Projects funded by the NCN


Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Synthesis and application of novel chiral triazolium salts derived from terpenes, as N-heterocyclic carbene precatalysts (NHC) for asymmetric synthesis

2011/03/D/ST5/05626

Keywords:

N-Heterocylic carbenes organocatalysis monoterpenes triazolium salts

Descriptors:

  • ST5_23:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Mikołaja Kopernika, Wydział Chemii

woj. kujawsko-pomorskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Zbigniew Rafiński 

Number of co-investigators in the project: 2

Call: SONATA 2 - announced on 2011-09-15

Amount awarded: 565 000 PLN

Project start date (Y-m-d): 2012-08-29

Project end date (Y-m-d): 2015-08-28

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. pompa próźniowa (17 000 PLN)
  2. mieszadła magnetyczne z czujnikiem temperatury (14 000 PLN)
  3. mikrodestylarka Kugelrohr.
  4. Komora typu Dry-box (87 000 PLN)
  5. pompa strzykawkowa (4 000 PLN)
  6. waga analityczna (7 000 PLN)
  7. pompa membranowa + wyparka (20 000 PLN)

Information in the final report

  • Publication in academic press/journals (5)
  1. Enantioselective Synthesis of Chromanones Bearing Quaternary Substituted Stereocenters Catalyzed by (1R)-Camphor-Derived N-Heterocyclic Carbenes
    Authors:
    Zbigniew Rafiński, Anna Kozakiewicz
    Academic press:
    The Journal of Organic Chemistry (rok: 2015, tom: 80, strony: 7468-7476), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.joc.5b01029 - link to the publication
  2. Highly efficient synthesis of spirocyclic (1R)-camphor-derived triazolium salts: application in the catalytic asymmetric benzoin condensation
    Authors:
    Zbigniew Rafiński, Anna Kozakiewicz, Katarzyna Rafińska
    Academic press:
    Tetrahedron (rok: 2014, tom: 70, strony: 5739-5745), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.tet.2014.06.066 - link to the publication
  3. A Novel (‒)-β-Pinene-derived Triazolium Salts - Synthesis and Application in Asymmetric Stetter Reaction
    Authors:
    Zbigniew Rafiński
    Academic press:
    ChemCatChem (rok: 2016, ), Wydawca: Wiley
    Status:
    Accepted for publication
    DOI:
    10.1002/cctc.201600498 - link to the publication
  4. (–)-β-Pinene-Derived N-Heterocyclic Carbenes (NHCs): Application to Highly Enantioselective Intramolecular Stetter Reaction
    Authors:
    Zbigniew Rafiński, Anna Kozakiewicz, Katarzyna Rafińska
    Academic press:
    ACS Catalysis (rok: 2014, tom: 4, strony: 1404-1408), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/cs500207d - link to the publication
  5. Enantioselective benzoin condensation catalyzed by spirocyclic terpene-based N-heterocyclic carbenes
    Authors:
    Zbigniew Rafiński
    Academic press:
    Tetrahedron (rok: 2016, tom: 72, strony: 1860-1867), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.tet.2016.02.049 - link to the publication