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Information of the project and the call

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Infrared and Raman studies of the role of hydrogen and halogen bonding in formation of the Mott insulating state in low-dimensional organic conductors based on TTF (tetrathiofulvalene) derivatives

2012/04/M/ST3/00774

Keywords:

low-dimensional organic conductors metal-insulator transition Mott localization IR and Raman spectroscopy electronic structure charge distribution

Descriptors:

  • ST3_5: Physical properties of semiconductors and insulators
  • ST3_14: Fluid dynamics (physics)
  • ST3_18:

Panel:

ST3 - Condensed matter physics: structure, electronic properties, fluids, nanosciences, biological physics

Host institution :

Instytut Fizyki Molekularnej PAN

woj. wielkopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Roman Świetlik 

Number of co-investigators in the project: 5

Call: HARMONIA 2 - announced on 2011-12-15

Amount awarded: 316 290 PLN

Project start date (Y-m-d): 2012-09-17

Project end date (Y-m-d): 2015-09-16

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Information in the final report

  • Publication in academic press/journals (5)
  • Articles in post-conference publications (19)
  1. Chirality Driven Metallic versus Semiconducting Behavior in a Complete Series of Radical Cation Salts Based on Dimethyl-Ethylenedithio-Tetrathiafulvalene (DM-EDT-TTF)
    Authors:
    F. Pop, P. Auban-Senzier, A. Frąckowiak, K. Ptaszyński, I. Olejniczak, J.D. Wallis, E. Canadell, and N. Avarvari,
    Academic press:
    J. Am. Chem. Soc. (rok: 2013, tom: 135, strony: 17176-17186), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/ja408350r - link to the publication
  2. Inter-layer charge disproportionation in the dual-layer organic metal (tTTF-I)2ClO4 with unsymmetrical I⋯O halogen bond interactions†
    Authors:
    Kyoung-Soon Shin, Olivier Jeannin, Mariya Brezgunova, Slimane Dahaoui, Emmanuel Aubert, Enrique Espinosa, Pascale Auban-Senzier, Roman Świetlik, Arkadiusz Frąckowiak and Marc Fourmigue
    Academic press:
    Dalton Transactions (rok: 2014, tom: 43, strony: 5280-5291), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c3dt52801d - link to the publication
  3. Spectroscopic studies of the phase transition from the Mott insulator state to the charge-ordering state of κ-(ET)4[M(CN)6][N(C2H5)4]∙2H2O (M=CoIII and FeIII) salts
    Authors:
    A. Łapiński, R. Świetlik, L. Ouahab, S. Golhen
    Academic press:
    Journal of Physical Chemistry A (rok: 2013, tom: 117, strony: 5241-5240), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/jp402027x - link to the publication
  4. Charge-sensitive vibrational modes In the (EDT-TTF-OX)2AsF6 chiral molecular conductors.
    Authors:
    I. Olejniczak, A. Frąckowiak, J. Matysiak, A. Madalan, F. Pop, N. Avarvari
    Academic press:
    Central European Journal of Physics 12, 215-220 (2014) (rok: 2014, tom: 12, strony: 215-220), Wydawca: Springer
    Status:
    Published
    DOI:
    10.2478/s11534-014-0443-1 - link to the publication
  5. Electron-molecular vibration coupling in (DMtTTF)Br and (o-DMTTF)2[W6O19] salts studied by infrared spectroscopy
    Authors:
    A. Łapiński, D. Jankowski, R. Świetlik, E.W. Reinheimer, M. Fourmigué
    Academic press:
    Synthetic Metals (rok: 2014, tom: 188, strony: 92-99), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.synthmet.2013.11.004 - link to the publication
  1. Spectroscopic studies of the phase transition from the Mott insulator state to the charge ordering state of κ-(ET)4[M(CN)6][N(C2H5)4]•2H2O (M = CoIII and FeIII) salts
    Authors:
    A. Łapiński, R. Świetlik, L. Ouahab, and S. Golhen
    Conference:
    The European Conference "Physics of Magnetism 2014" (PM'14), Poznań, Poland (rok: 2014, ), Wydawca: UAM
    Data:
    konferencja June 23-27, 2014
    Status:
    Published
  2. Charge redistribution in halogen bonded charge-transfer salts of unsymmetrical TTF derivatives studied by IR and Raman spectroscopy
    Authors:
    Roman Świetlik, Arkadiusz Frąckowiak, Iwona Olejniczak, Julien Lieffrig, Olivier Jeannin, and Marc Fourmigué
    Conference:
    11th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM 2015), Bad Goegging, Germany (rok: 2015, ), Wydawca: Goethe University, Frankfurt am Main
    Data:
    konferencja 06-11.09.2015
    Status:
    Published
  3. Fluktuacje rozkładu ładunku w organicznych półprzewodnikach (tTTF)2X (X =Br, I)
    Authors:
    R. Świetlik, D. Jankowski, E.W. Reinheimer, O. Jeannin, M. Fourmigué
    Conference:
    XIX Ogólnopolska Konferencja Kryształy Molekularne 2014 (KM 2014), Sromowce Niżne (rok: 2014, ), Wydawca: IFJ PAN, kraków
    Data:
    konferencja 8-12.09.2014
    Status:
    Published
  4. Neutral-to-ionic phase transition in (EDT-TTF-I2)2TCNQF
    Authors:
    A. Frąckowiak, R. Świetlik, I. Olejniczak, M. Fourmigué, J. Lieffrieg, O. Jeannin
    Conference:
    XXI Czech-Polish Seminar "Structural and Ferroelectric Phase Transitions", Sezimovo Ústi, Czech Republic (rok: 2014, ), Wydawca: Institute of Physics, Academy of Sciences of the Czech Republic
    Data:
    konferencja May 19-23, 2014
    Status:
    Published
  5. Optical investigations of TTF-based organic conductors with halogen bonding
    Authors:
    R. Świetlik, A. Frąckowiak, I. Olejniczak, J. Lieffrig, O. Jeannin, K. S. Shin, M. Fourmigué,
    Conference:
    3rd Workshop on Organic Electronics and Nanophotonics" (WOREN2013), Muszyna-Złockie (Poland) (rok: 2013, ), Wydawca: AGH
    Data:
    konferencja February 17-21, 2013
    Status:
    Published
  6. Charge-order fluctuations in organic conductors formed by TTF derivatives
    Authors:
    R. Świetlik
    Conference:
    13th INTERNATIONAL CONFERENCE on FRONTIERS of POLYMERS & ADVANCED MATERIALS, Marrakesh, Marocco (ICFPAM 2015) (rok: 2015, ), Wydawca: The Moroccan Association of Physics of Advanced Materials and Their Applications
    Data:
    konferencja 29.03. - 02. 04.2015
    Status:
    Published
  7. Infrared and Raman studies of the (EDT-TTF-I2)2TCNQFx (x = 0, 1, 2) salts
    Authors:
    A. Frąckowiak, I. Olejniczak, R. Świetlik, M. Fourmigué, J. Lieffrieg, O. Jeannin,
    Conference:
    2nd Workshop on Strongly Correlated Electron and Complex Systems: From Intermetallics to Molecular Materials, Sacavém (Portugal) (rok: 2013, ), Wydawca: Instituto Technologico e Nuclear, Sacavém, Portugal
    Data:
    konferencja 11-12 November 2013
    Status:
    Published
  8. Inter-layer charge disproportionation in the organic metal (tTTF-I)2ClO4 studied by Raman and infrared spectroscopy
    Authors:
    A. Frąckowiak , R. Świetlik, O. Jeannin, M. Fourmigué
    Conference:
    13th International Conference ELECTRONIC AND RELATED PROPERTIES OF ORGANIC SOLIDS (ERPOS 2014), Świeradów Zdrój (Poland) (rok: 2014, ), Wydawca: Politechnika Wroclawska
    Data:
    konferencja July 06-10, 2014
    Status:
    Published
  9. Spectroscopic studies of neutral –ionic transition in the (EDT-TTF-I2)2TCNQF salt
    Authors:
    Frąckowiak A., Olejniczak I., Świetlik R., Fourmigué M., Lieffrieg J., Jeannin O.
    Conference:
    XIIth International Conference on Molecular Spectroscopy, Kraków - Białka Tatrzańska (rok: 2103, ), Wydawca: AGH
    Data:
    konferencja 8-12 September 2013
    Status:
    Published
  10. Electron-molecular vibration coupling in (DMtTTF)Br and (o-DMTTF)2[W6O19] salts studied by infrared spectroscopy
    Authors:
    A. Łapiński, D. Jankowski, R. Świetlik, E.W. Reinheimer, M. Fourmigué
    Conference:
    3rd Workshop on Organic Electronics and Nanophotonics (WOREN2013), Muszyna-Złockie (Poland) (rok: 2013, ), Wydawca: AGH
    Data:
    konferencja February 17-21, 2013
    Status:
    Published
  11. Observation of the charge-order gap in d-(ET)4[2,6-anthracene-bis(sulfonate)]•(H2O)4
    Authors:
    Andrzej Łapiński, Arkadiusz Frąckowiak, Iwona Olejniczak, Roman Świetlik, Martin Dressel, David Neubauer, Frank Camerel, and Marc Fourmigué
    Conference:
    11th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM 2015), Bad Goegging, Germany (rok: 2105, ), Wydawca: Goethe University, Frankfurt am Main
    Data:
    konferencja 06 - 11.09.2015
    Status:
    Published
  12. Spektroskopowe badania przejścia fazowego ze stanu izolatora Motta do stanu z uporządkowaniem ładunkowym obserwowanego dla soli κ-(ET)4[M(CN)6][N(C2H5)4]×2H2O (gdzie M = CoIII, FeIII)
    Authors:
    A. Łapiński, R. Świetlik, L. Ouahab, S. Golhen
    Conference:
    XIX Ogólnopolska Konferencja Kryształy Molekularne 2014 (KM 2014), Sromowce Niżne, (rok: 2014, ), Wydawca: IFJ PAN, Kraków
    Data:
    konferencja 8-12.09.2014
    Status:
    Published
  13. Metal-insulator phase transition in the (DMED-TTF)2PF6 chiral organic conductor: optical study
    Authors:
    I. Olejniczak, A. Frąckowiak, J. Matysiak, K. Ptaszyński, A. Madalan, F. Pop, and N. Avarvari,
    Conference:
    XIIth International Conference on Molecular Spectroscopy, Kraków - Białka Tatrzańska (rok: 2013, ), Wydawca: AGH
    Data:
    konferencja 8-12 September 2013
    Status:
    Published
  14. Międzywarstwowe uporządkowanie ładunkowe w metalu organicznym (tTTF-I)2ClO4
    Authors:
    A. Frąckowiak, R. Świetlik, E. Espinosa, O. Jeannin, M. Fourmigué
    Conference:
    XIX Ogólnopolska Konferencja Kryształy Molekularne 2014 (KM 2014), Sromowce Niżne (rok: 2014, ), Wydawca: IFJ PAN, Kraków
    Data:
    konferencja 8-12.09.2014
    Status:
    Published
  15. Optical investigations of organic conductors (tTTF)2X (X=Br, I)
    Authors:
    R. Świetlik, D. Jankowski, E.W. Reinheimer, O. Jeannin, and M.Fourmigué
    Conference:
    10th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM 2013), Montréal, Québec, Canada (rok: 2013, ), Wydawca: Sherbrooke University
    Data:
    konferencja July 14-19, 2013
    Status:
    Published
  16. Optical properties of chiral molecular conductors based on EDT-TTF-OX and DMED-TTF
    Authors:
    I. Olejniczak, A. Frackowiak, K. Ptaszyński, A. Mdalan, F. Pop, N. Avarvari
    Conference:
    3rd Workshop on Organic Electronics and Nanophotonics" (WOREN2013), Muszyna-Złockie (Poland), (rok: 2013, ), Wydawca: AGH
    Data:
    konferencja February 17-21, 2013
    Status:
    Published
  17. Optical study of the metal-insulator phase transition in chiral molecular conductor [(S,S)-DM-EDT-TTF]2ClO4
    Authors:
    I. Olejniczak, J. Matysiak, F. Pop, N. Avarvari
    Conference:
    11th International Symposium on Crystalline Organic Metals, Superconductors and Magnets (ISCOM 2015), Bad Goegging, Germany (rok: 2015, ), Wydawca: Goethe University, Frankfurt am Main
    Data:
    konferencja 06 - 11.09.2015
    Status:
    Published
  18. Spectroscopic Studies of the Electronic States in the Organic Metal δ-(BEDT-TTF)4[2,6-Anthr(SO3)2]•(X2O)4 (X=H, D) Salts
    Authors:
    A. Frąckowiak, I. Olejniczak, R. Świetlik, M. Fourmigué, F. Camerel, O. Jeannin, E. Canadell
    Conference:
    22nd International Conference for Science and Technology of Synthetic Metals (ICSM 2014), Turku (Finland) (rok: 2014, ), Wydawca: Turku University, Finland
    Data:
    konferencja 30 June - 5 July, 2014
    Status:
    Published
  19. Spectroscopic studies of the phase transition from Mott insulating phase to charge ordering phase in the charge-transfer salt κ-(ET)4[FeIII(CN)6][N(C2H5)4]∙2(H2O)
    Authors:
    A. Łapiński, R. Świetlik, M. Dressel, D. Neubauer, W. Li, L. Ouahab, S. Golhen
    Conference:
    International Conference Multiscale phenomena in molecular matter (Multis 2015), Kraków (rok: 2105, ), Wydawca: Instytut Fizyki Jadrowej PAN, Kraków
    Data:
    konferencja 6-10.07.2015
    Status:
    Published

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