Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Asymmetric transformations with hypervalent iodine reagents. Merger with nucleophilic catalysis and novel chiral iodoarenes as entry to powerful synthetic reactions.

2016/22/E/ST5/00566

Keywords:

asymmetric catalysis organocatalysis hypervalent iodine synthetic methodology computational chemistry

Descriptors:

  • ST5_23:
  • ST5_18:
  • ST4_14: Catalysis

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Warszawski, Centrum Nowych Technologii Uniwersytetu Warszawskiego

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Marcin Kałek 

Number of co-investigators in the project: 6

Call: SONATA BIS 6 - announced on 2016-06-15

Amount awarded: 1 996 800 PLN

Project start date (Y-m-d): 2017-05-09

Project end date (Y-m-d): 2023-05-08

Project duration:: 72 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Mały sprzęt (10 000 PLN)
  2. Mieszadło magnetyczne z ogrzewaniem i kontrolą temperatury (5 szt.) (17 500 PLN)
  3. Mieszadło magnetyczne z wypozażeniem (3 szt.).
  4. Pompa próżniowa membranowa (12 000 PLN)
  5. Wyparka rotacyjna (14 000 PLN)
  6. Zbiornik Dewara 35 L (13 000 PLN)
  7. Chiller recyrkulacyjny (13 000 PLN)
  8. Kontroler pompy próżniowej do systemu oczyszczania rozpuszczalników.
  9. Pompa próżniowa olejowa (4 szt.) (44 000 PLN)
  10. Pompa strzykawkowa.
  11. System do chromatografii flash (130 000 PLN)
  12. Zestaw komputerowy.
  13. Chłodziarka laboratoryjna.

Information in the final report

  • Publication in academic press/journals (9)
  1. Organocatalytic group transfer reactions with hypervalent iodine reagents
    Authors:
    Ghosh, M.; Rajkiewicz, A. A.; Kalek, M.
    Academic press:
    Synthesis (rok: 2019, tom: 51, strony: 359-370), Wydawca: Thieme
    Status:
    Published
    DOI:
    10.1055/s-0037-1609639 - link to the publication
  2. Transition metal‐free aryl‐aryl cross‐coupling: C–H arylation of 2‐naphthols with diaryliodonium salts
    Authors:
    Ghosh, M. K.; Rzymkowski, J.; Kalek, M.
    Academic press:
    Chem. Eur. J. (rok: 2019, tom: 25, strony: 9619-9623), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/chem.201902204 - link to the publication
  3. Intermolecular enantioselective dearomatizing para-methoxylation of phenols using 2-iodoresorcinol/ lactamide catalysts
    Authors:
    Kraszewski, K.; Tomczyk, I.; Kalek, M.
    Academic press:
    Tetrahedron Lett. (rok: 2022, tom: 108, strony: 154127), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.tetlet.2022.154127 - link to the publication
  4. Mechanism of Iodine(III)‐Promoted Oxidative Dearomatizing Hydroxylation of Phenols: Evidence for a Radical‐Chain Pathway
    Authors:
    Kraszewski, K.; Tomczyk, I.; Drabinska, A.; Bienkowski, K.; Solarska, R.; Kalek, M.
    Academic press:
    Chem. Eur. J (rok: 2020, tom: 26, strony: 11584-11592), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/chem.202002026 - link to the publication
  5. Synthesis of Pummerer's ketone and its analogs by iodosobenzene-promoted oxidative phenolic coupling
    Authors:
    Sarkar, S.; Ghosh, M. K.; Kalek, M.
    Academic press:
    Tetrahedron Lett. (rok: 2020, tom: 61, strony: 152459), Wydawca: PERGAMON-ELSEVIER SCIENCE LTD
    Status:
    Published
    DOI:
    10.1016/j.tetlet.2020.152459 - link to the publication
  6. Metal-free S-arylation of phosphorothioate diesters and related compounds with diaryliodonium salts
    Authors:
    Sarkar, S.; Kalek, M.
    Academic press:
    Org. Lett. (rok: 2023, tom: 25, strony: 671-675), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.orglett.2c04310 - link to the publication
  7. Regioselective dearomatization of N-alkylquinolinium and pyridinium salts under Morita-Baylis-Hillman conditions
    Authors:
    Pareek, A.; Kalek, M.
    Academic press:
    Adv. Synth. Catal. (rok: 2022, tom: 364, strony: 2846-2851), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/adsc.202200429 - link to the publication
  8. Synthesis of aryl sulfides by metal-free arylation of thiols with diaryliodonium salts under basic conditions
    Authors:
    Sarkar, S.; Wojciechowska, N.; Rajkiewicz, A. A.; Kalek, M.
    Academic press:
    Eur. J. Org. Chem. (rok: 2022, tom: 2, strony: e202101408), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/ejoc.202101408 - link to the publication
  9. Transition metal-free and regioselective vinylation of phosphine oxides and H-phosphinates with VBX reagents
    Authors:
    Castoldi, L.; Rajkiewicz, A. A.; Olofsson, B.
    Academic press:
    Chem. Commun. (rok: 2020, tom: 56, strony: 14389-14392), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D0CC05992G - link to the publication

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