Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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New catalysts for hydrometallation of alkenes and alkynes

2016/23/B/ST5/00177

Keywords:

catalysts hydrosilylation hydroboration Schiff bases trasition metal complexes. design and modification of ligands metal borohydrides

Descriptors:

  • ST5_18:
  • ST5_23:
  • ST5_14: Other related subjects

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet im. Adama Mickiewicza w Poznaniu, Wydział Chemii

woj. wielkopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Piotr Pawluć 

Number of co-investigators in the project: 8

Call: OPUS 12 - announced on 2016-09-15

Amount awarded: 870 500 PLN

Project start date (Y-m-d): 2017-07-03

Project end date (Y-m-d): 2021-07-02

Project duration:: 48 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Chemoodporna pompa olejowa o maksymalnej próżni 0,0001 torr (12 000 PLN)
  2. System oczyszczania rozpuszczalników z podwójnym systemem sorbentów, rezerwuarami rozpuszczalników oraz pompą próżniową. (185 000 PLN)
  3. Zestaw komputerowy (4 000 PLN)

Information in the final report

  • Publication in academic press/journals (10)
  1. Hydroboration of alkynes initiated by sodium triethylborohydride
    Authors:
    A.M. Maj, B. Szarłan, P. Pawluc,, M. Zaranek
    Academic press:
    Polyhedron (rok: 2022, tom: 223, strony: 115961-115965), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.poly.2022.115961 - link to the publication
  2. Schiff Base Cobalt(II) Complex-Catalyzed Highly Markovnikov-Selective Hydrosilylation of Alkyn
    Authors:
    Maciej Skrodzki, Violetta Patroniak, Piotr Pawluć
    Academic press:
    Organic Letters (rok: 2021, tom: 23, strony: 663-667), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.orglett.0c03721 - link to the publication
  3. Searching for highly active cobalt catalysts bearing Schiff base ligands for Markovnikov-selective hydrosilylation of alkynes with tertiary silanes
    Authors:
    M. Skrodzki, V. Ortega Garrido, A.G. Csáky, P. Pawluc
    Academic press:
    Journal of Catalysis (rok: 2022, tom: 411, strony: 116-121), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jcat.2022.05.002 - link to the publication
  4. DFT study of trialkylborohydride-catalysed hydrosilylation of alkenes – the mechanism and its implications
    Authors:
    M. Nowicki, M. Zaranek, P. Pawluć, M. Hoffmann
    Academic press:
    Catalysis Science & Technology (rok: 2020, tom: 10, strony: 1066-1072), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C9CY02261A - link to the publication
  5. Direct Dehydrogenative Coupling of Alcohols with Hydrosilanes Promoted by Sodium tri(sec-butyl)borohydride
    Authors:
    M. Skrodzki, M. Zaranek, S. Witomska, P. Pawluć
    Academic press:
    Catalysts (rok: 2018, tom: 8, strony: 618-624), Wydawca: MDPI Basel, Switzerland
    Status:
    Published
    DOI:
    0.3390/catal8120618 - link to the publication
  6. Simple Schiff-Base Cu(II) Complexes as Efficient Catalysts for Benzyl Alcohol Oxidation
    Authors:
    W. Czepa, M.A. Fik, S. Witomska, M. Kubicki, G. Consiglio, P. Pawluć, V. Patroniak
    Academic press:
    Chemistry Select (rok: 2018, tom: 3, strony: 9504-9509), Wydawca: WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
    Status:
    Published
    DOI:
    10.1002/slct.2018015 - link to the publication
  7. The effect of Schiff base ligands on the structure and catalytic activity of cobalt complexes in hydrosilylation of olefins
    Authors:
    Aleksandra Bocian, Maciej Skrodzki, Maciej Kubicki, Adam Gorczyński, Piotr Pawluć, Violetta Patroniak
    Academic press:
    Applied Catalysis A General (rok: 2020, tom: 602, strony: 117665), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.apcata.2020.117665 - link to the publication
  8. Markovnikov Hydrosilylation of Alkenes: How an Oddity Becomes the Goal
    Authors:
    M. Zaranek. P. Pawluć
    Academic press:
    ACS Catalysis (rok: 2018, tom: 8, strony: 9865−9876), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acscatal.8b03104 - link to the publication
  9. Sodium triethylborohydride as a catalyst for the dehydrogenative silylation of terminal alkynes with hydrosilanes
    Authors:
    M. Skrodzki, S. Witomska, P. Pawluć
    Academic press:
    Dalton Transactions (rok: 2018, tom: 47, strony: 5948–5951), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c8dt00684a - link to the publication
  10. Markovnikov-selective double hydrosilylation of challenging terminal aryl alkynes under cobalt and iron catalysis
    Authors:
    Ł. Banach, D. Brykczyńska, A. Gorczyński, M. Skrodzki, P. Pawluć
    Academic press:
    Chemical Communications (rok: 2022, tom: -, strony: -), Wydawca: Royal Society of Chemistry
    Status:
    Submitted
    DOI:
    - - link to the publication

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