Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Searching for proton-conducting MOFs with mechanochemical approach

2015/17/B/ST5/01190

Keywords:

metal-organic frameworks coordination polymer mechanochemistry proton conduction post-synthetic modification

Descriptors:

  • ST5_14: Other related subjects
  • ST5_12: Methods of nanomaterials/materials synthesis
  • ST5_24:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Jagielloński, Wydział Chemii

woj. małopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Dariusz Matoga 

Number of co-investigators in the project: 10

Call: OPUS 9 - announced on 2015-03-16

Amount awarded: 1 150 000 PLN

Project start date (Y-m-d): 2016-02-11

Project end date (Y-m-d): 2021-02-10

Project duration:: 60 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Analizator impedancji.
  2. Dyfraktometr rentgenowski proszkowy (450 000 PLN)
  3. Komora klimatyczna (40 000 PLN)
  4. Młyn kulowy (35 000 PLN)
  5. Wielofunkcyjny zestaw reakcyjny (25 000 PLN)
  6. Spektometr FT-IR z przystawką ATR (150 000 PLN)

Information in the final report

  • Publication in academic press/journals (12)
  1. Collective breathing in an eightfold interpenetrated metal-organic framework: from mechanistic understanding towards threshold sensing architectures
    Authors:
    Kornel Roztocki, Filip Formalik, Anna Krawczuk, Irena Senkovska, Bogdan Kuchta, Stefan Kaskel, Dariusz Matoga
    Academic press:
    Angewandte Chemie, International Edition (rok: 2020, tom: 59, strony: 4491-4497), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/anie.201914198 - link to the publication
  2. Crystalline bilayers unzipped and rezipped: solid-state reaction cycle of a metal-organic framework with triple rearrangement of intralayer bonds
    Authors:
    Dariusz Matoga, Kornel Roztocki, Manuel Wilke, Franziska Emmerling, Marcin Oszajca, Magdalena Fitta, Maria Bałanda
    Academic press:
    CrystEngComm (rok: 2017, tom: 19, strony: 2987-2995), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C7CE00655A - link to the publication
  3. Introducing a Longer versus Shorter Acylhydrazone Linker to a Metal–Organic Framework: Parallel Mechanochemical Approach, Nonisoreticular Structures, and Diverse Properties
    Authors:
    Kornel Roztocki, Monika Szufla, Maciej Hodorowicz, Irena Senkovska, Stefan Kaskel, Dariusz Matoga
    Academic press:
    Crystal Growth & Design (rok: 2019, tom: 19, strony: 7160-7169), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.cgd.9b01031 - link to the publication
  4. Ladder-chain zinc coordination polymers based on adipic acid dihydrazide precursor: Synthesis and structural transformations
    Authors:
    Piotr Zabierowski, Marcin Oszajca, Maciej Hodorowicz, Dariusz Matoga
    Academic press:
    Polyhedron (rok: 2017, tom: 121, strony: 25-32), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.poly.2016.09.053 - link to the publication
  5. Interlinker hydrogen bonds govern CO2 adsorption in a series of flexible 2D diacylhydrazone/isophthalate-based MOFs: influence of metal center, linker substituent and activation temperature
    Authors:
    Kornel Roztocki, Monika Szufla, Volodymyr Bon, Irena Senkovska, Stefan Kaskel, Dariusz Matoga
    Academic press:
    Inorganic Chemistry (rok: 2020, tom: 59, strony: 10717-10726), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.0c01182 - link to the publication
  6. Water-stable metal-organic framework with three hydrogen-bond acceptors: versatile theoretical and experimental insights into adsorption ability and thermo-hydrolytic stability
    Authors:
    Kornel Roztocki, Magdalena Lupa, Andrzej Sławek, Wacław Makowski, Irena Senkovska, Stefan Kaskel, Dariusz Matoga
    Academic press:
    Inorganic Chemistry (rok: 2018, tom: 57, strony: 3287-3296), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.8b00078 - link to the publication
  7. Isophthalate−Hydrazone 2D Zinc−Organic Framework: Crystal Structure, Selective Adsorption, and Tuning of Mechanochemical Synthetic Conditions
    Authors:
    Kornel Roztocki, Damian Jędrzejowski, Maciej Hodorowicz, Irena Senkovska, Stefan Kaskel, Dariusz Matoga
    Academic press:
    Inorganic Chemistry (rok: 2016, tom: 55, strony: 9663-9670), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.6b01405 - link to the publication
  8. One-step introduction of terminal sulfonic groups into a proton-conducting metal-organic framework by concerted deprotonation-metalation-hydrolysis reaction
    Authors:
    Monika Szufla, Kornel Roztocki, Anna Krawczuk, Dariusz Matoga
    Academic press:
    Dalton Transactions (rok: 2020, tom: 49, strony: 9953-9956), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d0dt02017f - link to the publication
  9. Bulky substituent and solvent-induced alternative nodes for layered Cd-isophthalate/acylhydrazone frameworks
    Authors:
    Kornel Roztocki, Magdalena Lupa, Maciej Hodorowicz, Irena Senkovska, Stefan Kaskel, Dariusz Matoga
    Academic press:
    CrystEngComm (rok: 2018, tom: 20, strony: 2841-2849), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c8ce00269j - link to the publication
  10. Effect of linker substituent on layers arrangement, stability and sorption of Zn-isophthalate/acylhydrazone-frameworks
    Authors:
    Kornel Roztocki, Damian Jędrzejowski, Maciej Hodorowicz, Irena Senkovska, Stefan Kaskel, Dariusz Matoga
    Academic press:
    Crystal Growth & Design (rok: 2018, tom: 18, strony: 488-497), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.cgd.7b01468 - link to the publication
  11. Electronic Devices Using Open Framework Materials
    Authors:
    Mark D. Allendorf, Renhao Dong, Xinliang Feng, Stefan Kaskel, Dariusz Matoga, Vitalie Stavila
    Academic press:
    Chemical Reviews (rok: 2020, tom: 120, strony: 8581-8640), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.chemrev.0c00033 - link to the publication
  12. Trojan horse thiocyanate: induction and control of high proton conductivity in CPO-27/MOF-74 metal-organic frameworks by metal selection and solvent-free mechanochemical dosing
    Authors:
    Magdalena Lupa, Paweł Kozyra, Gabriela Jajko, Dariusz Matoga
    Academic press:
    ACS Applied Materials and Interfaces (rok: 2021, tom: 13, strony: 29820-29826), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acsami.1c06346 - link to the publication

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