Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

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Design and modular synthesis of tailor made catalysts of special properties, among others water-soluble and immobilized in/on fluorous as well as solid supports TM complexes. Application in environmentally beneficial (sustainable) syntheses.

2012/05/B/ST5/00362

Keywords:

transition metal complexes phosphorus ligands asymmetric synthesis aqueous – phase catalysis perfluorinated solvents immobilized catalysts cross coupling environmentally beneficial synthesis

Descriptors:

  • ST5_18:
  • ST5_23:
  • ST5_13: Research methods on materials/nanomaterials properties

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Marii Curie-Skłodowskiej, Wydział Chemii

woj. lubelskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Oleh Demchuk 

Number of co-investigators in the project: 7

Call: OPUS 3 - announced on 2012-03-15

Amount awarded: 433 300 PLN

Project start date (Y-m-d): 2013-03-06

Project end date (Y-m-d): 2017-09-05

Project duration:: 54 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. Pompa próżniowa (22 000 PLN)
  2. Zmywarka laboratoryjna (10 000 PLN)
  3. Automatyczny kolektor frakcji (45 000 PLN)
  4. Mieszadło magnetyczne (6 600 PLN)
  5. Mikroskop cyfrowy z wyposażeniem.

Information in the final report

  • Publication in academic press/journals (14)
  • Articles in post-conference publications (2)
  1. Brönsted acid catalysed direct oxidative arylation of 1,4-naphthoquinone
    Authors:
    K. Kapłon, O. M. Demchuk,* Marta Wieczorek and K. Michał Pietrusiewicz
    Academic press:
    Current Chemistry Letters (rok: 2014, tom: 3, strony: 23-36), Wydawca: Growing Science
    Status:
    Published
    DOI:
    10.001 - link to the publication
  2. Tris(acetonitrile)chloropalladium tetrafluoroborate synthesis, application and structural analysis
    Authors:
    Dybała, I., Demchuk, O.M.
    Academic press:
    Journal of Molecular Structure (rok: 2016, tom: 1121, strony: 135-141), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.molstruc.2016.05.056 - link to the publication
  3. 1,4-NAPHTHOQUINONE DERIVATIVES POTENTLY SUPPRESS C. ALBICANS GROWTH AND INHIBIT FORMATION OF HYPHAE
    Authors:
    Monika Janeczko; Konrad Kubiński; Aleksandra Martyna; Angelika Muzyczka; Anna Boguszewska-Czubara; Sławomir Czernik; Małgorzata Tokarska-Rodak; Marta Chwedczuk; Oleg Demchuk; Hieronim Golczyk; Maciej Masłyk
    Academic press:
    Journal of Medical Microbiology (rok: 2018, tom: 67, strony: 598-609), Wydawca: Microbiology Society
    Status:
    Published
    DOI:
    10.1099/jmm.0.000700 - link to the publication
  4. 2-Methoxynaphthylnaphthoquinone and its solvate: synthesis and structure - properties relationship
    Authors:
    O. M. Demchuk, I. Justyniak, B. Miroslaw, R. Jasinski
    Academic press:
    Journal of Physical Organic Chemistry (rok: 2014, tom: 27, strony: 66-73), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/poc.3237 - link to the publication
  5. A Quantum-Chemical DFT Approach to Elucidation of the Chirality Transfer Mechanism of the Enantioselective Suzuki–Miyaura Cross-Coupling Reaction
    Authors:
    Radomir JasiNski, Oleg M. Demchuk, Dmytro Babyuk
    Academic press:
    Journal of Chemistry (rok: 2017, tom: 2017, strony: Article ID 3617527, 12 pages), Wydawca: Hindawi
    Status:
    Published
    DOI:
    10.1155/2017/3617527 - link to the publication
  6. Green in water sonochemical synthesis of tetrazolopyrimidine derivatives by a novel core-shell magnetic nanostructure catalyst
    Authors:
    Maleki, Ali; Rahimi, Jamal ; Demchuk, Oleg; Wilczewska, Agnieszka; Jasiński, Radomir
    Academic press:
    Ultrasonics Sonochemistry (rok: 2018, tom: 43, strony: 262-271), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.ultsonch.2017.12.047 - link to the publication
  7. New Insights into the Mechanism of Reduction of Tertiary Phosphine Oxides by Means of Phenylsilane
    Authors:
    O. M. Demchuk, R. Jasinski, K. M. Pietrusiewicz
    Academic press:
    Heteroatom Chemistry (rok: 2015, tom: 26, strony: 441-448), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/hc.21279 - link to the publication
  8. A clean and simple method for deprotection of phosphines from borane complexes
    Authors:
    Oleg M. Demchuk, Radomir Jasinski, Dorota Strzelecka, Kamil Dziuba, Karolina Kula, Jacek Chrzanowski, Dorota Krasowska
    Academic press:
    Pure and Applied Chemistry (rok: 2018, tom: 90, strony: 49-62), Wydawca: IUPAC & De Gruyter
    Status:
    Published
    DOI:
    10.1515/pac-2017-0313 - link to the publication
  9. Organophosphorus ligands: Recent developments in design, synthesis, and application in environmentally benign catalysis
    Authors:
    Demchuk, O.M., Jasiński, R.
    Academic press:
    Phosphorus, Sulfur and Silicon and the Related Elements (rok: 2016, tom: 191, strony: 245-253), Wydawca: Taylor & Francis
    Status:
    Published
    DOI:
    10.1080/10426507.2015.1064921 - link to the publication
  10. Readily available catalysts for demanding Suzuki–Miyaura couplings under mild conditions
    Authors:
    Demchuk, O.M., Kapłon, K., Mazur, L., Strzelecka, D., Pietrusiewicz, K.M.
    Academic press:
    Tetrahedron (rok: 2016, tom: 72, strony: 6668-6677), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.tet.2016.08.087 - link to the publication
  11. Straightforward approach to norbornene core based chiral ligands by tandem cross dehydrogenative coupling reactions
    Authors:
    Szwaczko, K., Demchuk, O.M., Mirosław, B., Strzelecka, D., Pietrusiewicz, K.M.
    Academic press:
    Tetrahedron Letters (rok: 2016, tom: 57, strony: 3491-3495), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.tetlet.2016.06.104 - link to the publication
  12. The utilization of chiral phosphorus ligands in atroposelective cross-coupling reactions
    Authors:
    Demchuk, O.M., Kapłon, K., Kącka, A., Pietrusiewicz, K.M.
    Academic press:
    Phosphorus, Sulfur and Silicon and the Related Elements (rok: 2016, tom: 191, strony: 180-200), Wydawca: Taylor and Francis Ltd.
    Status:
    Published
    DOI:
    10.1080/10426507.2015.1079197 - link to the publication
  13. New family of antimicrobial agents derived from 1,4-naphthoquinone
    Authors:
    Janeczko, M., Demchuk, O.M., Strzelecka, D., Kubiński, K., Masłyk, M.
    Academic press:
    European Journal of Medicinal Chemistry (rok: 2016, tom: 124, strony: 1019–1025), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.034 - link to the publication
  14. The DFT study on racemisation of atropisomeric biaryls
    Authors:
    K. Kapłon, O. M. Demchuk, K. M. Pietrusiewicz
    Academic press:
    Current Chemistry Letters (rok: 2015, tom: 4, strony: 145-152), Wydawca: GrowingScience
    Status:
    Published
    DOI:
    10.5267/j.ccl.2015.6.003 - link to the publication
  1. STRUKTURALNA RÓŻNORODNOŚĆ KOMPLEKSÓW PALLADU Z LIGANDEM FOSFOROWYM O C,P- ORAZ O,P- TYPIE KOMPLEKSOWANIA
    Authors:
    Oleg M. Demchuk, Barbara Mirosław
    Conference:
    60 Zjazd Naukowy Polskiego Towarzystwa Chemicznego (rok: 2017, ), Wydawca: Politechnika Wrocławska
    Data:
    konferencja 17-21 września
    Status:
    Published
    DOI:
    link to the publication
  2. Zastosowanie magnetycznych, nanostrukturalnych katalizatorów w "zielonej" syntezie tetrazolopirymidyn
    Authors:
    Oleg M. Demchuk, A. Maleki, J. Rahimi, A. Z. Wilczewska, R. Jasiński
    Conference:
    XI OGÓLNOPOLSKIE SYMPOZJUM CHEMII ORGANICZNEJ (rok: 2018, ), Wydawca: Instytut Chemii Organicznej PAN
    Data:
    konferencja 8-11.04
    Status:
    Published

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