Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Exploration of directed transition-metal-catalyzed C-H activation reaction of nitro-substituted arenes and olefins accompanied by further transformation of manipulable nitro group

2015/19/D/ST5/02774

Keywords:

Directed C-H bond functionalization nitro group transition-metal catalysis heterocyclization transformation of the nitro group nitro-substituted arenes and olefins.

Descriptors:

  • ST5_18:
  • ST5_23:
  • ST4_12: Photochemistry

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Centrum Badań Molekularnych i Makromolekularnych Polskiej Akademii Nauk

woj. łódzkie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Viktor Iaroshenko 

Number of co-investigators in the project: 3

Call: SONATA 10 - announced on 2015-09-15

Amount awarded: 698 800 PLN

Project start date (Y-m-d): 2016-08-04

Project end date (Y-m-d): 2019-08-03

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Cylinder do systemu oczyszczania rozpuszczalników SPS-800 MBraun (6 800 PLN)
  2. Laptop Acer Aspire.
  3. Płyty grzejne z regulowaną temperaturą grzania do fiolek reakcyjnych z mieszadłem magnetycznym (3 szt.) (21 000 PLN)
  4. Mieszadło magnetyczne 2 szt.
  5. Wyparka próżniowa (25 000 PLN)
  6. Skaner Canon.
  7. Sprzęt komputerowy.
  8. Laptop z odpowiednim oprogramowaniem (14 000 PLN)
  9. Próżniowa pompa membranowa z kontrolerem próżni (30 000 PLN)
  10. Kolumna filtracyjna do THF kompatybilna do systemu oczyszczania rozpuszczalników SPS-800 MBraun (2 szt.) (14 000 PLN)

Information in the final report

  • Publication in academic press/journals (3)
  1. Application of Silicon-Initiated Water Splitting for the Reduction of Organic Substrates
    Authors:
    Ashot Gevorgyan, Satenik Mkrtchyan, Tatevik Grigoryan, Viktor O. Iaroshenko.*
    Academic press:
    ChemPlusChem (rok: 2018, tom: 83, strony: 375 – 382), Wydawca: Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
    Status:
    Published
    DOI:
    10.1002/cplu.201800131 - link to the publication
  2. Copper-catalyzed direct C-H arylselenation of 4-nitro-pyrazoles and other heterocycles with selenium powder and aryl iodides. Access to unsymmetrical heteroaryl selenides.
    Authors:
    Michał Jakubczyk, Satenik Mkrtchyan,* Izabela D. Madura, Paulina H. Marek, Viktor O. Iaroshenko.*
    Academic press:
    RSC Advances (rok: 2019, tom: 9, strony: 25368–25376), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c9ra05004c - link to the publication
  3. Disilanes as Oxygen Scavengers and Surrogates of Hydrosilanes Suitable for Selective Reduction of Nitroarenes, Phosphine Oxides and other Valuable Substrates
    Authors:
    Ashot Gevorgyan, Satenik Mkrtchyan, Tatevik Grigoryan, Viktor O. Iaroshenko.*
    Academic press:
    Org. Chem. Front. (rok: 2017, tom: 4, strony: 2437–2444), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C7QO00566K - link to the publication

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