in the selective reduction of carbon–carbon double bonds
    Authors:
    Rafał Kusy, Karol Grela
    Academic press:
    Current Opinion in Green and Sustainable Chemistry (rok: 2022, tom: 38, strony: 100678), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.cogsc.2022.100678 - link to the publication
  3. Ligand-to-metal ratio controls stereoselectivity: Highly functional-group-tolerant, iridium-based, (E)-selective alkyne transfer semihydrogenation
    Authors:
    Rafał Kusy, Marcin Lindner, Jakub Wagner, Karol Grela
    Academic press:
    Chem Catalysis (rok: 2022, tom: 2, strony: 1346-1361), Wydawca: Cell Press
    Status:
    Published
    DOI:
    10.1016/j.checat.2022.04.014 - link to the publication
  4. Protocol for (E)-selective alkyne transfer semihydrogenation catalyzed by generated in situ iridium catalyst
    Authors:
    Rafał Kusy, Karol Grela
    Academic press:
    STAR Protocols , Wydawca: Cell Press
    Status:
    Submitted
    DOI:
    brak - link to the publication

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