Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Synthesis of molecular and macromolecular organometallic compounds via novel synthetic protocols that utilize catalysis by Lewis acids

2015/19/B/ST5/00240

Keywords:

Lewis acids coupling reaction addition reactions allylsilanes allylboranes allylgermanes silsesquioxanes silicon compounds organometallic compounds hybrid materials

Descriptors:

  • ST5_3: Surface modification
  • ST5_18:
  • ST5_24:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet im. Adama Mickiewicza w Poznaniu, Wydział Chemii

woj. wielkopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Grzegorz Hreczycho 

Number of co-investigators in the project: 9

Call: OPUS 10 - announced on 2015-09-15

Amount awarded: 842 800 PLN

Project start date (Y-m-d): 2016-06-14

Project end date (Y-m-d): 2019-12-13

Project duration:: 42 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Chemoodporna pompa olejowa o wysokiej próżni (2 szt.) (26 000 PLN)
  2. Lodówka chemiczna (8 000 PLN)
  3. Pompa membranowa (10 000 PLN)
  4. System do prowadzenia reakcji równoległych (40 000 PLN)
  5. Pompa próżniowa CRV (11 663 PLN)
  6. Mieszadło magnetyczne z elektronicznym termometrem (4 szt.) (16 000 PLN)
  7. Wirówka laboratoryjna (20 000 PLN)
  8. Zestaw komputerowy (10 000 PLN)

Information in the final report

  • Publication in academic press/journals (12)
  • Articles in post-conference publications (8)
  1. Highly Efficient Catalytic Route for the Synthesis of Functionalized Silsesquioxanes
    Authors:
    Joanna Kaźmierczak, Krzysztof Kuciński, Grzegorz Hreczycho
    Academic press:
    Inorganic Chemistry (rok: 2017, tom: 56, strony: 9337-9342), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.7b01504 - link to the publication
  2. O-Metalation of silanols and POSS silanols over Amberlyst-15 catalyst: A facile route to unsymmetrical siloxanes, borasiloxanes and germasiloxanes
    Authors:
    Krzysztof Kuciński, Grzegorz Hreczycho
    Academic press:
    Inorganica Chimica Acta (rok: 2019, tom: 490, strony: 261-266), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.ica.2019.03.025 - link to the publication
  3. Catalyst-Free and Solvent-Free Hydroboration of Aldehydes
    Authors:
    Hanna Stachowiak, Joanna Kaźmierczak, Krzysztof Kuciński, Grzegorz Hreczycho
    Academic press:
    Green Chemistry (rok: 2018, tom: 20, strony: 1738-1742), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C8GC00042E - link to the publication
  4. Catalytic Approach to Germanium-functionalized Silsesquioxanes and Germasilsesquioxanes
    Authors:
    Joanna Kaźmierczak, Grzegorz Hreczycho
    Academic press:
    Organometallics (rok: 2017, tom: 36, strony: 3854−3859), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.organomet.7b00599 - link to the publication
  5. Chemoselective and catalyst-free O-borylation of silanols: a facile access to borasiloxanes
    Authors:
    Krzysztof Kuciński, Grzegorz Hreczycho
    Academic press:
    ChemSusChem (rok: 2017, tom: 10, strony: 4695–4698), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/cssc.201701648 - link to the publication
  6. Copper(II) triflate-mediated synthesis of functionalized silsesquioxanes via dehydrogenative coupling of POSS silanols with hydrosilanes
    Authors:
    Joanna Kaźmierczak, Grzegorz Hreczycho
    Academic press:
    Dalton Transactions (rok: 2019, tom: 48, strony: 6341-6346), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c9dt01135h - link to the publication
  7. Highly Efficient and Chemoselective Tertiary and Secondary Benzylation of Thiols Catalyzed by Indium(III) Triflate
    Authors:
    Krzysztof Kuciński, Grzegorz Hreczycho
    Academic press:
    European Journal of Organic Chemistry (rok: 2017, tom: 1, strony: 5572-5581), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejoc.201701007 - link to the publication
  8. A Highly Effective Route to Si-O-Si Moieties through O-Silylation of Silanols and Polyhedral Oligomeric Silsesquioxane Silanols with Disilazanes
    Authors:
    Krzysztof Kuciński, Grzegorz Hreczycho
    Academic press:
    ChemSusChem (rok: 2019, tom: 12, strony: 1043-1048), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/cssc.201802757 - link to the publication
  9. Catalytic Formation of Silicon-Heteroatom (N, P, O, S) Bonds
    Authors:
    Krzysztof Kuciński; Grzegorz Hreczycho
    Academic press:
    ChemCatChem (rok: 2017, tom: 9, strony: 1868-1885), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/cctc.201700054 - link to the publication
  10. S-Acetylation of thiols mediated by triflic acid: a novel route to thioesters
    Authors:
    Krzysztof Kuciński, Grzegorz Hreczycho
    Academic press:
    Organic Process Research & Development (rok: 2018, tom: 22, strony: 489-493), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.oprd.7b00378 - link to the publication
  11. Introduction of Boron Functionalities into Silsesquioxanes - Novel Independent Methodologies
    Authors:
    Joanna Kaźmierczak, Krzysztof Kuciński, Hanna Stachowiak Grzegorz Hreczycho
    Academic press:
    Chemistry - A European Journal (rok: 2018, tom: 24, strony: 2509-2514), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201705898 - link to the publication
  12. Nafion as effective and selective heterogeneous catalytic system in O-metalation of silanols and POSS silanols
    Authors:
    Joanna Kaźmierczak, Grzegorz Hreczycho
    Academic press:
    Journal of catalysis (rok: 2018, tom: 367, strony: 95-103), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jcat.2018.08.024 - link to the publication
  1. New method for hydroboration of carbonyl compounds in accordance with green chemistry's principles
    Authors:
    Hanna Stachowiak, Grzegorz Hreczycho
    Conference:
    XXXVII Biennial Meeting of the Spanish Royal Society of Chemistry (rok: 2019, ), Wydawca: IUPAC
    Data:
    konferencja 26-30 V 2019
    Status:
    Published
  2. SCANDIUM(III) TRIFLUOROMETHANESULFONATE – AN EFFICIENT LEWIS ACID CATALYST FOR ORGANIC AND ORGANOMETALLOIDAL SYNTHESIS
    Authors:
    Hreczycho Grzegorz, Krzysztof Kuciński, Joanna Kaźmierczak, Hanna Stachowiak, Dariusz Lewandowski
    Conference:
    4th International Conference on the Periodic Table endorsed by IUPAC (rok: 2019, ), Wydawca: IUPAC
    Data:
    konferencja 24-29 VII 2019
    Status:
    Published
  3. THE DEVELOPMENT OF SUSTAINABLE STRATEGIES IN ORGANOMETALLOIDAL SYNTHESIS
    Authors:
    KRZYSZTOF KUCIŃSKI, JOANNA KAŹMIERCZAK, HANNA STACHOWIAK, GRZEGORZ HRECZYCHO
    Conference:
    11th Conference Wasteless Technologies and Waste Management in Industry and Agriculture (rok: 2019, ), Wydawca: West Pomeranian University of Technology, Szczecin
    Data:
    konferencja 11 – 14 VI 2019
    Status:
    Published
  4. Highly efficient catalytic approach to the synthesis of functionalized silsesquioxanes
    Authors:
    Joanna Kaźmierczak, Grzegorz Hreczycho
    Conference:
    XXVIII International Conference on Organometallic Chemistry (rok: 2018, ), Wydawca: -
    Data:
    konferencja 15-20.07
    Status:
    Published
  5. Sustainable Strategies Utilizing Hydroboranes
    Authors:
    Krzysztof Kuciński Grzegorz Hreczycho
    Conference:
    XXXVII Biennial Meeting of the Spanish Royal Society of Chemistry (rok: 2019, ), Wydawca: IUPAC
    Data:
    konferencja 26-30 V 2019
    Status:
    Published
  6. Green Chemistry for Organosilicon and Organoboron Synthesis
    Authors:
    Krzysztof Kuciński
    Conference:
    The 20th General Assembly of the Federation of Asian Chemical Society and The 18th Asian Chemical Congress (rok: 2019, ), Wydawca: -
    Data:
    konferencja 08-12-.12
    Status:
    Published
  7. Metal triflates-mediated synthesis of thioethers
    Authors:
    Krzysztof Kuciński, Grzegorz Hreczycho
    Conference:
    XXII International Conference on Organic Synthesis - 22-ICOS (rok: 2018, ), Wydawca: -
    Data:
    konferencja 16-21.09
    Status:
    Published
  8. NOVEL, EFFICIENT CATALYTIC METHODS FOR FUNCTIONALIZATION OF SILSESQUIOXANES
    Authors:
    Joanna Kaźmierczak, Grzegorz Hreczycho
    Conference:
    French-Polish Chemistry Congress in Paris (rok: 2019, ), Wydawca: -
    Data:
    konferencja 4-6 VII 2019
    Status:
    Published

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