Projects funded by the NCN


Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Unsymmetric difluoroboranes - synthesis, spectral and theoretical studies of new fluorescent probes

2013/09/B/ST5/03550

Keywords:

fluorescence difluoroboranes spectral probes

Descriptors:

  • ST5_23:
  • ST5_9: Biomaterials, biocompatible materials
  • ST4_15: Colloid chemistry

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Technologiczno-Przyrodniczy im. Jana i Jędrzeja Śniadeckich w Bydgoszczy, Wydział Technologii i Inżynierii Chemicznej

woj. kujawsko-pomorskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Borys Ośmiałowski 

Number of co-investigators in the project: 7

Call: OPUS 5 - announced on 2013-03-15

Amount awarded: 627 042 PLN

Project start date (Y-m-d): 2014-03-03

Project end date (Y-m-d): 2017-03-02

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. spektrofluorymetr (130 000 PLN)

Information in the final report

  • Publication in academic press/journals (12)
  1. Photophysical Properties of Phenacylphenantridine Difluoroboranyls: Effect of Substituent and Double Benzannulation
    Authors:
    Anna Maria Grabarz, Beata Jędrzejewska, Anna Zakrzewska, Robert Zaleśny, Adele D. Laurent, Denis Jacquemin, Borys Ośmiałowski
    Academic press:
    J. Org. Chem. (rok: 2017, tom: 82, strony: 1529-1537), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.joc.6b02732 - link to the publication
  2. The Influence of the Nature of the Amino Group in Highly Fluorescent Difluoroborates Exhibiting Intramolecular Charge Transfer
    Authors:
    Beata Jędrzejewska, Agnieszka Skotnicka, Adèle D. Laurent, Marek Pietrzak, Denis Jacquemin, Borys Ośmiałowski
    Academic press:
    Journal or Organic Chemistry , Wydawca: American Chemical Society
    Status:
    Submitted
  3. First-Principles Simulations of One- and Two-Photon Absorption Band Shapes of the Bis(BF2) Core Complex
    Authors:
    Robert Zaleśny, Murugan Natarajan Arul, Guangjun Tian, Miroslav Medved, Hans Ågren
    Academic press:
    J. Phys. Chem. B (rok: 2016, tom: 120, strony: 2323-2332), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpcb.5b09726 - link to the publication
  4. Influence of Substituent and Benzoannulation on Photophysical Properties of 1‐Benzoylmethyleneisoquinoline Difluoroborates
    Authors:
    Borys Ośmiałowski, Anna Zakrzewska, Beata Jędrzejewska, Anna Grabarz, Robert Zaleśny, Wojciech Bartkowiak, Erkki Kolehmainen
    Academic press:
    Journal of Organic Chemistry (rok: 2015, tom: 80, strony: 2072-2080), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jo502244j - link to the publication
  5. Spectral and physicochemical properties of difluoroboranyls containing N,N-dimethylamino group studied by solvatochromic methods
    Authors:
    Beata Jędrzejewska, Anna Grabarz, Wojciech Bartkowiak, Borys Ośmiałowski
    Academic press:
    Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy (rok: 2018, tom: 199, strony: 86-95), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.saa.2018.03.048 - link to the publication
  6. Toward Fully Nonempirical Simulations of Optical Band Shapes of Molecules in Solution: A Case Study of Heterocyclic Ketoimine Difluoroborates
    Authors:
    Robert Zaleśny, N. Arul Murugan, Faris Gel'mukhanov, Zilvinas Rinkevicius, Borys Ośmiałowski, Wojciech Bartkowiak, Hans Ågren
    Academic press:
    Journal of Physical Chemistry A (rok: 2015, tom: 119, strony: 5145-5152), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jp5094417 - link to the publication
  7. Tuning the Electronic Properties of the Dative N-B Bond with Associated O-B Interaction: Electron Localizability Indicator from X-Ray Wavefunction Refinement
    Authors:
    Lilianna Chęcińska, Stefan Mebs, Borys Ośmiałowski, Anna Zakrzewska, Krzysztof Ejsmont, M. Kohout
    Academic press:
    ChemPhysChem (rok: 2016, tom: 17, strony: 2395-2406), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/cphc.201600223 - link to the publication
  8. Collision induced dissociation of N-(pyridin-2-yl)-substituted benzo(thio)amides and N-(isoquinolin-1-yl)furan(thiophene)-2-carboxamides and their difluoroboranyl derivatives
    Authors:
    Małgorzata A. Kaczorowska, Borys Ośmiałowski
    Academic press:
    International Journal of Mass Spectrometry (rok: 2018, tom: 428, strony: 35-42), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.ijms.2018.02.006 - link to the publication
  9. Two-photon absorption of BF2-carrying compounds: insights from theory and experiment
    Authors:
    Joanna Bednarska, Robert Zaleśny, Małgorzata Wielgus, Beata Jędrzejewska, Rakesh Puttreddy, Kari Rissanen, Wojciech Bartkowiak, Hans Agren, Borys Ośmiałowski
    Academic press:
    Phys.Chem.Chem.Phys. (rok: 2017, tom: 19, strony: 5705-5708), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c7cp00063d - link to the publication
  10. Synthesis and photophysical properties of novel donor-acceptor N-(pirydyn-2-yl) substituted benzo(thio)amides and their difluoroboranyl derivatives
    Authors:
    Beata Jędrzejewska, Šimon Budzák, Małgorzata A. Kaczorowska, Anna Zakrzewska, Karina Mroczyńska, Grzegorz Mlostoń, Anna Maria Grabarz, Denis Jacquemin, Borys Ośmiałowski
    Academic press:
    J. Phys. Chem. A (rok: 2016, tom: 120, strony: 4116-4123), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpca.6b04004 - link to the publication
  11. The influence of the π-conjugated spacer on photophysical properties of difluoroboranyls derived from amides carrying donor group
    Authors:
    Anna Maria Grabarz, Adèle D. Laurent, Beata Jędrzejewska, Anna Zakrzewska, Denis Jacquemin, Borys Ośmiałowski
    Academic press:
    J. Org. Chem. (rok: 2016, tom: 81, strony: 2280-2292), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.joc.5b02691 - link to the publication
  12. Difluoroboranyl Derivatives as Efficient Panchromatic Photoinitiators in Radical Polymerization Reactions
    Authors:
    Beata Jędrzejewska, Borys Ośmiałowski
    Academic press:
    Polymer Bulletin (rok: 2017, tom: brak, strony: brak), Wydawca: Springer
    Status:
    Accepted for publication
    DOI:
    10.1007/s00289-017-2201-1 - link to the publication