Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Quantum nanomagnets based on metal complexes with unusual geometries and using new unusual ligands

2016/22/E/ST5/00055

Keywords:

nanomaganetism organometallics magnetic relaxation molecular crystals

Descriptors:

  • ST5_12: Methods of nanomaterials/materials synthesis
  • ST5_14: Other related subjects
  • ST5_17:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Jagielloński, Wydział Chemii

woj. małopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Dawid Pinkowicz 

Number of co-investigators in the project: 5

Call: SONATA BIS 6 - announced on 2016-06-15

Amount awarded: 1 497 483 PLN

Project start date (Y-m-d): 2017-04-13

Project end date (Y-m-d): 2022-04-12

Project duration:: 60 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Dwustopniowa rotacyjna pompa próżniowa do linii Schlenka (11 700 PLN)
  2. Indukcyjne mieszadło magnetyczne 1.
  3. System oczyszczania rozpuszczlaników w atmosferze gazu obojętnego (160 110 PLN)
  4. Zakrzywiony monochromator krystaliczny do rentgenowskiego dyfraktometru monokrystalicznego (145 000 PLN)
  5. Komora rękawicowa do pracy w warunkach beztlenowych i bezwodnych (290 890 PLN)
  6. Pompa próżniowa do komory rękawicowej.
  7. Indukcyjne mieszadło magnetyczne 2.
  8. Waga analityczna do gloveboxa (3 300 PLN)

Information in the final report

  • Publication in academic press/journals (25)
  1. Correlating magnetic anisotropy with [Mo(CN)7]4− geometry of MnII–MoIII magnetic frameworks
    Authors:
    Michał Magott, Kim R. Dunbar, Dawid Pinkowicz
    Academic press:
    Dalton Transactions (rok: 2019, tom: 48, strony: 15493-15500), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/c9dt02164g - link to the publication
  2. Magnetization Dynamics and Coherent Spin Manipulation of a Propeller Gd(III) Complex with the Smallest Helicene Ligand
    Authors:
    Gabriela Handzlik, Michał Magott, Mirosław Arczyński, Alena M. Sheveleva, Floriana Tuna, Marcin Sarewicz, Artur Osyczka, Michał Rams, Veacheslav Vieru, Liviu F. Chibotaru, Dawid Pinkowicz
    Academic press:
    Journal of Physical Chemistry Letters (rok: 2020, tom: 11, strony: 1508-1515), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpclett.9b03275 - link to the publication
  3. Syntheses, crystal structures and magnetic properties of a series of ZnII2LnIII2 compounds (Ln = Gd, Tb, Dy, Ho and Er): contrasting structural and magnetic features
    Authors:
    Sagar Ghosh, Nairita Hari, Dawid Pinkowicz, Magdalena Fitta, Sasankasekhar Mohanta
    Academic press:
    New Journal of Chemistry (rok: 2018, tom: 42, strony: 15917-15929), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C8NJ02532K - link to the publication
  4. Cross-linking of cyanide magnetic coordination polymers by rational insertion of formate, cyanide or azide
    Authors:
    Gabriela Handzlik, Barbara Sieklucka, Dawid Pinkowicz
    Academic press:
    Dalton Transactions (rok: 2018, tom: 47, strony: 11888-11894), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C8DT01513A - link to the publication
  5. Heterotrimetallic Cyanide-Bridged 3d-4d-5d Frameworks Based on a Photomagnetic Secondary Building Unit
    Authors:
    Michał Magott, Marcin Sarewicz, Szymon Buda, Dawid Pinkowicz
    Academic press:
    Inorganic Chemisry (rok: 2020, tom: 59, strony: 8925-8934), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c00737 - link to the publication
  6. Large breathing effect induced by water sorption in a remarkably stable nonporous cyanide-bridged coordination polymer
    Authors:
    Michał Magott, Bartłomiej Gaweł, Marcin Sarewicz, Mateusz Reczyński, Karolina Ogorzały, Wacław Makowski, Dawid Pinkowicz
    Academic press:
    Chemical Science (rok: 2021, tom: 12, strony: 9176-9188), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D1SC02060A - link to the publication
  7. Molecular realizations of 3D Heisenberg magnet: Critical scaling
    Authors:
    Robert Pełka, Dawid Pinkowicz, Barbara Sieklucka, Magdalena Fitta
    Academic press:
    Journal of Alloys and Compounds (rok: 2018, tom: 765, strony: 520-526), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jallcom.2018.06.171 - link to the publication
  8. A photomagnetic sponge: high-temperature light-induced ferrimagnet controlled by water sorption
    Authors:
    Michał Magott, Mateusz Reczyński, Bartłomiej Gaweł, Barbara Sieklucka, Dawid Pinkowicz
    Academic press:
    Journal of the American Chemical Society (rok: 2018, tom: 140, strony: 15876-15882), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jacs.8b09322 - link to the publication
  9. How to Quench Ferromagnetic Ordering in a CN-Bridged Ni(II)-Nb(IV) Molecular Magnet? A Combined High-Pressure Single-Crystal X-Ray Diffraction and Magnetic Study
    Authors:
    Gabriela Handzlik, Barbara Sieklucka, Hanna Tomkowiak, Andrzej Katrusiak, Dawid Pinkowicz
    Academic press:
    Magnetochemistry (rok: 2019, tom: 5, strony: 33), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/magnetochemistry5020033 - link to the publication
  10. Identical anomalous Raman relaxation exponent in a family of single ion magnets: towards reliable Raman relaxation determination?
    Authors:
    Gabriela Handzlik, Michał Magott, Mirosław Arczyński, Alena M. Sheveleva, Floriana Tuna, Stanisław Baran, Dawid Pinkowicz
    Academic press:
    Dalton Transactions (rok: 2020, tom: 49, strony: 11942-11949), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d0dt02439b - link to the publication
  11. Low-Coordinate Dinuclear Dysprosium (III) Single Molecule Magnets Utilizing LiCl as Bridging Moieties and Tris (amido) amine as Blocking Ligands
    Authors:
    Maria Brzozowska, Gabriela Handzlik, Mikolaj Zychowicz, Dawid Pinkowicz
    Academic press:
    Magnetochemistry (rok: 2021, tom: 7, strony: 125), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/magnetochemistry7090125 - link to the publication
  12. Photoinduced Mo-CN Bond Breakage in Octacyanomolybdate Leading to Spin Triplet Trapping
    Authors:
    Xinghui Qi, Sebastien Pillet, Coen de Graaf, Michał Magott, El-Eulmi Bendeif, Philippe Guionneau, Mathieu Rouzieres, Valerie Marvaud, Olaf Stefańczyk, Dawid Pinkowicz, Corine Mathoniere
    Academic press:
    Angewante Chemie International Edition (rok: 2020, tom: 59, strony: 45297), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/anie.201914527 - link to the publication
  13. Pseudo-tetrahedral vs. pseudo-octahedral ErIII single molecule magnets and the disruptive role of coordinated TEMPO radical
    Authors:
    Maria Brzozowska, Gabriela Handzlik, Katarzyna Kurpiewska, Mikołaj Zychowicz, Dawid Pinkowicz
    Academic press:
    Inorganic Chemistry Frontiers (rok: 2021, tom: 8, strony: 2817-2828), Wydawca: Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/D1QI00262G - link to the publication
  14. Site-Selective Photoswitching of Two Distinct Magnetic Chromophores in a Propeller-Like Molecule To Achieve Four Different Magnetic States
    Authors:
    Mirosław Arczyński, Jan Stanek, Barbara Sieklucka, Kim R. Dunbar, Dawid Pinkowicz
    Academic press:
    Journal of the American Chemical Society (rok: 2019, tom: 141, strony: 19067-19077), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/jacs.9b09576 - link to the publication
  15. How to Make a Better Magnet? Insertion of Additional Bridging Ligands into a Magnetic Coordination Polymer
    Authors:
    Gabriela Handzlik, Dawid Pinkowicz
    Academic press:
    Magnetochemistry (rok: 2018, tom: 4, strony: 41), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/magnetochemistry4030041 - link to the publication
  16. Influence of the Increasing Number of Organic Radicals on the Structural, Magnetic, and Electrochemical Properties of the Copper(II)–Dioxothiadiazole Family of Complexes
    Authors:
    Mirosław Arczyński, Dawid Pinkowicz
    Academic press:
    Inorganic Chemistry (rok: 2020, tom: 59, strony: 13489-13501), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c01904 - link to the publication
  17. Iron(II) spin crossover (SCO) materials based on dipyridyl-N-alkylamine
    Authors:
    Taous Houari, Emmelyne Cuza, Dawid Pinkowicz, Mathieu Marchivie, Said Yefsah, Smail Triki
    Academic press:
    Crystals (rok: 2018, tom: 8, strony: 401), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/cryst8110401 - link to the publication
  18. Light‐Induced Spin‐State Switching of the MoIV Centre in Trinuclear [CuII(diamine)2]2[MoIV(CN)8] Molecules
    Authors:
    Tomasz Korzeniak, Sujit Sasmal, Dawid Pinkowicz, Olaf Stefańczyk, Barbara Sieklucka
    Academic press:
    European Journal of Inorganic Chemistry (rok: 2018, tom: 2018, strony: 2019-2025), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejic.201800138 - link to the publication
  19. The photomagnetic effect in 2-D cyanido-bridgedcoordination polymer [Cu(aepa)]10[Mo(CN)8]5.30H2O
    Authors:
    Tomasz Korzeniak, Sujit Sasmal, Dawid Pinkowicz, Barbara Sieklucka
    Academic press:
    New Journal of Chemistry (rok: 2018, tom: 42, strony: 17009-17015), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C8NJ02952K - link to the publication
  20. 1,2,5-Thiadiazole 1,1-dioxides and Their Radical Anions: Structure, Properties, Reactivity, and Potential Use in the Construction of Functional Molecular Materials
    Authors:
    Paweł Pakulski, Dawid Pinkowicz
    Academic press:
    Molecules (rok: 2021, tom: 26, strony: 4873), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules26164873 - link to the publication
  21. A new look at molecular and electronic structure of homoleptic diiron (II, II) complexes with N, N‐bidentate ligands: Combined experimental and theoretical study
    Authors:
    Krzesimir Korona, Michał Terlecki, Iwona Justyniak, Michał Magott, Jan Żukrowski, Arkadiusz Kornowicz, Dawid Pinkowicz, Adam Kubas, Janusz Lewinski
    Academic press:
    Chemistry–A European Journal (rok: 2022, tom: online, strony: online), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.202200620 - link to the publication
  22. An intermetallic molecular nanomagnet with the lanthanide coordinated only by transition metals
    Authors:
    Michał Magott, Maria Brzozowska, Stanisław Baran, Veacheslav Vieru, Dawid Pinkowicz
    Academic press:
    Nature Communications (rok: 2022, tom: 13, strony: 2014), Wydawca: Springer Nature
    Status:
    Published
    DOI:
    10.1038/s41467-022-29624-7 - link to the publication
  23. Bis(triphenylphosphine)iminium Salts of Dioxothiadiazole Radical Anions: Preparation, Crystal Structures, and Magnetic Properties
    Authors:
    PAweł Pakulski, Mirosław Arczyński, Dawid Pinkowicz
    Academic press:
    Crystals (rok: 2019, tom: 9, strony: 30), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/cryst9010030 - link to the publication
  24. Cyanide vs. azide ''magnetic arm wrestling'': MnII–NbIV and MnII–MoIV magnetic coordination polymers with mixed bridging
    Authors:
    Gabriela Handzlik, Marcin Kozieł, Anna Olejniczak, Barbara Sieklucka, Dawid Pinkowicz
    Academic press:
    Chemical Communications (rok: 2017, tom: 53, strony: 9753-9756), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c7cc05319c - link to the publication
  25. Reversible Single-Crystal-to-Single-Crystal Transformation in Photomagnetic Cyanido-Bridged Cd4M2 Octahedral Molecules
    Authors:
    Tomasz Korzeniak, Robert Jankowski, Marcin Kozieł, Dawid Pinkowicz, Barbara Sieklucka
    Academic press:
    Inorganic Chemistry (rok: 2017, tom: 56, strony: 12914-12919), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.7b01708 - link to the publication

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