Projects funded by the NCN


Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Synthesis and physicochemical properties of mixed valence metal-organic frameworks

2013/11/B/ST5/01058

Keywords:

metal-organic frameworks multiferroics optical materials Raman infrared phase transitions

Descriptors:

  • ST5_8: Metals, alloys
  • ST4_3: Molecular architecture and structure
  • ST3_18:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Instytut Niskich Temperatur i Badań Strukturalnych im. Włodzimierza Trzebiatowskiego PAN

woj. dolnośląskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Mirosław Mączka 

Number of co-investigators in the project: 10

Call: OPUS 6 - announced on 2013-09-16

Amount awarded: 683 200 PLN

Project start date (Y-m-d): 2014-08-08

Project end date (Y-m-d): 2017-08-07

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. samodzielny mikroskop IR wyposażony w czuły detektor MCT, automatyczny stolik i automatyczny polaryzator (330 000 PLN)
  2. suszarka laboratoryjna (8 000 PLN)
  3. mieszadło magnetyczne (2 000 PLN)

Information in the final report

  • Publication in academic press/journals (13)
  1. Luminescence, magnetic and vibrational properties of novel heterometallic niccolites [(CH3)2NH2][CrIIIMII(HCOO)6] (MII=Zn, Ni,Cu) and [(CH3)2NH2][AlIIIZnII(HCOO)6]:Cr3+
    Authors:
    Mirosław Mączka, Adam Pietraszko,Adam Pikul, Krzysztof Hermanowicz
    Academic press:
    Journal of Solid State Chemistry (rok: 2016, tom: 233, strony: 455-462), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jssc.2015.11.027 - link to the publication
  2. Synthesis, magnetic and vibrational properties of two novel mixedvalence iron(II)-iron(III) formate frameworks
    Authors:
    Mirosław Mączka, Edyta Kucharska, Anna Gągor, Adam Pikul, Jerzy Hanuza
    Academic press:
    Journal of Solid State Chemistry (rok: 2018, tom: 258, strony: 163-169), Wydawca: Elsevier
    Status:
    Published
  3. Vibrational and magnetic properties of [C2H5NH3][FeIIIMII(HCOO)6] (M = Mn, Ni) and [C2H5NH3][CrIIIMnII(HCOO)6] framework compounds
    Authors:
    M. Mączka, A. Gągor, A. Pikul, M. Trzebiatowska
    Academic press:
    Vibrational Spectroscopy (rok: 2017, tom: 90, strony: 74-80), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.vibspec.2017.04.004 - link to the publication
  4. Experimental and theoretical studies of structural phase transition in a novel polar perovskite-like [C2H5NH3][Na0.5Fe0.5(HCOO)3] formate
    Authors:
    Maciej Ptak, Mirosław Mączka, Anna Gągor, Adam Sieradzki, Alessandro Stroppa, Domenico Di Sante, Juan Manuel Perez-Mato and Lucyna Macalik
    Academic press:
    Dalton Transactions (rok: 2016, tom: 45, strony: 2574-2583), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c5dt04536c - link to the publication
  5. Phonon, optical and luminescent properties of novel heterometallic frameworks of [(NH4)(H2O)][CrIIIMII(HCOO)6] (MII=Mn, Zn, Co, Ni)
    Authors:
    M. Mączka, J. Janczak, K. Hermanowicz, J. Hanuza
    Academic press:
    Journal of Alloys and Compounds (rok: 2018, tom: 732, strony: 201-209), Wydawca: Elsevier
    Status:
    Published
  6. Structural,magnetic and phonon properties of Cr(III)-doped perovskite metal formate framework [(CH3)2NH2][Mn(HCOO)3]
    Authors:
    Mirosław Mączka, Anna Gągor, Krzysztof Hermanowicz, Adam Sieradzki, Lucyna Macalik, Adam Pikul
    Academic press:
    Journal of Solid State Chemistry (rok: 2016, tom: 237, strony: 150-158), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jssc.2016.02.010 - link to the publication
  7. Temperature-dependent studies of [(CH3)2NH2][FeIIIMII(HCOO)6] frameworks (MII = Fe and Mg): structural, magnetic, dielectric and phonon properties
    Authors:
    Aneta Ciupa, Mirosław Mączka, Anna Gągor, Adam Sieradzki, Justyna Trzmiel, Adam Pikul, Maciej Ptak
    Academic press:
    Dalton Transactions (rok: 2015, tom: 44, strony: 8846-8854), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c5dt00512d - link to the publication
  8. Synthesis and characterization of novel niccolites [(CH3)2NH2][FeIIIMII(HCOO)6] (MII = Zn, Ni, Cu)
    Authors:
    Aneta Ciupa, Mirosław Mączka, Anna Gągor, Adam Pikul and Maciej Ptak
    Academic press:
    Dalton Transactions (rok: 2015, tom: 44, strony: 13234-13241), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c5dt01608h - link to the publication
  9. Synthesis and characterization of two novel chiral-type formate frameworks templated by protonated diethylamine and ammonium cations
    Authors:
    Mirosław Mączka, Anna Gągor, Jerzy Hanuza, Adam Pikul, Marek Droz
    Academic press:
    Journal of Solid State Chemistry (rok: 2017, tom: 245, strony: 23-29), Wydawca: Elsevier
    Status:
    Published
  10. Dielectric relaxation behavior in antiferroelectric metal organic framework [(CH3)2NH2][FeIIIFeII(HCOO)6] single crystals
    Authors:
    A. Sieradzki, S. Pawlus, S. N. Tripathy, A. Gągor, A. Ciupa, M. Mączka and M. Paluch
    Academic press:
    Physical Chemistry Chemical Physics (rok: 2016, tom: 18, strony: 8462-8467), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c6cp00064a - link to the publication
  11. Effect of aliovalent doping on the properties of perovskite-like multiferroic formates
    Authors:
    Mirosław Mączka, Adam Sieradzki, Bartosz Bondzior, Przemysław Dereń, Jerzy Hanuza, Krzysztof Hermanowicz
    Academic press:
    Journal of Materials Chemistry C (rok: 2015, tom: 3, strony: 9337-9345), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c5tc02295a - link to the publication
  12. Magnetic, optical and phonon properties of novel heterometallic formates [NH3CH2CH2OH][MIIIMII(HCOO)6] (MIII = Fe, Cr; MII = Mn, Ni, Co)
    Authors:
    Mirosław Mączka, Jan Janczak, Krzysztof Hermanowicz, Adam Pikul, Jerzy Hanuza
    Academic press:
    Journal of Solid State Chemistry (rok: 2018, tom: 260, strony: 45488), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jssc.2017.12.017 - link to the publication
  13. Structural, magnetic and dielectric properties of two novel mixed-valence iron(II)–iron(III) metal formate frameworks
    Authors:
    Mirosław Mączka, Aneta Ciupa, Anna Gągor, Adam Sieradzki, Adam Pikul and Maciej Ptak
    Academic press:
    Journal of Materials Chemistry C (rok: 2016, tom: 4, strony: 1186-1193), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c5tc03683f - link to the publication