Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Nanoscale molecular rings and cages: development of dynamic covalent chemistry

2012/06/A/ST5/00230

Keywords:

imines thermodynamic control chirality acyl hydrazides boronates molecular cages molecular modeling

Descriptors:

  • ST4_4: Theoretical and computational chemistry
  • ST5_23:
  • ST5_6: Porous materials, ceramics, glasses

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet im. Adama Mickiewicza w Poznaniu, Wydział Chemii

woj. wielkopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Jacek Gawroński 

Number of co-investigators in the project: 9

Call: MAESTRO 3 - announced on 2012-06-15

Amount awarded: 2 882 900 PLN

Project start date (Y-m-d): 2013-04-25

Project end date (Y-m-d): 2018-04-24

Project duration:: 60 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. Aparat do mierzenia temperatury topnienia SMP 40 (20 000 PLN)
  2. Polarymetr (137 000 PLN)
  3. Zestaw do chromatografii typu flash z detektorem UV (50 000 PLN)
  4. Planetarny młyn kulowy PM 100 wraz z wyposażeniem (45 000 PLN)
  5. Wyparka obrotowa (2 szt.) (25 000 PLN)
  6. Lampa do aparatu rentgenowskiego (25 000 PLN)
  7. Pompa próżniowa z kontrolerem cisnienia (2 szt.) (44 000 PLN)
  8. Reaktor Parra serii 5100 (73 000 PLN)
  9. Kriostat zanurzeniowy (35 500 PLN)
  10. beziskrowa zamrażarka laboratoryjna (8 383 PLN)
  11. Rozbudowa klastra obliczeniowego (32 500 PLN)

Information in the final report

  • Publication in academic press/journals (20)
  • Book publications / chapters in book publications (1)
  1. Dynamic Formation of Noncovalent Calixsalen Aggregates
    Authors:
    Małgorzata Petryk, Anna Troć, Błażej Gierczyk, Witold Danikiewicz and Marcin Kwit
    Academic press:
    Chemistry - A European Journal (rok: 2015, tom: 21, strony: 10318-10321), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201500945 - link to the publication
  2. Fine tuning of molecular and supramolecular properties of simple trianglimines - the role of functional group
    Authors:
    Jadwiga Gajewy, Joanna Szymkowiak, Marcin Kwit
    Academic press:
    RSC Advances (rok: 2016, tom: 6, strony: 53358-53369), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/c6ra06095a - link to the publication
  3. One-step Access to Resorcinsalens – Solvent Dependent Synthesis, Tautomerism, Self-sorting and Supramolecular Architectures of Chiral Polyimine Analogues of Resorcinarene
    Authors:
    J. Szymkowiak, B. Warżajtis, U. Rychlewska and M. Kwit
    Academic press:
    Chemistry - A European Journal (rok: 2018, tom: 24, strony: 6041-6046), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201800316 - link to the publication
  4. Unexpected relationship between inclusion and sorption properties of chiral calixsalens solids
    Authors:
    A. Janiak, M. Kwit, and L. J. Barbour
    Academic press:
    Supramolecular Chemistry (rok: 2018, tom: 30, strony: 479-487), Wydawca: Taylor&Francis
    Status:
    Published
    DOI:
    10.1080/10610278.2018.1427865 - link to the publication
  5. One-step Construction of the Shape Persistent, Chiral But Symmetrical Polyimine Macrocycles
    Authors:
    M. Kwit, J. Grajewski, P. Skowronek, M. Zgorzelak and J. Gawroński
    Academic press:
    The Chemical Records (rok: 2019, tom: 19, strony: 213-237), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/tcr.201800052 - link to the publication
  6. Readily Prepared Inclusion Forming Chiral Calixsalens
    Authors:
    Agnieszka Janiak, Małgorzata Petryk, Len J. Barbour, Marcin Kwit
    Academic press:
    Organic & Biomolecular Chemistry (rok: 2016, tom: 14, strony: 669-673), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/C5OB02090E - link to the publication
  7. Specific Noncovalent Association of Chiral Large-ring Hexaimines - Ion Mobility Mass Spectrometry and PM7 Study
    Authors:
    Anna Troć, Jadwiga Gajewy, Witold Danikiewicz, Marcin Kwit
    Academic press:
    Chemistry - A European Journal (rok: 2016, tom: 22, strony: 13258 – 13264), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201602515 - link to the publication
  8. A thermo-responsive structural switch and colossal anisotropic thermal expansion in a chiral organic solid
    Authors:
    A. Janiak, C. Esterhuysen and L. J. Barbour
    Academic press:
    Chemical Communication (rok: 2018, tom: 54, strony: 3727-3730), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/c8cc00952j - link to the publication
  9. Awkwardly‐shaped dimers, capsules and tetramers: molecular and supramolecular motifs in C5‐arylated chiral calixsalens
    Authors:
    M. Petryk, A. Janiak, L. Barbour and M. Kwit
    Academic press:
    European Journal of Organic Chemistry (rok: 2018, tom: -, strony: 1916-1923), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejoc.201800314 - link to the publication
  10. Chiral, triformylphenol-derived salen-type [4 + 6] organic cages
    Authors:
    Małgorzata Petryk, Joanna Szymkowiak, Błażej Gierczyk, Grzegorz Spólnik, Łukasz Popenda, Agnieszka Janiak, Marcin Kwit
    Academic press:
    Organic & Biomolecular Chemistry (rok: 2016, tom: 14, strony: 7495–7499), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/c6ob01429a - link to the publication
  11. Consistent supramolecular assembly arising from a mixture of components – self-sorting and solid solutions of chiral oxygenated trianglimines
    Authors:
    J. Szymkowiak, B. Warżajtis, U. Rychlewska, and M. Kwit
    Academic press:
    CrystEngComm (rok: 2018, tom: 20, strony: 5200-5208), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/c8ce01044g - link to the publication
  12. From cavities to channels in host:guest complexes of bridged trianglamine and aliphatic alcohols
    Authors:
    Agnieszka Janiak, Mateusz Bardziński, Jacek Gawroński and Urszula Rychlewska
    Academic press:
    Crystal Growth & Design (rok: 2016, tom: 16, strony: 2779−2788), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.cgd.6b00100 - link to the publication
  13. Introduction of Axial Chirality at a Spiro Carbon Atom in the Synthesis of a Pentaerythritol – Imine Macrocycles
    Authors:
    J. Grajewski, K. Piotrowska, M. Zgorzelak, A. Janiak, K. Biniek-Antosiak, U. Rychlewska, J. Gawronski
    Academic press:
    Organic & Biomolecular Chemistry (rok: 2018, tom: 16, strony: 981-987), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/C7OB02672B - link to the publication
  14. Unexpected formation of tubular architecture by optically active pure organic calixsalen
    Authors:
    M. Petryk, A. Janiak and M. Kwit
    Academic press:
    CrystEngComm (rok: 2017, tom: 19, strony: 5825-5829), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/c7ce01529a - link to the publication
  15. "Double chiral" new members of calixsalen family
    Authors:
    M. Petryk, A. Janiak and M. Kwit
    Academic press:
    Tetrahedron: Asymmetry (rok: 2017, tom: 28, strony: 1373-1383), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.tetasy.2017.08.021 - link to the publication
  16. Axial chirality inversion at a spiro carbon leads to efficient synthesis ofpolyimine macrocycle
    Authors:
    M. Zgorzelak and J. Grajewski
    Academic press:
    Journal of Molecular Structure (rok: 2020, tom: 1202, strony: 127336 (nr artykułu)), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.molstruc.2019.127336 - link to the publication
  17. Electronic and vibrational exciton coupling in oxidized trianglimines
    Authors:
    J. Szymkowiak and M. Kwit
    Academic press:
    Chirality (rok: 2018, tom: 30, strony: 117-130), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chir.22783 - link to the publication
  18. Enantiopure tertiary urea and thiourea derivatives of trianglamine macrocycle – structural studies and metallogeling properties
    Authors:
    N. Prusinowska, J. Szymkowiak, and M. Kwit
    Academic press:
    The Journal of Organic Chemistry (rok: 2018, tom: 83, strony: 1167-1175), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.joc.7b02600 - link to the publication
  19. Sterically Crowded Trianglimines - Synthesis, Structure, Solid State Self-Assembly and Unexpected Chiroptical Properties
    Authors:
    N. Prusinowska, M. Bardziński, A. Janiak, M. Kwit and P. Skowronek
    Academic press:
    Chemistry - An Asian Journal (rok: 2018, tom: 13, strony: 2691-2699), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/asia.201800938 - link to the publication
  20. Unexpected narcissistic self-sorting at molecular and supramolecular level in racemic chiral calixsalens
    Authors:
    Małgorzata Petryk, Katarzyna Biniek, Agnieszka Janiak and Marcin Kwit
    Academic press:
    CrystEngCom (rok: 2016, tom: 18, strony: 4996–5003), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/c6ce00256k - link to the publication
  1. Trianglamines and Related Chiral Macrocycles
    Authors:
    Jacek Gawroński, Marcin Kwit and Urszula Rychlewska
    Book:
    Comprehensive Supramolecular Chemistry II (rok: 2017, tom: 3, strony: 267–291), Wydawca: Elsevier
    Status:
    Published

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