Ruthenium carbene complexes bearing quaternary ammonium groups as a effective metathesis catalysts. The influence of the anionic counter-ion on the properties of ruthenium catalysts.

2012/07/B/ST5/02119

Keywords

Descriptors

  • ST5_18: Kataliza homogeniczna i heterogeniczna
  • ST5_20: Chemia pojedynczych cząsteczek i makrocząsteczek
  • ST5_23: Chemia organiczna

Panel

ST5 – Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution

Apeiron Synthesis S.A.

Voivodeship: dolnośląskie

Other projects carried out by the institution »

Principal investigator (from the host institution)

dr Michał Bieniek

Number of co-investigators in the project: 3

Call

OPUS 4 – announced on 2012-09-15

Amount awarded
500 700 PLN
Project start date
2013-09-10
Project end date
2016-09-09
Project duration
36 months (the same as in the proposal)
Project status
Project settled

Equipment purchased [PL]

  1. Chromatograf gazowy z autosamplerem. Cost: 26 527 PLN
  2. Czasza aluminowa. Cost: 1 500 PLN
  3. Mieszadło magnetyczne. Cost: 1 051 PLN
  4. Szkło laboratoryjne. Cost: 25 556 PLN
  5. Waga analityczna. Cost: 1 547 PLN
  6. Wyparka próżniowa. Cost: 4 733 PLN

Information in the final report

Publication in academic press/journals (3)

  1. Ru-Based Complexes with Quaternary Ammonium Tags Immobilized on Mesoporous Silica as Olefin Metathesis Catalysts

    Authors:
    Jakub Pastva, Krzysztof Skowerski, Stefan J. Czarnocki, Naděžda Žilková, Jiří Čejka, Zdeněk Bastl, Hynek Balcar
    Academic press:
    American Chemical Society (year: 2014, volume: nie dotyczy, pages: 3227-3236), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/cs500796u – link to the publication
  2. Ammonium NHC-tagged olefin metathesis catalysts – influence of the counter-ion on the catalytic activity

    Authors:
    Andrzej Tracz, Anna Gawin, Michał Bieniek, Tomasz K. Olszewski, Krzysztof Skowerski
    Academic press:
    New Journal of Chemistry (year: 2018, volume: nie dotyczy, pages: 8609-8614), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C8NJ00614H – link to the publication
  3. Rutheniumbased complexes bearing quaternary ammonium tags as versatile catalysts for olefin metathesis: From the discovery to practical applications

    Authors:
    Olszewski Tomasz, Skowersk Krzysztof, Bieniek Michal
    Academic press:
    Organic Process Research & Development (year: 2020, volume: 24(2), pages: 125-145), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.oprd.9b00483 – link to the publication

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Graphic design and implementation: Jakub Piotrowski