Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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Molecular propellers, bevel gears and sea anemones - dynamically chiral triarylmethyl derivatives as versatile stereochemical probes, receptors, catalysts and inclusion forming compounds

2016/21/B/ST5/00100

Keywords:

chirality molecular recognition stereoselective synthesis inclusion circular dichroism

Descriptors:

  • ST5_22:
  • ST5_23:
  • ST4_3: Molecular architecture and structure

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet im. Adama Mickiewicza w Poznaniu, Wydział Chemii

woj. wielkopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Marcin Kwit 

Number of co-investigators in the project: 8

Call: OPUS 11 - announced on 2016-03-15

Amount awarded: 1 077 710 PLN

Project start date (Y-m-d): 2017-01-17

Project end date (Y-m-d): 2020-04-16

Project duration:: 39 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Licencja na pakiety oprogramowania ADF i Turbomole (30 000 PLN)
  2. Pompa próżniowa z kontrolerem (22 000 PLN)
  3. Rozbudowa klastra obliczeniowego (30 000 PLN)
  4. System próżniowy z wymrażaniem (50 000 PLN)
  5. zamrażarka laboratoryjna.
  6. Przystawka do automatycznego miareczkowania z wyposażeniem (120 000 PLN)
  7. Lampa rentgenowska (50 000 PLN)

Information in the final report

  • Publication in academic press/journals (10)
  1. Dynamic Induction of Optical Activity in Triarylmethanols and Their Carbocations
    Authors:
    Bartosz Stasiak, Agnieszka Czapik, and Marcin Kwit
    Academic press:
    The Journal of Organic Chemistry (rok: 2021, tom: 86, strony: 643-656), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.joc.0c02289 - link to the publication
  2. Trityl-containing alcohols – an efficient chirality transmission process from inductor to the stereodynamic propeller and their solid-state structural diversity
    Authors:
    S. Górczyńska, A. Brzdonkiewicz, M. Jelecki, A. Czapik, B. Stasiak, and M. Kwit
    Academic press:
    Molecules (rok: 2020, tom: 25, strony: 707), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules25030707 - link to the publication
  3. Diversity of N-tiphenylacetyl-l-tyrosine solvates with halogenated solvents
    Authors:
    A. Czapik, M. Kwit
    Academic press:
    Acta Crystallographica Section C , Wydawca: IUCr Journals
    Status:
    Submitted
    DOI:
    brak - link to the publication
  4. Chiral Cocrystal Solid Solutions, Molecular Complexes, and Salts of N-Triphenylacetyl-L-Tyrosine and Diamines
    Authors:
    A. Czapik, M. Jelecki, and M. Kwit
    Academic press:
    International Journal of Molecular Sciences (rok: 2019, tom: 20, strony: 5004), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/ijms20205004 - link to the publication
  5. Chiral Triphenylacetic Acid Esters: Residual Stereoisomerism and Solid-State Variability of Molecular Architectures
    Authors:
    Natalia Prusinowska, Agnieszka Czapik, and Marcin Kwit
    Academic press:
    The Journal of Organic Chemistry (rok: 2021, tom: 86, strony: 6433-6448), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.joc.1c00279 - link to the publication
  6. Dynamic optical activity induction in the N-alkyl-N'-trityl ureas and thioureas
    Authors:
    N. Prusinowska, A. Czapik, M. Wojciechowska, and M. Kwit
    Academic press:
    Organic&Biomolecular Chemistry (rok: 2019, tom: 17, strony: 7782-7793), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/c9ob01319a - link to the publication
  7. Optical activity and helicity enhancement of highly sensitive dinaphthylmethane-based stereodynamic probes for secondary alcohols
    Authors:
    Tomasz Madry, Agnieszka Czapik, Marcin Kwit
    Academic press:
    ACS Omega (rok: 2019, tom: 4, strony: 3244−3256), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acsomega.8b03337 - link to the publication
  8. Transfer of chirality in N-triphenylacetylamino acids and chiral derivatives of N-triphenylacetyl Gly-Gly-dipetide, and control of their assembly with steric constraints
    Authors:
    W. Bendzińska-Berus, M. Jelecki, M. Kwit, and U. Rychlewska
    Academic press:
    CrystEngComm (rok: 2019, tom: 21, strony: 3420-3430), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/c9ce00429g - link to the publication
  9. Trityl Group as an Crystal Engineering Tool for Construction of Inclusion Compounds and for Suppression of Amide NH···O=C Hydrogen Bonds
    Authors:
    Wioletta Bendzińska-Berus, Beata Warżajtis, Jadwiga Gajewy, Marcin Kwit, and Urszula Rychlewska
    Academic press:
    Crystal Growth & Design (rok: 2017, tom: 17, strony: 2560-2568), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.cgd.7b00105 - link to the publication
  10. Molecular and supramolecular helicity induction in trityl group-containing compunds: the case of chiral 3,3,3-triphenylpropionic acid derivatives
    Authors:
    P. Skowronek, A. Czapik, Z. Rajska, and M. Kwit
    Academic press:
    Tetrahedron (rok: 2019, tom: 75, strony: 4497-4505), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.tet.2019.06.040 - link to the publication

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