Projects funded by the NCN


Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Exploration of low-temperature conformational landscapes using diode lasers and matrix-isolation technique.

2011/01/B/ST4/00718

Keywords:

matrix isolation infrared spectroscopy conformer diode laser tunneling

Descriptors:

  • ST4_3: Molecular architecture and structure
  • ST4_4: Theoretical and computational chemistry
  • ST4_17: Chemical reactions: mechanisms, thermodynamics, kinetics

Panel:

ST4 - Chemistry: physical chemistry/chemical physics, theoretical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, method development

Host institution :

Instytut Fizyki PAN

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Leszek Łapiński 

Number of co-investigators in the project: 4

Call: OPUS 1 - announced on 2011-03-15

Amount awarded: 193 310 PLN

Project start date (Y-m-d): 2011-12-20

Project end date (Y-m-d): 2014-12-19

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. przestrajalny laser diodowy na zakres 1400 - 1500 nm i układ pomiarowy, w którego skład wchodzi laser diodowy (85 500 PLN)

Information in the final report

  • Publication in academic press/journals (8)
  1. "Tunable diode lasers as a tool for conformational control: the case of matrix-isolated oxamic acid"
    Authors:
    A. Halasa, L. Lapinski, H. Rostkowska, I. Reva, M.J. Nowak
    Academic press:
    Journal of Physical Chemistry A (rok: 2015, tom: 119, strony: 2203 - 2210), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jp501448m - link to the publication
  2. "Conformational transformation in squaric acid induced by near-IR laser light"
    Authors:
    L. Lapinski, I. Reva, H. Rostkowska, A. Halasa, R. Fausto, M.J. Nowak
    Academic press:
    Journal of Physical Chemistry A (rok: 2013, tom: 117, strony: 5251-5259), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jp402128g - link to the publication
  3. "Hydrogen atom transfer reactions in thiophenol: photogeneration of two new thione isomers"
    Authors:
    I. Reva, M.J. Nowak, L. Lapinski, R. Fausto
    Academic press:
    Physical Chemistry Chemical Physics (rok: 2015, tom: 17, strony: 4888 - 4898), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C4CP04125A - link to the publication
  4. "Near-IR-induced, UV-induced and spontaneous isomerizations in 5-methylcytosine and 5-fluorocytosine"
    Authors:
    L. Lapinski, I. Reva, H. Rostkowska, R. Fausto, M.J. Nowak
    Academic press:
    Journal of Physical Chemistry B (rok: 2014, tom: 118, strony: 2831 - 2841), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jp411423c - link to the publication
  5. "Near-infrared laser-induced generation of three rare conformers of glycolic acid"
    Authors:
    A. Halasa, L. Lapinski, I. Reva, H. Rostkowska, R. Fausto, M.J. Nowak
    Academic press:
    Journal of Physical Chemistry A (rok: 2014, tom: 118, strony: 5626 - 5635), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jp5051589 - link to the publication
  6. "Photochemical isomerizations of thiosemicarbazide, a matrix isolation study"
    Authors:
    H. Rostkowska, L. Lapinski, B. Kozankiewicz, M.J. Nowak
    Academic press:
    Journal of Physical Chemistry A (rok: 2012, tom: 116, strony: 9863-9871), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jp305995k - link to the publication
  7. "Three Conformers of 2-Furoic Acid. Structure Changes Induced with Near-IR Laser Light."
    Authors:
    A. Halasa, L. Lapinski, I. Reva, H. Rostkowska, R. Fausto, M.J. Nowak
    Academic press:
    Journal of Physical Chemistry A (rok: 2015, tom: 119, strony: 1037 - 1047), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jp512302s - link to the publication
  8. "NIR-laser generation of a high-energy conformer of L-alanine and the mechanism of its decay in a low-temperature nitrogen matrix"
    Authors:
    C.M. Nunes, L. Lapinski, R. Fausto, I. Reva
    Academic press:
    Journal of Chemical Physics (rok: 2013, tom: 138, strony: 125101), Wydawca: American Institute of Physics
    Status:
    Published
    DOI:
    10.1063/1.4795823 - link to the publication