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Rhodium and Platinum complexes with ionic liquids as ligands - new catalysts for hydrosilylation processes

2014/15/B/ST5/04257

Keywords

Descriptors

  • ST5_7: Ciecze jonowe
  • ST5_18: Kataliza homogeniczna i heterogeniczna
  • ST5_24: Chemia nieorganiczna

Panel

ST5 – Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution

Uniwersytet im. Adama Mickiewicza w Poznaniu, Wydział Chemii

Voivodeship: wielkopolskie

Other projects carried out by the institution »

Principal investigator (from the host institution)

prof. Hieronim Franciszek Maciejewski

Number of co-investigators in the project: 6

Call

OPUS 8 – announced on 2014-09-15

Amount awarded
1 077 630 PLN
Project start date
2015-08-07
Project end date
2019-08-06
Project duration
48 months (the same as in the proposal)
Project status
Project settled

Equipment purchased [PL]

  1. Chromatograf Gazowy. Cost: 175 000 PLN
  2. Rotacyjna wyparka próżniowa. Cost: 25 000 PLN

Information in the final report

Publication in academic press/journals (10)

  1. New anionic rhodium complexes as catalysts for the reduction of acetophenone and its derivatives

    Authors:
    Olga Bartlewicz, Magdalena Jankowska-Wajda, Hieronim Maciejewski
    Academic press:
    RSC Advances (year: 2019, volume: 9, pages: 711-720), Publisher: ROYAL SOC CHEMISTRY
    Status:
    Published
    DOI:
    10.1039/c8ra08954j – link to the publication

  2. Versatile Method for the Simultaneous Synthesis of Two Ionic Liquids, Otherwise Difficult to Obtain, with High Atom Economy

    Authors:
    Andrea Szpecht, Adrian Zając, Dawid Zieliński, Hieronim Maciejewski, Marcin Śmiglak
    Academic press:
    ChemistryOpen (year: 2019, volume: 8, pages: 972-983), Publisher: WILEY-V C H VERLAG GMBH
    Status:
    Published
    DOI:
    10.1002/open.201900217 – link to the publication

  3. Platinum and rhodium complexes lioated by imidazolium-substituted phosphine as the efficient and recyclable catalysts for hydrosilylation

    Authors:
    Magdalena Jankowska-Wajda, Olga Bartlewicz, Andrea Szpecht, Adrian Zając, Marcin Śmiglak, Hieronim Maciejewski
    Academic press:
    RSC Advances (year: 2019, volume: 9, pages: 29396 - 29404), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c9ra05948b – link to the publication

  4. Highly efficient hydrosilylation catalysts based on chloroplatinate ionic liquids

    Authors:
    Magdalena Jankowska-Wajda, Olga Bartlewicz, Anna Walczak, Artur R. Stefankiewicz, Hieronim Maciejewski
    Academic press:
    Journal of Catalysis (year: 2019, volume: 374, pages: 266-275), Publisher: Elsevier Inc.
    Status:
    Published
    DOI:
    10.1016/j.jcat.2019.05.005 – link to the publication

  5. A recyclable Ru(CO)Cl(H)(PPh3)3/PEG catalytic system for regio- and stereoselective hydroboration of terminal and internal alkynes

    Authors:
    Jakub Szyling, Adrian Franczyk, Kinga Stefanowska, Jędrzej Walkowiak
    Academic press:
    Advanced Synthesis & Catalysis (year: 2018, volume: 360, pages: 2966-2974), Publisher: WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
    Status:
    Published
    DOI:
    10.1002/adsc.201800409 – link to the publication

  6. An efficient method for synthesizing monofunctionalized derivatives of 1,1, 3,3-tetramethyldisiloxane in ionic liquids as recoverable solvents for rhodium catalyst

    Authors:
    Rafał Kukawkaa, Rafał Januszewski, Ireneusz Kownacki, Marcin Śmiglak, Hieronim Maciejewski
    Academic press:
    Catalysis Communications (year: 2018, volume: 108, pages: 59-63), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.catcom.2018.01.021 – link to the publication

  7. Recyclable Hydroboration of Alkynes Using RuH@IL and RuH@IL/ scCO2 Catalytic Systems

    Authors:
    Jakub Szyling, Adrian Franczyk, Kinga Stefanowska, Hieronim Maciejewski, Jędrzej Walkowiak
    Academic press:
    ACS Sustainable Chemistry & Engineering (year: 2018, volume: 6, pages: 10980-10988), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acssuschemeng.8b02388 – link to the publication

  8. Optimization and intensification of hydrosilylation reactions using a microreactor system

    Authors:
    Anna Pawłowska-Zygarowicz, Rafał Kukawka, Hieronim Maciejewski, Marcin Śmiglak
    Academic press:
    New Journal of Chemistry (year: 2018, volume: 42, pages: 15332-15339), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c8nj01167b – link to the publication

  9. The effect of the morpholinium ionic liquid anion on the catalytic activity of Rh (or Pt) complex–ionic liquid systems in hydrosilylation processes

    Authors:
    Magdalena Jankowska-Wajda, Izabela Dąbek, Ryszard Fiedorow, Hieronim Maciejewski
    Academic press:
    RSC Advances (year: 2018, volume: 8, pages: 26922-26927), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c8ra05251d – link to the publication

  10. The effect of the catalyst and the type of ionic liquid on the hydrosilylation process under batch and continuous reaction conditions

    Authors:
    Magdalena Jankowska-Wajda, Rafał Kukawka, Marcin Śmiglak, Hieronim Maciejewski
    Academic press:
    New Journal of Chemisty (year: 2018, volume: 42, pages: 5229-5236), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c7nj04396a – link to the publication

Articles in post-conference publications (22)

  1. Syntheses, Structures, and Application of an Ionic Platinum and Rhodium Complexes

    Authors:
    Magdalena Jankowska – Wajda , Olga Wolna , Hieronim Maciejewski
    Conference:
    EuCheMS International Organometallic Conference XXII (year: 2017, pages: 262), Publisher: University of Amsterdam
    Date:
    conference 9-13.07
    Status:
    Published

  2. Synteza efektywnych katalizatorów hydrosililowania w oparciu o reakcje kompleksów Rh i Pt z cieczami jonowymi

    Authors:
    Hieronim Maciejewski, Magdalena Jankowska-Wajda, Olga Wolna
    Conference:
    61 Zjazd Naukowy Polskiego Towarzystwa Chemicznego (year: 2018, pages: S06-4), Publisher: Polskie Towarzystwo Chemiczne
    Date:
    conference 17-21.09
    Status:
    Published

  3. New unsaturated nitrogen cation-based ionic liquids -synthesis and characterization

    Authors:
    Andera Szpecht, Adrian Zając, Marcin Śmiglak, Hieronim Maciejewski
    Conference:
    27th EuChemS Conference on Molten Salts and Ionic Liquids (year: 2018, pages: 163 PP-057), Publisher: CCB – Centro Cultural de Belém
    Date:
    conference 7-12.10
    Status:
    Published

  4. Synthesis of new platinum and rhodium complexes on-containing ionic liquids and determination of their structures

    Authors:
    Magdalena Jankowska-Wajda, Artur Stefankiewicz, Hieronim Maciejewski
    Conference:
    2nd Advances in Green Chemistry Conference (year: 2018, pages: 91 (P_025)), Publisher: Poznan Science and Technology Park, Adam Mickiewicz University Foundation
    Date:
    conference 16-19.04
    Status:
    Published

  5. Supported Ionic Liquid Catalysts as efficient tool for hydrosilylation reaction

    Authors:
    Rafal Kukawka, Anna Pawlowska-Zygarowicz, Joanna Działkowska, Hieronim Maciejewski, Katharina Schroder, Marcin Śmiglak
    Conference:
    2nd Advances in Green Chemistry Conference (year: 2018, pages: 90 (P_024)), Publisher: Poznan Science and Technology Park, Adam Mickiewicz University Foundation
    Date:
    conference 16-19.04
    Status:
    Published

  6. Ionic Liquids in the Synthesis of Ligands for Transition Metal-Based Catalysts

    Authors:
    Adrian Zając, Andrea Szpecht, Olga Stolarska, Sandra Rutecka, Magdalena Jankowska- Wajda, Marcin Śmiglak, Hieronim Maciejewski
    Conference:
    2nd Advances in Green Chemistry Conference (year: 2018, pages: 94 (P_029)), Publisher: Poznan Science and Technology Park, Adam Mickiewicz University Foundation
    Date:
    conference 16-19.04
    Status:
    Published

  7. Anionic platinum complexes as highly efficient catalysts for the hydrosilylation reaction

    Authors:
    Olga Bartlewicz, Magdalena Jankowska-Wajda, Hieronim Maciejewski
    Conference:
    IUPAC 50th assembly & 47th World Chemistry Congress (year: 2019, pages: 1791), Publisher: IUPAC
    Date:
    conference 5-12.07
    Status:
    Published
    DOI:
    link to the publication

  8. Allyl and multiallyl based ionic liquids – synthesis, properties and applications

    Authors:
    Andrea Szpecht, Dawid Zieliński, Jakub Hoppe, Marcin Śmiglak, Hieronim Maciejewski
    Conference:
    62 Zjazd Naukowy PTChem (year: 2019, pages: S05-7), Publisher: Polskie Towarzystwo Chemiczne
    Date:
    conference 02-06.09
    Status:
    Published

  9. Synthesis of ligands based on ionic liquids

    Authors:
    Olga Stolarska, Sandra Rutecka, Andrea Szpecht, Adrian Zając, Marcin Śmiglak, Hieronim Maciejewski
    Conference:
    3rd Green & Sustainable Chemistry Conference (year: 2018, pages: P2.40), Publisher: Elsevier
    Date:
    conference 13-16.05
    Status:
    Published

  10. Synteza i charakterystyka nowych cieczy jonowych z anionami alkilosiarczanami

    Authors:
    Andrea Szpecht, Adrian Zając, Dawid Zieliński, Marcin Śmiglak, Hieronim Maciejewski
    Conference:
    X Poznańska Konferencja Naukowa Chemia - Nauka i Przemysł (year: 2018, pages: 57 (S1-P4)), Publisher: -
    Date:
    conference 30,11
    Status:
    Published

  11. Anionowe kompleksy rodu jako nowe katalizatory reakcji hydrosililowania ketonów

    Authors:
    Olga Bartlewicz, Magdalena Jankowska-Wajda, Hieronim Maciejewski
    Conference:
    X Poznańska Konferencja Naukowa Chemia - Nauka i Przemysł (year: 2018, pages: 99 (S1-P29)), Publisher: -
    Date:
    conference 30,11
    Status:
    Published

  12. Ion chromatography as an excellent tool for ion exchange control in ionic liquids synthesis

    Authors:
    Andrea Szpecht, Adrian Zając, Dawid Zieliński, Marcin Śmiglak, Hieronim Maciejewski
    Conference:
    2nd Advances in Green Chemistry Conference (year: 2018, pages: 62 (F_007)), Publisher: Poznan Science and Technology Park, Adam Mickiewicz University Foundation
    Date:
    conference 16-19.04
    Status:
    Published

  13. Synteza ligandów opartych o ciecze jonowe

    Authors:
    Sandra Rutecka, Olga Stolarska, Andrea Szpecht, Adrian Zając, Marcin Śmiglak, Hieronim Maciejewski
    Conference:
    VI Ogólnopolska Konferencja Pomiędzy Naukami (year: 2017, pages: 91), Publisher: Uniwersytet Śląski
    Date:
    conference 15,09
    Status:
    Published
    DOI:
    link to the publication

  14. Funkcjonalizowane ciecze jonowe, jako prekursory związków kompleksowych rodu i platyny

    Authors:
    Sandra Rutecka , Olga Stolarska , Adrian Zając , Marcin Śmiglak, Hieronim Maciejewski
    Conference:
    IV Poznańskie Sympozjum Młodych Naukowców (year: 2017, pages: 87), Publisher: Uniwersytet im. Adama Mickiewicza w Poznaniu
    Date:
    conference 18,11
    Status:
    Published
    DOI:
    link to the publication

  15. Wykorzystanie cieczy jonowych do syntezy nowych fosfinowych ligandów

    Authors:
    Andrea Szpecht, Adrian Zając, Magdalena Jankowska-Wajda, Marcin Śmiglak,Hieronim Maciejewski
    Conference:
    60 Zjazd Naukowy Polskiego Towarzystwa Chemicznego (year: 2017, pages: 689), Publisher: Polskie Towarzystwo Chemiczne
    Date:
    conference 17-21.09
    Status:
    Published

  16. Kataliza reakcji hydrosililowania z wykorzystaniem nowych kompleksów rodu i platyny

    Authors:
    Olga Wolna, Magdalena Jankowska-Wajda, Hieronim Maciejewski
    Conference:
    II OGÓLNOPOLSKIE SYMPOZJUM CHEMII BIOORGANICZNEJ, ORGANICZNEJ I BIOMATERIAŁÓW (year: 2017, pages: 415-416), Publisher: Poznański Park Naukowo Technologiczny
    Date:
    conference 2,12
    Status:
    Published

  17. Kataliza reakcji hydrosililowania z wykorzystaniem nowych kompleksów rodu i platyny

    Authors:
    Olga Wolna, Hieronim Maciejewski, Magdalena Jankowska-Wajda
    Conference:
    60 Zjazd Naukowy Polskiego Towarzystwa Chemicznego (year: 2017, pages: 940), Publisher: Polskie Towarzystwo Chemiczne
    Date:
    conference 17-21.09
    Status:
    Published

  18. Anionic platinum and rhodium complexes as effective catalysts for hydrosilylation processes

    Authors:
    Hieronim Maciejewski, Magdalena Jankowska-Wajda, Olga Wolna
    Conference:
    18th International Symposium on Silicon Chemistry (ISOS XVIII) in conjunction with the 6th Asian Silicon Symposium (ASiS-6) (year: 2017, pages: 169), Publisher: Shandong University
    Date:
    conference 6-11.08
    Status:
    Published

  19. Anionic rhodium complexes as new catalysts for the hydrosilylafiom reaction of acetophenone

    Authors:
    Olga Wolna, Magdalena Jankowska - Wajda, Hieronim Maciejewski
    Conference:
    9th European Silicon Days (year: 2018, pages: 182 (P-66)), Publisher: Universitat des Saarlandes
    Date:
    conference 9-12.09
    Status:
    Published

  20. Highly efficient catalytic system for hydrosilylation processes based - on new platinum and rhodium complexes

    Authors:
    Magdalena Jankowska- Wajda, Olga Wolna, Hieronim Maciejewski
    Conference:
    9th European Silicon Days (year: 2018, pages: 194 (P-78)), Publisher: Universitat des Saarlandes
    Date:
    conference 9-12.09
    Status:
    Published

  21. Catalysis of hydrosilylation by new rhodium and Platinum complexes

    Authors:
    Olga Wolna, Magdalena Jankowska-Wajda, Hieronim Maciejewski
    Conference:
    18th International Symposium on Silicon Chemistry (ISOS XVIII) in conjunction with the 6th Asian Silicon Symposium (ASiS-6) (year: 2017, pages: 383), Publisher: Shandong University
    Date:
    conference 6-11.08
    Status:
    Published

  22. Synthesis of effective hydrositylation catalysts on the basis of reactions of Rh and Pt complexes with ionic liquids

    Authors:
    Hieronim Maciejewski, Magdalena Jankowska-Wajda, Olga Wolna
    Conference:
    9th European Silicon Days (year: 2018, pages: 53 (IL-24)), Publisher: Universitat des Saarlandes
    Date:
    conference 9-12.09
    Status:
    Published

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Graphic design and implementation: Jakub Piotrowski