Generation of strong photoluminescence and strong magnetic anisotropy through desolvation and further post-synthetic functionalization of novel d-f coordination networks

2018/29/B/ST5/00337

Keywords

Descriptors

  • ST5_14: Chemia koordynacyjna
  • ST5_9: Materiały do konstrukcji sensorów
  • ST5_2: Materiały o strukturze ciała stałego

Panel

ST5 – Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution

Uniwersytet Jagielloński, Wydział Chemii

Voivodeship: małopolskie

Other projects carried out by the institution »

Principal investigator (from the host institution)

dr hab. Szymon Chorąży

Number of co-investigators in the project: 6

Call

OPUS 15 – announced on 2018-03-15

Amount awarded
1 877 120 PLN
Project start date
2019-01-24
Project end date
2022-04-23
Project duration
39 months (the same as in the proposal)
Project status
Project settled

Project description

Download the project description in a pdf file

Note — project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Dysk zewnętrzny. Cost: 529 PLN
  2. Kriostat helowy do pomiarów optycznych. Cost: 340 000 PLN
  3. Termograwimetr TGA/DTA do analizy termograwimetrycznej (TGA) oraz różnicowej analizy termicznej (DTA). Cost: 290 000 PLN

Information in the final report

Publication in academic press/journals (13)

  1. Dehydration-Hydration Switching of Single-Molecule Magnet Behavior and Visible Photoluminescence in a Cyanido-Bridged DyIIICoIII Framework

    Authors:
    Yue Xin, Junhao Wang, Mikolaj Zychowicz, Jakub J. Zakrzewski, Koji Nakabayashi, Barbara Sieklucka, Szymon Chorazy, Shin-ichi Ohkoshi
    Academic press:
    Journal of the American Chemical Society (year: 2019, volume: 141, pages: 18211-18220), Publisher: American Chemical Society (ACS) Publications
    Status:
    Published
    DOI:
    10.1021/jacs.9b09103 – link to the publication
  2. Neutral dicyanidoferrate(II) metalloligands for the rational design of dysprosium(III) single-molecule magnets

    Authors:
    Michal Liberka, Mikolaj Zychowicz, Wiktor Zychowicz, Szymon Chorazy
    Academic press:
    Chemical Communications (year: 2022, volume: 58, pages: 6381-6384), Publisher: Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/d2cc02238a – link to the publication
  3. Holmium(III) molecular nanomagnets for optical thermometry exploring the luminescence re-absorption effect

    Authors:
    Junhao Wang, Jakub J. Zakrzewski, Mikolaj Zychowicz, Veacheslav Vieru, Liviu F. Chibotaru, Koji Nakabayashi, Szymon Chorazy, Shin-ichi Ohkoshi
    Academic press:
    Chemical Science (year: 2021, volume: 12, pages: 730-741), Publisher: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D0SC04871B – link to the publication
  4. Reversible Humidity-Driven Transformation of a Bimetallic {EuCo} Molecular Material: Structural, Sorption, and Photoluminescence Studies

    Authors:
    Jakub J. Zakrzewski, Michal Heczko, Robert Jankowski, Szymon Chorazy
    Academic press:
    Molecules (year: 2021, volume: 26, pages: 1-15 (artykuł nr 1102)), Publisher: MDPI (Multidisciplinary Digital Publishing Institute)
    Status:
    Published
    DOI:
    10.3390/molecules26041102 – link to the publication
  5. Photoluminescent Lanthanide(III) Single-Molecule Magnets in Three-Dimensional Polycyanidocuprate(I)-Based Frameworks

    Authors:
    Jakub J. Zakrzewski, Szymon Chorazy, Koji Nakabayashi, Shin-ichi Ohkoshi, Barbara Sieklucka
    Academic press:
    Chemistry - A European Journal (year: 2019, volume: 25, pages: 11820-11825), Publisher: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/chem.201902420 – link to the publication
  6. Diverse physical functionalities of rare-earth hexacyanidometallate frameworks and their molecular analogues

    Authors:
    Jakub J. Zakrzewski, Michal Liberka, Mikolaj Zychowicz, Szymon Chorazy
    Academic press:
    Inorganic Chemisty Frontiers (year: 2021, volume: 8, pages: 452-483), Publisher: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D0QI01197E – link to the publication
  7. Europium(III) Photoluminescence Governed by d8-d10 Heterometallophilic Interactions in Trimetallic Cyanido-Bridged Coordination Frameworks

    Authors:
    Jakub J. Zakrzewski, Barbara Sieklucka, Szymon Chorazy
    Academic press:
    Inorganic Chemistry (year: 2020, volume: 59, pages: 1393-1404), Publisher: American Chemical Society (ACS) Publications
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem9b03114 – link to the publication
  8. Proton Conductive Luminescent Thermometer Based on Near-Infrared Emissive {YbCo2} Molecular Nanomagnets

    Authors:
    Junhao Wang, Jakub J. Zakrzewski, Michal Heczko, Mikolaj Zychowicz, Kosuke Nakagawa, Koji Nakabayashi, Barbara Sieklucka, Szymon Chorazy, Shin-ichi Ohkoshi
    Academic press:
    Journal of the American Chemical Society (year: 2020, volume: 142, pages: 3970-3979), Publisher: American Chemical Society (ACS) Publications
    Status:
    Published
    DOI:
    10.1021/jacs.9b13147 – link to the publication
  9. Near-infrared emissive Er(III) and Yb(III) molecular nanomagnets in metal-organic chains functionalized by octacyanidometallates(IV)

    Authors:
    Robert Jankowski, Jakub J. Zakrzewski, Olga Surma, Shin-ichi Ohkoshi, Szymon Chorazy, Barbara Sieklucka
    Academic press:
    Inorganic Chemistry Frontiers (year: 2019, volume: 6, pages: 2423-2434), Publisher: Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/c9qi00583h – link to the publication
  10. Tunable magnetic anisotropy in luminescent cyanido-bridged {Dy2Pt3} molecules incorporating heteroligand PtIV linkers

    Authors:
    Agnieszka Puzan, Mikolaj Zychowicz, Junhao Wang, Jakub J. Zakrzewski, Mateusz Reczyński, Shin-ichi Ohkoshi, Szymon Chorazy
    Academic press:
    Dalton Transactions (year: 2021, volume: 50, pages: 16242-16253), Publisher: Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/d1dt03071j – link to the publication
  11. Near-Infrared Emissive Cyanido-Bridged {YbFe2} Molecular Nanomagnets Sensitive to the Nitrile Solvents of Crystallization

    Authors:
    Michal Liberka, Kseniia Boidachenko, Jakub J. Zakrzewski, Mikolaj Zychowicz, Junhao Wang, Shin-ichi Ohkoshi, Szymon Chorazy
    Academic press:
    Magnetochemistry (year: 2021, volume: 7, pages: 1-20 (numer artykułu 79)), Publisher: MDPI (Multidisciplinary Digital Publishing Institute)
    Status:
    Published
    DOI:
    10.3390/magnetochemistry7060079 – link to the publication
  12. Effect of Noble Metals on Luminescence and Single-Molecule Magnet Behavior in the Cyanido-Bridged Ln-Ag and Ln-Au (Ln = Dy, Yb, Er) Complexes

    Authors:
    Kunal Kumar, Olaf Stefańczyk, Szymon Chorazy, Koji Nakabayashi, Barbara Sieklucka, Shin-ichi Ohkoshi
    Academic press:
    Inorganic Chemistry (year: 2019, volume: 58, pages: 5677-5687), Publisher: American Chemical Society (ACS) Publications
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.8b03634 – link to the publication
  13. Metal-cyanido molecular modulators of the sensing range and performance in lanthanide-based luminescent thermometers

    Authors:
    Maciej Wyczesany, Jakub J. Zakrzewski, Barbara Sieklucka, Szymon Chorazy
    Status:
    Accepted for publication

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Graphic design and implementation: Jakub Piotrowski