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Synthesis and physicochemical properties of lanthanide complexes with heterocyclic ligands and their application for spectral and energetic transformation of femtosecond light impulses

2014/15/B/ST5/04730

Keywords

Descriptors

  • ST5_8: Nowe materiały: tlenki, stopy, kompozyty, hybrydy organiczno-nieorganiczne, nadprzewodniki
  • ST4_3: Metody spektroskopowe i spektrometryczne

Panel

ST5 – Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution

Instytut Niskich Temperatur i Badań Strukturalnych im. Włodzimierza Trzebiatowskiego PAN

Voivodeship: dolnośląskie

Other projects carried out by the institution »

Principal investigator (from the host institution)

prof. Jerzy Kazimierz Hanuza

Number of co-investigators in the project: 8

Call

OPUS 8 – announced on 2014-09-15

Amount awarded
596 640 PLN
Project start date
2015-07-10
Project end date
2019-06-09
Project duration
47 months (the same as in the proposal)
Project status
Project settled

Equipment purchased [PL]

  1. Fourierowski spektrometr na podczerwień z automatycznym polaryzatorem na zakres 10 – 12.000 cm-1. Cost: 160 000 PLN
  2. Przystawka ATR do spektrometru FT-IR. Cost: 60 000 PLN
  3. Stanowisko do hodowli metodą solwotermalną (reaktor mikrofalowy, komputer PC, naczynie reakcyjne, pompka wodna). Cost: 35 000 PLN

Information in the final report

Publication in academic press/journals (14)

  1. Conformation of the azo bond and its influence on the molecular and crystal structure, IR and Raman spectra, and electron properties of 6-methyl-3,5-dinitro-2-[(E)-phenyldiazenyl]pyridine – quantum chemical DFT calculations

    Authors:
    J. Michalski, I. Bryndal, J. Lorenc, K. Hermanowicz, J. Janczak, J. Hanuza
    Academic press:
    Spectrochimica Acta A (year: 2018, volume: 191, pages: 521-531), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.saa.2017.10.053 – link to the publication

  2. Molecular structure and vibrational spectra of quercetin and quercetin-5'-sulfonic acid

    Authors:
    J. Hanuza, P. Godlewska, E. Kucharska, M. Ptak, M. Kopacz, M. Mączka, K. Hermanowicz, L. Macalik
    Academic press:
    Vibrational Spectroscopy (year: 2017, volume: 88, pages: 94-105), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.vibspec.2016.11.007 – link to the publication

  3. Crystallographic and spectroscopic studies as well as DFT quantum chemical calculations of hydrazo-bond conformation in 4,4'-dimethyl-3,3',5,5'-tetranitro-2,2'-hydrazobipyridine

    Authors:
    E. Kucharska, I. Bryndal, T. Lis, K. Hermanowicz, J. Hanuza
    Academic press:
    Journal of Molecular Stucture (year: 2018, volume: 1173, pages: 750-762), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.molstruc.2018.07.040 – link to the publication

  4. Molecular structure and vibrational properties of pyramidal MPc+ phthalocyanine cation in InPcI and LuPc(OAc) complexes

    Authors:
    J. Hanuza, P. Godlewska, P. Kadłubański, M. Ptak, M. Mączka, Y.S. Gerasymchuk, J. Legendziewicz
    Academic press:
    Journal of Molecular Structure (year: 2017, volume: 1130, pages: 699-710), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.molstruc.2016.11.013 – link to the publication

  5. Spectral and energetic transformation of femtosecond light impulses in the Eu3+ complex with dehydroacetic acid

    Authors:
    J. Hanuza, M. Ptak, R. Lisiecki, J. Janczak, A. Kwocz, E. Kucharska, S. Roszak, W. Ryba- Romanowski, M. Mączka, K. Hermanowicz, L. Macalik
    Academic press:
    Journal of Luminescence (year: 2018, volume: 198, pages: 471-481), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jlumin.2018.02.067 – link to the publication

  6. Spectroscopic investigation and DFT modelling studies of Eu3+ complex with 1-(2,6-dihydroxyphenyl)ethanone

    Authors:
    J. Hanuza, M. Ptak, R. Lisiecki, A. Kwocz, E. Kucharska, W. Ryba-Romanowski, M. Mączka, K. Hermanowicz, L. Macalik
    Academic press:
    Spectrochimica Acta A (year: 2018, volume: 200, pages: 322-329), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.saa.2018.04.035 – link to the publication

  7. Spectroscopic properties of Eu3+ complex with 2-hydroxy-4-metoxy-benzophenone – IR, Raman, DFT calculations and femtosecond laser excited luminescence

    Authors:
    J. Hanuza, M. Ptak, R. Lisiecki, A. Kwocz, E. Kucharska, W. Ryba-Romanowski, M. Mączka, K. Hermanowicz, L. Macalik
    Academic press:
    Journal of Luminescence (year: 2017, volume: 190, pages: 371-378), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jlumin.2017.05.082 – link to the publication

  8. DFT study of electron absorption and emission spectra of pyramidal LnPc(OAc) complexes of some lanthanide ions in the solid state

    Authors:
    J. Hanuza, P. Godlewska, R. Lisiecki, W. Ryba-Romanowski, P. Kadłubański, J. Lorenc, A. Łukowiak, L. Macalik, Yu. Gerasymchuk, J. Legendziewicz
    Academic press:
    Spectrochimica Acta A (year: 2018, volume: 196, pages: 202-208), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.saa.2018.01.003 – link to the publication

  9. Molecular structure and spectroscopic properties of new neodymium complex with 3- bromo-2-chloro-6-picolinic N-oxide showing the ligand-to-metal energy transfer

    Authors:
    L. Macalik, M. Wandas, W. Sąsiadek, J. Lorenc, R. Lisiecki, J. Hanuza
    Academic press:
    Journal of Molecular Structure (year: 2020, volume: 1223, pages: 128967.1-128967.11), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.molstruc.2020.128967 – link to the publication

  10. Crystal structure, vibrational and optic properties of 2-N-methylamino-3-methylpyridine N-oxide - its X-ray and spectroscopic studies as well as DFT quantum chemical calculations

    Authors:
    I. Bryndal, J. Lorenc, L. Macalik, J. Michalski, W. Sąsiadek, T. Lis, J. Hanuza
    Academic press:
    Journal of Molecular Structure (year: 2019, volume: 1195, pages: 208-219), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.molstruc.2019.05.064 – link to the publication

  11. Optical and magnetic properties of neodymium(III) six-coordinate complexes of 2,6-lutidine N-oxide derivatives

    Authors:
    P. Godlewska, L. Macalik, J. Lorenc, R. Lisiecki, W. Ryba-Romanowski, J. Hanuza, S.M. Kaczmarek, H. Fuks, G. Leniec
    Academic press:
    Journal of Solid State Chemistry (year: 2019, volume: 276, pages: 294-301), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jssc.2019.05.018 – link to the publication

  12. Optical and magnetic properties of lanthanide(III) complexes with quercetin-5'-sulfonic acid in the solid state and silica glass

    Authors:
    P. Godlewska, J. Hanuza, E. Kucharska, P. Solarz, S. Roszak, S.M. Kaczmarek, G. Leniec, M. Ptak, M. Kopacz, K. Hermanowicz
    Academic press:
    Journal of Molecular Structure (year: 2020, volume: 1219, pages: 128504.1-128504.13), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.molstruc.2020.128504 – link to the publication

  13. Optical properties of terbium(III) and gadolinium(III) complexes with 2 hydroxy 5 methyl 3 nicotinic and 5 methyl 3 nicotinic acids - a new sensitive ligands for energy transfer process

    Authors:
    P. Godlewska, J. Hanuza, K. Hermanowicz, R. Lisiecki, J. Lorenc, W. Ryba-Romanowski, E. Kucharska, M. Ptak, L. Macalik
    Academic press:
    Optical Materials (year: 2020, volume: 109, pages: 110208.1- 110208.7), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.optmat.2020.110208 – link to the publication

  14. Optical studies of Pr(PAN)3, Gd(PAN)3 and Gd0.99Ln0.01(PAN)3 complexes where PAN = 1-(2-pyridylazo)-2-naphthol and Ln = Eu, Sm, Tb, Nd, Yb

    Authors:
    E. Kucharska, K. Hermanowicz, P. Solarz, M. Ptak, J. Hanuza, W. Ryba-Romanowski, P. Drożdżewski
    Academic press:
    Polyhedron (year: 2020, volume: 184, pages: 114558.1-114558.10), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.poly.2020.114558 – link to the publication

Articles in post-conference publications (4)

  1. Abstract Book - Optical, dielectric and magnetic properties of lanthanide(III) complexes with quercetin-5'-sulfonic acid in the solid state and silica glass

    Authors:
    J. Hanuza, E. Kucharska, S.M. Kaczmarek, G. Leniec, M. Ptak, M. Kopacz, M. Mączka, K. Hermanowicz, B. Macalik, L. Macalik
    Conference:
    The 5th International Conference on Rare Earth Materials - REMAT 2018 (year: 2018, pages: P21), Publisher: INTech Transfer Technology Centre, Wrocław, Poland
    Date:
    conference 16 - 18.05
    Status:
    Published

  2. Abstract Book - Spectroscopic investigations and DFT modelling studies of Eu3+ complex with 1-(2,6-dihydroxyphenyl)ethanone

    Authors:
    J. Hanuza, M. Ptak, R. Lisiecki, E. Kucharska, W. Ryba-Romanowski, K. Hermanowicz, L. Macalik
    Conference:
    XIVth International Conference on Molecular Spectroscopy (ICMS'2017) (year: 2017, pages: T4:P-7 str. 274), Publisher: AGH University of Science and Technology, Kraków, Poland
    Date:
    conference 03-07.09
    Status:
    Published

  3. Abstract Book - Structure and optical properties of 3-bromo-4-methylthio-2,6-lutidine n-oxide and its europium(III) and terbium(III) complexes

    Authors:
    I. Bryndal, J. Hanuza, P. Godlewska, R Lisiecki, J. Janczak, J. Lorenc, J. Cieplik
    Conference:
    61 Konwersatorium Krystalograficzne (Polish Crystallographic Meeting) (year: 2019, pages: B-31), Publisher: INTiBS PAN Wrocław oraz Komitet Krystalografii PAN, Wrocław, Poland
    Date:
    conference 26-28.06
    Status:
    Published

  4. Lectures and Communications Abstracts - Structural and spectroscopic properties of terbium complex with thiosemicarbazone

    Authors:
    J. Hanuza, M. Pyrkosz-Bulska, G.J. Małecki, K. Hermanowicz, P. Solarz, L. Macalik
    Conference:
    The 8th International Solid State Chemistry Conference (ISSCC 2017) (year: 2017, pages: PC:104), Publisher: Tunisian Chemical Society, Monastir, Tunisia
    Date:
    conference 17-20.12
    Status:
    Published

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