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Information on the principal investigator and host institution

Information of the project and the call

Keywords

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Frustrated Lewis Pairs (FLP): new class of phosphorus compounds with applications in synthetic chemistry and catalysis.

2016/21/B/ST5/03088

Keywords:

phosphorus frustrated Lewis pairs catalysis

Descriptors:

  • ST5_24:
  • ST5_8: Metals, alloys
  • ST5_18:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Politechnika Gdańska, Wydział Chemiczny

woj. pomorskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Rafał Grubba 

Number of co-investigators in the project: 6

Call: OPUS 11 - announced on 2016-03-15

Amount awarded: 466 500 PLN

Project start date (Y-m-d): 2017-07-19

Project end date (Y-m-d): 2020-07-18

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Oprogramowanie do obliczeń DFT - Amsterdam Density Functional (ADF) (25 000 PLN)
  2. Pompa próżniowa (10 000 PLN)
  3. Reaktor ciśnieniowy (15 000 PLN)
  4. Stacja robocza do obliczeń DFT (20 000 PLN)

Information in the final report

  • Publication in academic press/journals (10)
  1. Diphosphination of CO2 and CS2 mediated by frustrated Lewis pairs – catalytic route to phosphanyl derivatives of formic and dithioformic acid
    Authors:
    Natalia Szynkiewicz, Łukasz Ponikiewski, Rafał Grubba
    Academic press:
    Chemical Communications (rok: 2019, tom: 55, strony: 2928--2931), Wydawca: The Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/c9cc00621d - link to the publication
  2. Diphosphinoboranes as Intramolecular Frustrated Lewis Pairs: P−B−P Bond Systems for the Activation of Dihydrogen, Carbon Dioxide, and Phenyl Isocyanate
    Authors:
    Natalia Szynkiewicz, Anna Ordyszewska, Jarosław Chojnacki, Rafał Grubba
    Academic press:
    Inorganic Chemistry (rok: 2021, tom: 60, strony: 3794−3806), Wydawca: The American Chemical Society (ACS)
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c03563 - link to the publication
  3. Reactivity of bulky aminophosphanes towards small molecules: activation of dihydrogen and carbon dioxide by aminophosphane/borane frustrated Lewis pairs
    Authors:
    Magdalena Siedzielnik, Kinga Kaniewska-Laskowska, Natalia Szynkiewicz, Jarosław Chojnacki, Rafał Grubba
    Academic press:
    Polyhedron (rok: 2021, tom: 194, strony: 114930-114942), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.poly.2020.114930 - link to the publication
  4. Bonding in Phosphanylphosphinidene Complexes of Transition Metals and their Correlation with Structures, 31P NMR Spectra, and Reactivities
    Authors:
    Mateusz Zauliczny, Anna Ordyszewska, Jerzy Pikies, Rafał Grubba
    Academic press:
    European Journal of Inorganic Chemistry (rok: 2018, tom: 2018, strony: 3131–3141), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/ejic.201800270 - link to the publication
  5. Symmetrical and unsymmetrical diphosphanes with diversified alkyl, aryl, and amino substituents
    Authors:
    Natalia Szynkiewicz, Łukasz Ponikiewski, Rafał Grubba
    Academic press:
    Dalton Transactions (rok: 2018, tom: 47, strony: 16885–16894), Wydawca: The Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/c8dt03775b - link to the publication
  6. The new diphosphanylphosphido complexes of tungsten(VI) and molybdenum(VI). Their synthesis, structures and properties
    Authors:
    Aleksandra Wiśniewska, Rafał Grubba, Łukasz Ponikiewski, Mateusz Zauliczny, Jerzy Pikies
    Academic press:
    Dalton Transactions (rok: 2018, tom: 47, strony: 10213–10222), Wydawca: The Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/c8dt01977k - link to the publication
  7. Diaminophosphinoboranes: effective reagents for phosphinoboration of CO2.
    Authors:
    Natalia Szynkiewicz, Anna Ordyszewska, Jarosław Chojnacki, Rafał Grubba
    Academic press:
    RSC Advances (rok: 2019, tom: 9, strony: 27749–27753), Wydawca: The Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/c9ra06638a - link to the publication
  8. Structural and spectroscopic analysis of a new family of monomeric diphosphinoboranes
    Authors:
    Anna Ordyszewska, Natalia Szynkiewicz, Emil Perzanowski, Jarosław Chojnacki, Aleksandra Wiśniewska, Rafał Grubba
    Academic press:
    Dalton Transactions (rok: 2019, tom: 48, strony: 12482–12495), Wydawca: The Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/c9dt02195g - link to the publication
  9. Syntheses, Structures and Reactivity of Terminal Phosphido Complexes of Iron(II) Supported by a β-Diketiminato Ligand
    Authors:
    Kinga Kaniewska, Alina Dragulescu-Andrasi, Łukasz Ponikiewski, Jerzy Pikies,Sebastian A. Stoian, Rafał Grubba
    Academic press:
    European Journal of Inorganic Chemistry (rok: 2018, tom: 2018, strony: 4298–4308), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/ejic.201800850 - link to the publication
  10. Activation of N2O and SO2 by the P-B bond system. Reversible binding of SO2 by the P-O-B geminal frustrated Lewis pair.
    Authors:
    Natalia Szynkiewicz, Jarosław Chojnacki, Rafał Grubba
    Academic press:
    Inorganic Chemistry (rok: 2020, tom: 59, strony: 6332–6337), Wydawca: The American Chemical Society (ACS)
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c00435 - link to the publication

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