Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Quantum nanomagnets based on metal complexes with unusual geometries and using new unusual ligands

2016/22/E/ST5/00055

Keywords:

nanomaganetism organometallics magnetic relaxation molecular crystals

Descriptors:

  • ST5_12: Methods of nanomaterials/materials synthesis
  • ST5_14: Other related subjects
  • ST5_17:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Jagielloński, Wydział Chemii

woj. małopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Dawid Pinkowicz 

Number of co-investigators in the project: 5

Call: SONATA BIS 6 - announced on 2016-06-15

Amount awarded: 1 497 483 PLN

Project start date (Y-m-d): 2017-04-13

Project end date (Y-m-d): 2022-04-12

Project duration:: 60 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Zakrzywiony monochromator krystaliczny do rentgenowskiego dyfraktometru monokrystalicznego (145 000 PLN)
  2. Indukcyjne mieszadło magnetyczne 1.
  3. Pompa próżniowa do komory rękawicowej.
  4. Dwustopniowa rotacyjna pompa próżniowa do linii Schlenka (11 700 PLN)
  5. System oczyszczania rozpuszczlaników w atmosferze gazu obojętnego (160 110 PLN)
  6. Waga analityczna do gloveboxa (3 300 PLN)
  7. Indukcyjne mieszadło magnetyczne 2.
  8. Komora rękawicowa do pracy w warunkach beztlenowych i bezwodnych (290 890 PLN)

Information in the final report

  • Publication in academic press/journals (25)
  1. Cyanide vs. azide ''magnetic arm wrestling'': MnII–NbIV and MnII–MoIV magnetic coordination polymers with mixed bridging
    Authors:
    Gabriela Handzlik, Marcin Kozieł, Anna Olejniczak, Barbara Sieklucka, Dawid Pinkowicz
    Academic press:
    Chemical Communications (rok: 2017, tom: 53, strony: 9753-9756), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c7cc05319c - link to the publication
  2. Iron(II) spin crossover (SCO) materials based on dipyridyl-N-alkylamine
    Authors:
    Taous Houari, Emmelyne Cuza, Dawid Pinkowicz, Mathieu Marchivie, Said Yefsah, Smail Triki
    Academic press:
    Crystals (rok: 2018, tom: 8, strony: 401), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/cryst8110401 - link to the publication
  3. Photoinduced Mo-CN Bond Breakage in Octacyanomolybdate Leading to Spin Triplet Trapping
    Authors:
    Xinghui Qi, Sebastien Pillet, Coen de Graaf, Michał Magott, El-Eulmi Bendeif, Philippe Guionneau, Mathieu Rouzieres, Valerie Marvaud, Olaf Stefańczyk, Dawid Pinkowicz, Corine Mathoniere
    Academic press:
    Angewante Chemie International Edition (rok: 2020, tom: 59, strony: 45297), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/anie.201914527 - link to the publication
  4. Site-Selective Photoswitching of Two Distinct Magnetic Chromophores in a Propeller-Like Molecule To Achieve Four Different Magnetic States
    Authors:
    Mirosław Arczyński, Jan Stanek, Barbara Sieklucka, Kim R. Dunbar, Dawid Pinkowicz
    Academic press:
    Journal of the American Chemical Society (rok: 2019, tom: 141, strony: 19067-19077), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/jacs.9b09576 - link to the publication
  5. 1,2,5-Thiadiazole 1,1-dioxides and Their Radical Anions: Structure, Properties, Reactivity, and Potential Use in the Construction of Functional Molecular Materials
    Authors:
    Paweł Pakulski, Dawid Pinkowicz
    Academic press:
    Molecules (rok: 2021, tom: 26, strony: 4873), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules26164873 - link to the publication
  6. A photomagnetic sponge: high-temperature light-induced ferrimagnet controlled by water sorption
    Authors:
    Michał Magott, Mateusz Reczyński, Bartłomiej Gaweł, Barbara Sieklucka, Dawid Pinkowicz
    Academic press:
    Journal of the American Chemical Society (rok: 2018, tom: 140, strony: 15876-15882), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jacs.8b09322 - link to the publication
  7. Heterotrimetallic Cyanide-Bridged 3d-4d-5d Frameworks Based on a Photomagnetic Secondary Building Unit
    Authors:
    Michał Magott, Marcin Sarewicz, Szymon Buda, Dawid Pinkowicz
    Academic press:
    Inorganic Chemisry (rok: 2020, tom: 59, strony: 8925-8934), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c00737 - link to the publication
  8. Low-Coordinate Dinuclear Dysprosium (III) Single Molecule Magnets Utilizing LiCl as Bridging Moieties and Tris (amido) amine as Blocking Ligands
    Authors:
    Maria Brzozowska, Gabriela Handzlik, Mikolaj Zychowicz, Dawid Pinkowicz
    Academic press:
    Magnetochemistry (rok: 2021, tom: 7, strony: 125), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/magnetochemistry7090125 - link to the publication
  9. Magnetization Dynamics and Coherent Spin Manipulation of a Propeller Gd(III) Complex with the Smallest Helicene Ligand
    Authors:
    Gabriela Handzlik, Michał Magott, Mirosław Arczyński, Alena M. Sheveleva, Floriana Tuna, Marcin Sarewicz, Artur Osyczka, Michał Rams, Veacheslav Vieru, Liviu F. Chibotaru, Dawid Pinkowicz
    Academic press:
    Journal of Physical Chemistry Letters (rok: 2020, tom: 11, strony: 1508-1515), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpclett.9b03275 - link to the publication
  10. The photomagnetic effect in 2-D cyanido-bridgedcoordination polymer [Cu(aepa)]10[Mo(CN)8]5.30H2O
    Authors:
    Tomasz Korzeniak, Sujit Sasmal, Dawid Pinkowicz, Barbara Sieklucka
    Academic press:
    New Journal of Chemistry (rok: 2018, tom: 42, strony: 17009-17015), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C8NJ02952K - link to the publication
  11. A new look at molecular and electronic structure of homoleptic diiron (II, II) complexes with N, N‐bidentate ligands: Combined experimental and theoretical study
    Authors:
    Krzesimir Korona, Michał Terlecki, Iwona Justyniak, Michał Magott, Jan Żukrowski, Arkadiusz Kornowicz, Dawid Pinkowicz, Adam Kubas, Janusz Lewinski
    Academic press:
    Chemistry–A European Journal (rok: 2022, tom: online, strony: online), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.202200620 - link to the publication
  12. Correlating magnetic anisotropy with [Mo(CN)7]4− geometry of MnII–MoIII magnetic frameworks
    Authors:
    Michał Magott, Kim R. Dunbar, Dawid Pinkowicz
    Academic press:
    Dalton Transactions (rok: 2019, tom: 48, strony: 15493-15500), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/c9dt02164g - link to the publication
  13. Cross-linking of cyanide magnetic coordination polymers by rational insertion of formate, cyanide or azide
    Authors:
    Gabriela Handzlik, Barbara Sieklucka, Dawid Pinkowicz
    Academic press:
    Dalton Transactions (rok: 2018, tom: 47, strony: 11888-11894), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C8DT01513A - link to the publication
  14. Identical anomalous Raman relaxation exponent in a family of single ion magnets: towards reliable Raman relaxation determination?
    Authors:
    Gabriela Handzlik, Michał Magott, Mirosław Arczyński, Alena M. Sheveleva, Floriana Tuna, Stanisław Baran, Dawid Pinkowicz
    Academic press:
    Dalton Transactions (rok: 2020, tom: 49, strony: 11942-11949), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d0dt02439b - link to the publication
  15. Large breathing effect induced by water sorption in a remarkably stable nonporous cyanide-bridged coordination polymer
    Authors:
    Michał Magott, Bartłomiej Gaweł, Marcin Sarewicz, Mateusz Reczyński, Karolina Ogorzały, Wacław Makowski, Dawid Pinkowicz
    Academic press:
    Chemical Science (rok: 2021, tom: 12, strony: 9176-9188), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D1SC02060A - link to the publication
  16. Molecular realizations of 3D Heisenberg magnet: Critical scaling
    Authors:
    Robert Pełka, Dawid Pinkowicz, Barbara Sieklucka, Magdalena Fitta
    Academic press:
    Journal of Alloys and Compounds (rok: 2018, tom: 765, strony: 520-526), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jallcom.2018.06.171 - link to the publication
  17. Reversible Single-Crystal-to-Single-Crystal Transformation in Photomagnetic Cyanido-Bridged Cd4M2 Octahedral Molecules
    Authors:
    Tomasz Korzeniak, Robert Jankowski, Marcin Kozieł, Dawid Pinkowicz, Barbara Sieklucka
    Academic press:
    Inorganic Chemistry (rok: 2017, tom: 56, strony: 12914-12919), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.7b01708 - link to the publication
  18. An intermetallic molecular nanomagnet with the lanthanide coordinated only by transition metals
    Authors:
    Michał Magott, Maria Brzozowska, Stanisław Baran, Veacheslav Vieru, Dawid Pinkowicz
    Academic press:
    Nature Communications (rok: 2022, tom: 13, strony: 2014), Wydawca: Springer Nature
    Status:
    Published
    DOI:
    10.1038/s41467-022-29624-7 - link to the publication
  19. Bis(triphenylphosphine)iminium Salts of Dioxothiadiazole Radical Anions: Preparation, Crystal Structures, and Magnetic Properties
    Authors:
    PAweł Pakulski, Mirosław Arczyński, Dawid Pinkowicz
    Academic press:
    Crystals (rok: 2019, tom: 9, strony: 30), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/cryst9010030 - link to the publication
  20. How to Make a Better Magnet? Insertion of Additional Bridging Ligands into a Magnetic Coordination Polymer
    Authors:
    Gabriela Handzlik, Dawid Pinkowicz
    Academic press:
    Magnetochemistry (rok: 2018, tom: 4, strony: 41), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/magnetochemistry4030041 - link to the publication
  21. How to Quench Ferromagnetic Ordering in a CN-Bridged Ni(II)-Nb(IV) Molecular Magnet? A Combined High-Pressure Single-Crystal X-Ray Diffraction and Magnetic Study
    Authors:
    Gabriela Handzlik, Barbara Sieklucka, Hanna Tomkowiak, Andrzej Katrusiak, Dawid Pinkowicz
    Academic press:
    Magnetochemistry (rok: 2019, tom: 5, strony: 33), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/magnetochemistry5020033 - link to the publication
  22. Influence of the Increasing Number of Organic Radicals on the Structural, Magnetic, and Electrochemical Properties of the Copper(II)–Dioxothiadiazole Family of Complexes
    Authors:
    Mirosław Arczyński, Dawid Pinkowicz
    Academic press:
    Inorganic Chemistry (rok: 2020, tom: 59, strony: 13489-13501), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c01904 - link to the publication
  23. Light‐Induced Spin‐State Switching of the MoIV Centre in Trinuclear [CuII(diamine)2]2[MoIV(CN)8] Molecules
    Authors:
    Tomasz Korzeniak, Sujit Sasmal, Dawid Pinkowicz, Olaf Stefańczyk, Barbara Sieklucka
    Academic press:
    European Journal of Inorganic Chemistry (rok: 2018, tom: 2018, strony: 2019-2025), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejic.201800138 - link to the publication
  24. Pseudo-tetrahedral vs. pseudo-octahedral ErIII single molecule magnets and the disruptive role of coordinated TEMPO radical
    Authors:
    Maria Brzozowska, Gabriela Handzlik, Katarzyna Kurpiewska, Mikołaj Zychowicz, Dawid Pinkowicz
    Academic press:
    Inorganic Chemistry Frontiers (rok: 2021, tom: 8, strony: 2817-2828), Wydawca: Royal Society of Chemistry (RSC)
    Status:
    Published
    DOI:
    10.1039/D1QI00262G - link to the publication
  25. Syntheses, crystal structures and magnetic properties of a series of ZnII2LnIII2 compounds (Ln = Gd, Tb, Dy, Ho and Er): contrasting structural and magnetic features
    Authors:
    Sagar Ghosh, Nairita Hari, Dawid Pinkowicz, Magdalena Fitta, Sasankasekhar Mohanta
    Academic press:
    New Journal of Chemistry (rok: 2018, tom: 42, strony: 15917-15929), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C8NJ02532K - link to the publication

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