Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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In the marches of sulfur and fluorine - new strategies of formation of the CC and CF bonds

2018/31/B/ST5/01118

Keywords:

organic synthesis olefination fluorine compounds sulfur compounds catalysis

Descriptors:

  • ST5_23:
  • ST5_18:
  • ST5_20:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Warszawski, Wydział Chemii

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Michał Barbasiewicz 

Number of co-investigators in the project: 8

Call: OPUS 16 - announced on 2018-09-14

Amount awarded: 1 659 700 PLN

Project start date (Y-m-d): 2019-07-01

Project end date (Y-m-d): 2023-06-30

Project duration:: 48 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Sprzęt komputerowy, urządzenia peryferyjne, oprogramowanie (20 000 PLN)
  2. Waga laboratoryjna (8 000 PLN)
  3. Wyparka rotacyjna (30 000 PLN)
  4. Zasłona z pleksi (2 000 PLN)
  5. Linia próżniowo-argonowa (10 000 PLN)

Information in the final report

  • Publication in academic press/journals (7)
  1. Alkylation of Nitropyridines via Vicarious Nucleophilic Substitution
    Authors:
    Damian Antoniak and Michał Barbasiewicz*
    Academic press:
    Organic Letters (rok: 2022, tom: 24, strony: 516-519), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.orglett.1c03920 - link to the publication
  2. Enantioselective Addition of Dialkyl Malonates to β-Arylethenesulfonyl Fluorides under High-Pressure Conditions
    Authors:
    Michał Kopyt, Michał Tryniszewski, Michał Barbasiewicz* and Piotr Kwiatkowski*
    Academic press:
    Organic Letters (rok: 2023, tom: 25, strony: 6818-6822), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.orglett.3c02302 - link to the publication
  3. Olefination with Sulfonyl Halides and Esters: Synthesis of Unsaturated Sulfonyl Fluorides
    Authors:
    Michał Tryniszewski, Dariusz Basiak, and Michał Barbasiewicz*
    Academic press:
    Oragnic Letters (rok: 2022, tom: 24, strony: 4270-4274), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.orglett.2c01604 - link to the publication
  4. Olefination with sulfonyl halides and esters – sulfur-based variant of the Horner-Wadsworth-Emmons reaction
    Authors:
    Dariusz Basiak and Michał Barbasiewicz
    Academic press:
    Arkivoc (rok: 2021, tom: part (ii), strony: 118-135), Wydawca: ARKAT USA, Inc.
    Status:
    Published
    DOI:
    10.24820/ark.5550190.p011.385 - link to the publication
  5. Olefination with sulfonyl halides and esters: Mechanistic DFT & experimental studies, and comparison with reactivity of phosphonates
    Authors:
    Tymoteusz Basak,* Jan Nowak, Michał Tryniszewski, Bartosz Trzaskowski, Michał Barbasiewicz*
    Academic press:
    Phosphorus, Sulfur, Silicon and Related Elements , Wydawca: Taylor & Francis
    Status:
    Submitted
    DOI:
    brak - link to the publication
  6. Gram-Scale Preparation of Acyl Fluorides and Their Reactions with Hindered Nucleophiles
    Authors:
    Michał Tryniszewski, Michał Barbasiewicz*
    Academic press:
    Synthesis (rok: 2022, tom: 54, strony: 1446-1460), Wydawca: Thieme Chemistry
    Status:
    Published
    DOI:
    10.1055/a-1649-5460 - link to the publication
  7. Are β-Lactones Involved in Carbon-Based Olefination Reactions?
    Authors:
    Jan Nowak, Michał Tryniszewski, Michał Barbasiewicz*
    Academic press:
    Synlett (rok: 2024, tom: 35, strony: accepted article), Wydawca: Thieme Chemistry
    Status:
    Published
    DOI:
    10.1055/a-2268-4386 - link to the publication

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