Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Heterometallic cyanido-bridged coordination networks as magnetic molecular switches

2017/27/B/ST5/00947

Keywords:

polycyanidometallate complexes coordination networks molecular magnetism molecular switchable materials smart molecules

Descriptors:

  • ST5_12: Methods of nanomaterials/materials synthesis
  • ST5_14: Other related subjects
  • ST5_2: Solid-state materials

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Jagielloński, Wydział Chemii

woj. małopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Barbara Sieklucka 

Number of co-investigators in the project: 9

Call: OPUS 14 - announced on 2017-09-15

Amount awarded: 1 711 600 PLN

Project start date (Y-m-d): 2018-07-13

Project end date (Y-m-d): 2021-09-12

Project duration:: 38 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Kriostat do monokrystalicznego dyfraktometru rentgenowskiego (205 000 PLN)
  2. Proszkowy dyfraktometr rentgenowski (500 000 PLN)
  3. Dysk zewnętrzny 6TB (679 PLN)
  4. Fotopowielacz z rozszerzonym zakresem detekcji do 980 nm z wyposażeniem.

Information in the final report

  • Publication in academic press/journals (11)
  1. The rationalized pathway from single-ion to single-chain magnet governed by the 5d-metal oxidation state in cobalt-octacyanidotungstate chains
    Authors:
    Tomasz Charytanowicz, Robert Jankowski, Mikolaj Zychowicz, Szymon Chorazy, Barbara Sieklucka
    Academic press:
    Inorganic Chemistry Frontiers , Wydawca: The Royal Society of Chemistry
    Status:
    Submitted
    DOI:
    brak - link to the publication
  2. In Situ Ligand Transformation for Two-Step Spin Crossover in FeII[MIV(CN)8]4- (M = Mo, Nb) Cyanido-Bridged Frameworks
    Authors:
    Shintaro Kawabata, Szymon Chorazy, Jakub J. Zakrzewski, Kenta Imoto, Takashi Fujimoto, Koji Nakabayashi, Jan Stanek, Barbara Sieklucka, Shin-ichi Ohkoshi
    Academic press:
    Inorganic Chemistry (rok: 2019, tom: 58, strony: 6052-6063), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.9b00361 - link to the publication
  3. SHG-active NIR-emissive molecular nanomagnets generated in layered neodymium(III)-octacyanidometallate(IV) frameworks
    Authors:
    Robert Jankowski, Jakub J. Zakrzewski, Mikolaj Zychowicz, Junhao Wang, Yurie Oki, Shin-ichi Ohkoshi, Szymon Chorazy, Barbara Sieklucka
    Academic press:
    Journal of Materials Chemistry C (rok: 2021, tom: 9, strony: 10705-10717), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d1tc00825k - link to the publication
  4. Guest-Dependent Pressure-Induced Spin Crossover in FeII4[MIV(CN)8]2 (M = Mo, W) Cluster-Based Material Showing Persistent Solvent-Driven Structural Transformations
    Authors:
    Robert Jankowski, Mateusz Reczyński, Szymon Chorazy, Mikołaj Zychowicz, Mirosław Arczyński, Marcin Kozieł, Karolina Ogorzały, Wacław Makowski, Dawid Pinkowicz, Barbara Sieklucka
    Academic press:
    Chemistry-A European Journal (rok: 2020, tom: 26, strony: 11187-11198), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/chem.202000146 - link to the publication
  5. Humidity driven molecular switch based on photoluminescent DyIIICoIII single-molecule magnets
    Authors:
    Szymon Chorazy, Jakub J. Zakrzewski, Mateusz Reczyński, Koji Nakabayashi, Shin-ichi Ohkoshi, Barbara Sieklucka
    Academic press:
    Journal of Materials Chemistry C (rok: 2019, tom: 7, strony: 4164-4172), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c8tc06630b - link to the publication
  6. Octacyanidorhenate(V) Ion as an Efficient Linker for Hysteretic Two-Step Iron(II) Spin Crossover Switchable by Temperature, Light, and Pressure
    Authors:
    Szymon Chorazy, Tomasz Charytanowicz, Dawid Pinkowicz, Junhao Wang, Koji Nakabayashi, Stephen Klimke, Franz Renz, Shin-ichi Ohkoshi, Barbara Sieklucka
    Academic press:
    Angewandte Chemie International Edition (rok: 2020, tom: 59, strony: 15741-15749), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/anie.202007327 - link to the publication
  7. Proton-Conducting Humidity-Sensitive NiII-NbIV Magnetic Coordination Network
    Authors:
    Mateusz Reczyński, Michał Heczko, Marcin Kozieł, Shin-ichi Ohkoshi, Barbara Sieklucka, Beata Nowicka
    Academic press:
    Inorganic Chemistry (rok: 2019, tom: 58, strony: 15812-15823), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.9b02141 - link to the publication
  8. The ON-OFF switching of thermal spin crossover by interstitial solvent exchange in a layered ReV-CN-FeII coordination framework
    Authors:
    Tomasz Charytanowicz, Jakub J. Zakrzewski, Katarzyna Dziedzic-Kocurek, Szymon Chorazy, Barbara Sieklucka
    Academic press:
    Journal of Applied Physics (rok: 2021, tom: 129, strony: 143902(1-10)), Wydawca: AIP Publishing
    Status:
    Published
    DOI:
    10.1063/5.0046296 - link to the publication
  9. Chiral Photomagnets Based on Copper(II) complexes of 1,2-Diaminocyclohexane and Octacyanidomolybdate(IV) Ions
    Authors:
    Tomasz Korzeniak, Sujit Sasmal, Dawid Pinkowicz, Wojciech Nitek, Robert Pełka, Dominik Czernia, Olaf Stefańczyk, Barbara Sieklucka
    Academic press:
    Inorganic Chemistry (rok: 2020, tom: 59, strony: 5872-5882), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.9b03511 - link to the publication
  10. Connecting Visible Photoluminescence and Slow Magnetic Relaxation in Dysprosium(III) Octacyanidorhenate(V) Helices
    Authors:
    Szymon Chorazy, Tomasz Charytanowicz, Anna M. Majcher, Mateusz Reczyński, Barbara Sieklucka
    Academic press:
    Inorganic Chemistry (rok: 2018, tom: 57, strony: 14039-14043), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.8b02674 - link to the publication
  11. Octacyanidometallates for multifunctional molecule-based materials
    Authors:
    Szymon Chorazy, Jakub J. Zakrzewski, Michał Magott, Tomasz Korzeniak, Beata Nowicka, Dawid Pinkowicz, Robert Podgajny, Barbara Sieklucka
    Academic press:
    Chemical Society Reviews (rok: 2020, tom: 49, strony: 5945-6001), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D0CS00067A - link to the publication

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