Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Non-classical asymetric catalysis effected by hydrogen-bond donors

2016/22/E/ST5/00046

Keywords:

C-H activation hydrogen bonding squaramides asymmetric synthesis catalysis

Descriptors:

  • ST5_23:
  • ST5_18:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Politechnika Wrocławska

woj. dolnośląskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Rafał Kowalczyk 

Number of co-investigators in the project: 11

Call: SONATA BIS 6 - announced on 2016-06-15

Amount awarded: 1 304 481 PLN

Project start date (Y-m-d): 2017-04-12

Project end date (Y-m-d): 2022-12-11

Project duration:: 68 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Młyn kulowy (37 900 PLN)
  2. waga półanalityczna.
  3. waga analityczna.
  4. chromatograf HPLC z autosamplerem (303 021 PLN)

Information in the final report

  • Publication in academic press/journals (8)
  1. Trans -1,2-Diaminocyclohexane-based sulfonamides as effective hydrogen-bonding organocatalysts for asymmetric Michael-hemiacetalization reaction"
    Authors:
    Dajek, Maciej, Kowalczyk, Rafał, Boratyński, Przemysław, J.
    Academic press:
    Catalysis Science and Technology (rok: 2018, tom: 8, strony: 4358-4363), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/C8CY01199K - link to the publication
  2. Cinchona Squaramide-Catalyzed Intermolecular Desymmetrization of 1,3-Diketones Leading to Chiral 1,4- Dihydropyridines
    Authors:
    Maciej Dajek, Agnieszka Pruszczyńska, Krzysztof A. Konieczny, Rafał Kowalczyk
    Academic press:
    Advanced Synthesis and Catalysis (rok: 2020, tom: 362, strony: 3613-3620), Wydawca: Wiley-VCH GmbH, Weinheim
    Status:
    Published
    DOI:
    10.1002/adsc.202000455 - link to the publication
  3. Efficacy of Selenourea Organocatalysts in Asymmetric Michael Reactions under Standard and Solvent-Free Conditions
    Authors:
    Mariola Zielińska-Błajet, Żaneta A. Mała, Rafał Kowalczyk
    Academic press:
    Molecules (rok: 2021, tom: 26, strony: 7303), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules - link to the publication
  4. Stereoselectivity Enhancement During the Generation of Three Contiguous Stereocenters in Tetrahydrothiophenes
    Authors:
    Żaneta A. Mała, Mikołaj J. Janicki, Natalia H. Niedźwiecka Robert W. Góra, Krzysztof A. Konieczny, Rafał Kowalczyk
    Academic press:
    ChemCatChem (rok: 2021, tom: 13, strony: 574-580), Wydawca: Wiley-VCH GmbH, Weinheim
    Status:
    Published
    DOI:
    10.1002/cctc.202001583 - link to the publication
  5. Hydrogen Bonding Template Enables Remote meta-C-H Alkenylation of Nitroarenes
    Authors:
    Dutta , Bishal ; Mahajan, Mayank; Ghosh, Animesh ; Dajek, Maciej; Kowalczyk, Rafał; Mondal, Bhaskar; Ge, Haibo; Maiti, Debabrata
    Academic press:
    Journal of the American Chemical Society , Wydawca: American Chemical Society
    Status:
    Submitted
    DOI:
    brak - link to the publication
  6. Applications of Thermal Activation, Ball-milling and Aqueous Medium in Stereoselective Michael Addition of Nitromethane to En-ynones Catalyzed by Chiral Squaramides
    Authors:
    Żaneta A. Ignatiuk, Mikołaj J. Janicki, Robert W. Góra, Krzysztof Konieczny, Rafał Kowalczyk
    Academic press:
    Advanced Synthesis and Catalysis (rok: 2019, tom: 361, strony: 1108-1116), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/adsc.201801498 - link to the publication
  7. Mechanochemical Assisted Chemoselective and Stereoselective Hydrogen-Bonding Catalyzed Addition of Dithiomalonates to Enones
    Authors:
    Żaneta A. Mała, Mikołaj J. Janicki, Robert W. Góra, Krzysztof A. Konieczny, Rafał Kowalczyka
    Academic press:
    Advanced Synthesis and Catalysis (rok: 2023, tom: 365, strony: 3342-3352), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/adsc.202300636 - link to the publication
  8. Betaketothioesters in Organocatalysis: Harnessing Nucleophilic Reactivity, the Fluorophobic Effect, and Expanding the Substrate Repertoire
    Authors:
    Maciej Dajek, Paulina D. Kubiak, Julia Bąkowicz, Błażej Dziuk, Rafał Kowalczyk
    Academic press:
    Chem Catalysis , Wydawca: Cell Press
    Status:
    Submitted
    DOI:
    brak - link to the publication

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