Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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A new look at the phenomenon of up-conversion in nanoparticles doped with lanthanide ions: synthesis of core/shell structures and studies of emission under radiation from the second and third biological window

2016/22/E/ST5/00016

Keywords:

nanoparticles lanthanides upconversion multifunctionality cytotoxicity

Descriptors:

  • ST5_10: Functional materials/nanomaterials, nanoparticles
  • ST5_12: Methods of nanomaterials/materials synthesis
  • ST5_24:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet im. Adama Mickiewicza w Poznaniu, Wydział Chemii

woj. wielkopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Tomasz Grzyb 

Number of co-investigators in the project: 6

Call: SONATA BIS 6 - announced on 2016-06-15

Amount awarded: 1 929 300 PLN

Project start date (Y-m-d): 2017-03-30

Project end date (Y-m-d): 2022-09-29

Project duration:: 66 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Laser półprzewodnikowy (30 000 PLN)
  2. Suszarka.
  3. Waga analityczna.
  4. Wyparka.
  5. Komputer (2 szt.) (6 000 PLN)
  6. Reaktor do syntez nanocząstek (30 000 PLN)
  7. Laptop (4 000 PLN)
  8. Moduł do rejestracji widm emisji i zaników luminescencji w zakresie 950 – 1600 nm.
  9. Analizator wielkości nanocząstek i potencjału dzeta - Zetasizer Nano ZS (330 000 PLN)
  10. Rozbudowa układu do pomiarów wydajności kwantowej emisji. (20 000 PLN)
  11. stacja dokująca.

Information in the final report

  • Publication in academic press/journals (18)
  1. Functionalization of cellulose fibers and paper with lanthanide-based luminescent core/shell nanoparticles providing 3-level protection for advanced anti-counterfeiting purposes
    Authors:
    A. Szczeszak, M. Skwierczyńska, D. Przybylska, M. Runowski, E. Śmiechowicz, A. Erdman, O. Ivashchenko, T. Grzyb, P. Kulpiński, K. Olejnik
    Academic press:
    Materials and Design (rok: 2022, tom: 218, strony: 110684), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.matdes.2022.110684 - link to the publication
  2. NIR-to-NIR and NIR-to-Vis up-conversion of SrF2:Ho3+ nanoparticles under 1156 nm excitation
    Authors:
    Sylwia Ryszczyska, Tomasz Grzyb
    Academic press:
    Methods and Applications in Fluorescence (rok: 2022, tom: 10, strony: 24001), Wydawca: IOP Publishing
    Status:
    Published
    DOI:
    10.1088/2050-6120/ac4999 - link to the publication
  3. Upconversion in Detail: Multicolor Emission of Yb/Er/Tm‐Doped Nanoparticles under 800, 975, 1208, and 1532 nm Excitation Wavelengths
    Authors:
    Artur Tymiński, Inocencio R. Martín, Tomasz Grzyb
    Academic press:
    Particle & Particle Systems Characterization (rok: 2020, tom: 37, strony: 2000068), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ppsc.202000068 - link to the publication
  4. Improvement in Luminescence Intensity of β-NaYF4: 18%Yb3+, 2%Er3+@β-NaYF4 Nanoparticles as a Result of Synthesis in the Presence of Stearic Acid
    Authors:
    Piotr Kaminski, Dominika Przybylska, Gabriela Klima, Tomasz Grzyb
    Academic press:
    Nanomaterials (rok: 2022, tom: 12, strony: 319), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/nano12030319 - link to the publication
  5. Manipulation of up-conversion emission in NaYF4 core@shell nanoparticles doped by Er3+, Tm3+, or Yb3+ ions by excitation wavelength—three ions—plenty of possibilities
    Authors:
    Tomasz Grzyb, Piotr Kamiński, Dominika Przybylska, Artur Tymiński, F. Sanz-Rodríguezb, Patricia Haro Gonzalez
    Academic press:
    Nanoscale (rok: 2021, tom: 13, strony: 7322-7333), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D0NR07136F - link to the publication
  6. In search of ideal nanoparticles based on up-conversion for applications in human blood
    Authors:
    Natalia Jurga, Sylwia Ryszczyńska, Tomasz Grzyb
    Academic press:
    Materials & Design , Wydawca: Elsevier
    Status:
    Submitted
    DOI:
    brak - link to the publication
  7. Formation Mechanism, Structural, and Upconversion Properties of Alkaline Rare-Earth Fluoride Nanocrystals Doped With Yb3+/Er3+ Ions
    Authors:
    Tomasz Grzyb, Dominika Przybylska
    Academic press:
    Inorganic Chemistry (rok: 2018, tom: 57, strony: 6410−6420), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.8b00484 - link to the publication
  8. Multifunctional Cellulose Fibers: Intense Red Upconversion under 1532 Nm Excitation and Temperature-Sensing Properties
    Authors:
    T. Grzyb, D. Przybylska, A. Szczeszak, E. Śmiechowicz, P. Kulpiński, I.R. Martín
    Academic press:
    Carbohydrate Polymers (rok: 2022, tom: 294, strony: 119782), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.carbpol.2022.119782 - link to the publication
  9. Synthesis and up-conversion of core/shell SrF2:Yb3+,Er3+@SrF2:Yb3+,Nd3+ nanoparticles under 808, 975, and 1532 nm excitation wavelengths
    Authors:
    Dominika Przybylska , Tomasz Grzyb
    Academic press:
    Journal of Alloys and Compounds (rok: 2020, tom: 831, strony: 154797), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jallcom.2020.154797 - link to the publication
  10. Tailoring structure, morphology and up-conversion properties of CaF2:Yb3+,Er3+ nanoparticles by the route of synthesis
    Authors:
    Dominika Przybylska, Tomasz Grzyb
    Academic press:
    Journal of Materials Science (rok: 2020, tom: 55, strony: 14166-14178), Wydawca: Springer
    Status:
    Published
    DOI:
    10.1007/s10853-020-05049-9 - link to the publication
  11. Upconverting SrF2:Er3+ Nanoparticles for Optical Temperature Sensors
    Authors:
    Sylwia Ryszczyńska, Karolina Trejgis, Łukasz Marciniak, Tomasz Grzyb
    Academic press:
    ACS Applied Nano Materials (rok: 2021, tom: 4, strony: 10438−10448), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acsanm.1c01964 - link to the publication
  12. Anti-Counterfeiting System Based on Luminescent Varnish Enriched by NIR- Excited Nanoparticles for Paper Security
    Authors:
    D. Przybylska, T. Grzyb, A. Erdman, K. Olejnik, A. Szczeszak
    Academic press:
    Scientific Reports (rok: 2022, tom: 12, strony: 19388), Wydawca: Nature
    Status:
    Published
    DOI:
    10.1038/s41598-022-23686-9 - link to the publication
  13. Bi3+ as an enhancer for down- and upconversion luminescence in ternary vanadate structures
    Authors:
    NinaKaczorowska, AgataSzczeszak, StefanLis
    Academic press:
    Ceramics International (rok: 2021, tom: 47, strony: 24182-24190), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.ceramint.2021.05.129 - link to the publication
  14. Improvement of ligand‑free modification strategy to obtain water‑stable up‑converting nanoparticles with bright emission and high reaction yield
    Authors:
    Natalia Jurga, Dominika Przybylska, Piotr Kamiński, Tomasz Grzyb
    Academic press:
    Scientific Reports (rok: 2021, tom: 11, strony: 18846), Wydawca: Nature Research
    Status:
    Published
    DOI:
    10.1038/s41598-021-98240-0 - link to the publication
  15. Influence of the synthesis route on the spectroscopic, cytotoxic, and temperature-sensing properties of oleate-capped and ligand-free core/ shell nanoparticles
    Authors:
    Natalia Jurga, Dominika Przybylska, Piotr Kaminski, Artur Tyminnski, Bartosz F. Grzeskowiak, Tomasz Grzyb
    Academic press:
    Journal of Colloid and Interface Science (rok: 2022, tom: 606, strony: 1421-1434), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jcis.2021.08.093 - link to the publication
  16. Upconverting SrF2 nanoparticles doped with Yb3+/Ho3+, Yb3+/Er3+ and Yb3+/Tm3+ ions – optimisation of synthesis method, structural, spectroscopic and cytotoxicity studies
    Authors:
    Dominika przybylska, Anna Ekner-Grzyb, Bartosz F. Grześkowiak, Tomasz Grzyb
    Academic press:
    Scientific Reports (rok: 2019, tom: 9, strony: 8669), Wydawca: Nature Publishing Group
    Status:
    Published
    DOI:
    10.1038/s41598-019-45025-1 - link to the publication
  17. Sr 2 LuF 7 :Yb 3+ –Ho 3+ –Er 3+ Upconverting Nanoparticles as Luminescent Thermometers in the First, Second, and Third Biological Windows
    Authors:
    Marcin Runowski, Szymon Goderski, Dominika Przybylska, Tomasz Grzyb, Stefan Lis, Inocencio R. Martín
    Academic press:
    ACS Applied Nano Material (rok: 2020, tom: 3, strony: 6406–6415), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acsanm.0c00839 - link to the publication
  18. Ultraviolet- and Near-Infrared-Excitable LaPO 4 :Yb 3+ /Tm 3+ /Ln 3+ (Ln = Eu, Tb) Nanoparticles for Luminescent Fibers and Optical Thermometers
    Authors:
    Artur Tymiński, Emilia Śmiechowicz, Inocencio R. Martín, and Tomasz Grzyb
    Academic press:
    ACS Applied Nano Materials (rok: 2020, tom: 3, strony: 6541-6551), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acsanm.0c01025 - link to the publication

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