Synthesis of ruthenium complexes bearing CAAC ligands and their use in metathesis reactions

2017/27/B/ST5/02563

Keywords

Descriptors

  • ST5_18: Kataliza homogeniczna i heterogeniczna
  • ST5_23: Chemia organiczna
  • ST5_24: Chemia nieorganiczna

Panel

ST5 – Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution

Uniwersytet Warszawski, Centrum Nauk Biologiczno-Chemicznych

Voivodeship: mazowieckie

Other projects carried out by the institution »

Principal investigator (from the host institution)

dr hab. Anna Kajetanowicz

Number of co-investigators in the project: 3

Call

OPUS 14 – announced on 2017-09-15

Amount awarded
746 600 PLN
Project start date
2018-07-31
Project end date
2022-02-27
Project duration
43 months (the same as in the proposal)
Project status
Project settled

Project description

Download the project description in a pdf file

Note — project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Pompa próżniowa rotacyjna łopatkowa z miernikiem próżni. Cost: 20 000 PLN
  2. komputer stacjonarny Dell.
  3. monitor Dell.

Information in the final report

Publication in academic press/journals (4)

  1. Aza-Claisen rearrangement as a key step in synthesis of specialised anilines used in the production of efficient ethenolysis catalysts

    Authors:
    Adrian Sytniczuk, Filip Struzik, Vishal Purohit, Karol Grela, Anna Kajetanowicz
    Academic press:
    Catalysis Science&Technology (year: 2023, volume: 13, pages: 3682-3688), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d3cy00395g – link to the publication
  2. A tunable family of CAAC-ruthenium olefin metathesis catalysts modularly derived from a large-scale produced ibuprofen intermediate

    Authors:
    Adrian Sytniczuk, Filip Struzik, Karol Grela, Anna Kajetanowicz
    Academic press:
    Chemical Science (year: 2023, volume: 14, pages: 10744-10755), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d3sc03849a – link to the publication
  3. Non‐Glovebox Ethenolysis of Ethyl Oleate and FAME at Larger Scale Utilizing a Cyclic (Alkyl)(Amino)Carbene Ruthenium Catalyst

    Authors:
    Kajetanowicz, A.; Chwalba, M.; Gawin, A.; Tracz, A.; Grela, K.
    Academic press:
    European Journal of Lipid Science and Technology (year: 2020, volume: 122 (1), pages: 1900263), Publisher: Wiley
    Status:
    Published
    DOI:
    10.1002/ejlt.201900263 – link to the publication
  4. Inverted cyclic(alkyl)(amino)carbene ligands allow olefin metathesis with ethylene at parts-per-billion catalyst loading

    Authors:
    Adrian Sytniczuk, Anna Kajetanowicz, Karol Grela
    Academic press:
    Chem Catalysis (year: 2023, volume: 3, pages: 100713), Publisher: Cell Press
    Status:
    Published
    DOI:
    10.1016/j.checat.2023.100713 – link to the publication

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Graphic design and implementation: Jakub Piotrowski