Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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The optically pure aziridine rings as highly effective units to transfer of chirality to racemic or prochiral reagents. Aziridine phosphines as a new class of P,N-ligands and transition metal free catalysts.

2016/21/B/ST5/00421

Keywords:

Aziridines aziridine phosphines chiral catalysts/ligands asymmetric synthesis

Descriptors:

  • ST5_18:
  • ST5_23:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Łódzki, Wydział Chemii

woj. łódzkie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Michał Rachwalski 

Number of co-investigators in the project: 6

Call: OPUS 11 - announced on 2016-03-15

Amount awarded: 833 400 PLN

Project start date (Y-m-d): 2017-01-17

Project end date (Y-m-d): 2021-01-16

Project duration:: 48 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. System do chromatografii Flash (250 000 PLN)
  2. Chemoodporna pompa olejowa (30 000 PLN)
  3. Zestaw komputerowy z oprogramowaniem i akcesoriami (w tym jeden komputer typu laptop). (10 000 PLN)

Information in the final report

  • Publication in academic press/journals (4)
  1. Asymmetric Friedel–Crafts Alkylation of Indoles Catalyzed by Chiral Aziridine-Phosphines
    Authors:
    Aleksandra Buchcic, Anna Zawisza, Stanisław Leśniak, Michał Rachwalski
    Academic press:
    Catalysts (rok: 2020, tom: 10, strony: 971 (1-10)), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/catal10090971 - link to the publication
  2. Efficient Asymmetric Simmons-Smith Cyclopropanation and Diethylzinc Addition to Aldehydes Promoted by Enantiomeric Aziridine-Phosphines
    Authors:
    A. Buchcic-Szychowska, J. Adamczyk, L. Marciniak, A. M. Pieczonka, A. Zawisza, S. Leśniak, M. Rachwalski
    Academic press:
    Catalysts (rok: 2021, tom: 11, strony: 968 (1-11)), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/catal11080968 - link to the publication
  3. Enantioselective Mannich Reaction Promoted by Chiral Phosphinoyl-Aziridines
    Authors:
    Aleksandra Buchcic, Anna Zawisza,Stanisław Leśniak, Justyna Adamczyk, Adam Marek Pieczonka, Michał Rachwalski
    Academic press:
    Catalysts (rok: 2019, tom: 9, strony: 837 (1-9)), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/catal9100837 - link to the publication
  4. Phosphinoyl-aziridines as a new class of chiral catalysts for enantioselective Michael addition
    Authors:
    Zuzanna Wujkowska, Anna Zawisza, Stanisław Leśniak, Michał Rachwalski
    Academic press:
    Tetrahedron (rok: 2019, tom: 75, strony: 230-235), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.tet.2018.11.052 - link to the publication

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