Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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The oxygenation chemistry of main group metal alkyls: A new look at the old problem.

2012/04/A/ST5/00595

Keywords:

dioxygen organometallic compounds main group metals mechanism alkyperoxides alkoxides

Descriptors:

  • ST5_14:
  • ST5_24:
  • ST5_20:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Politechnika Warszawska, Wydział Chemiczny Politechniki Warszawskiej

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Janusz Zbigniew Lewiński 

Number of co-investigators in the project: 12

Call: MAESTRO 2 - announced on 2011-12-15

Amount awarded: 2 937 000 PLN

Project start date (Y-m-d): 2012-10-08

Project end date (Y-m-d): 2017-03-07

Project duration:: 53 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. Glovebox - Komora rękawicowa wyposażona w wagę analityczną, lodówkę i "cold well" (433 734 PLN)
  2. pompa próżniowa (3 szt.) (50 000 PLN)
  3. Komputery stacjonarne (6 517 PLN)
  4. mikroskop steroskopowy z wyposażeniem (12 238 PLN)
  5. komputery stacjonarne i laptop (notebook) (4 szt.) (20 000 PLN)
  6. zwiększenie wartości młyna miksującego MM400 - naczynia miksujące-2 szt,kule mielące-4 szt.

Information in the final report

  • Publication in academic press/journals (18)
  1. Catalytic Epoxidation of Enones Mediated by Zinc Alkylperoxide/tert- BuOOH Systems.
    Authors:
    M. Kubisiak, K. Zelga, I. Justyniak, E. Tratkiewicz, T. Pietrzak, A. R. Keeri, Z. Ochal, L Hartenstein, P. W. Roesky, J. Lewiński
    Academic press:
    Organometallics (rok: 2013, tom: 32, strony: 5263-5265), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/om400830e - link to the publication
  2. Oxygenation of RZn(N,O)-type complexes as an efficient route to zinc alkoxides not accessible via the classical alcoholysis path.
    Authors:
    Z. Wróbel, T. Pietrzak, I. Justyniak, J. Lewiński
    Academic press:
    Chemical Communications (rok: 2017, tom: 53, strony: 10808--10811), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c7cc05818g - link to the publication
  3. Chemical fixation and conversion of CO2 into cyclic and cage-type metal carbonates.
    Authors:
    K. Soltys-Brzostek, M. Terlecki, K. Sokolowski, J. Lewiński
    Academic press:
    Coordination Chemistry Reviews (rok: 2017, tom: 334, strony: 199-231), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.008 - link to the publication
  4. Unprecedented variety of outcomes in the oxygenation of dinuclear alkylzinc derivatives of a N,N-coupled bis(β-diketimine).
    Authors:
    T. Pietrzak, M. D. Korzyński, I. Justyniak, K. Zelga, A. Kornowicz, Z Ochal, J. Lewiński
    Academic press:
    Chemistry – a European Journal (rok: 2017, tom: 23, strony: 7997-8005), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201700503 - link to the publication
  5. Synthesis and Structure of Alkylzinc 3,5-Diphenylpyrazolates: Dramatic Influence of Steric and Solvent Effects.
    Authors:
    S. Komorski, M. Leszczyński, I. Justyniak, J. Lewiński
    Academic press:
    Inorganic Chemistry (rok: 2016, tom: 55, strony: 5104 - 5105), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.6b00745 - link to the publication
  6. Structural Diversity of Ethylzinc Carboxylates
    Authors:
    A. Grala, M. Wolska-Pietkiewicz, A. Wojewódzka, M. Dabergut, I. Justyniak, J. Lewiński
    Academic press:
    Organometallics , Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.organomet.5b00557 - link to the publication
  7. Zinc hydroxides and oxides supported by organic ligands: Synthesis and structural diversity.
    Authors:
    D. Prochowicz, K. Sokolowski, J Lewiński
    Academic press:
    Coordination Chemistry Reviews (rok: 2014, tom: 270–271, strony: 112-126), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.ccr.2013.12.003 - link to the publication
  8. Structure investigations of group 13 organometallic carboxylates.
    Authors:
    I.Justyniak, D. Prochowicz, A. Tulewicz, W. Bury, P.Gos, J. Lewinski
    Academic press:
    Dalton Transactions (rok: 2017, tom: 46, strony: 669-677), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c6dt03958h - link to the publication
  9. A New Look at the Reactivity of TEMPO towards Diethylzinc
    Authors:
    K. Budny-Godlewski, D. Kubicki, I. Justyniak, J. Lewiński
    Academic press:
    Organometallics (rok: 2014, tom: 33 (19), strony: 5093–5096), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/om5008117 - link to the publication
  10. Synthesis, Structure, and Magnetic Properties of a Mononuclear Chiral (Acetato)bis(aminoalkoxido) manganese(III) Complex.
    Authors:
    A. Kornowicz, M. Terlecki, D. Prochowicz, C. Pichon, I. Justyniak, W Bury, Z Wróbel, J.P. Sutter, J. Lewiński
    Academic press:
    European Journal Of Inorganic Chemistry (rok: 2017, tom: 10, strony: 1392-1395), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejic.201700084 - link to the publication
  11. Alkylzinc diorganophosphates: synthesis, structural diversity and unique ability to incorporate zincoxane units.
    Authors:
    M. Wolska-Pietkiewicz, A. Swierkosz, I. Justyniak, A. Grala, K. Sokolowski, J. Lewinski
    Academic press:
    Dalton Transactions (rok: 2016, tom: 45, strony: 18813-18816), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c6dt03324e - link to the publication
  12. Quest for Efficient Catalysts based on Zinc tert-Butyl Peroxides for Asymmetric Epoxidation of Enones: C2- vs C1-Symmetric Auxiliaries
    Authors:
    A. R. Keeri, I. Justyniak, J. Jurczak, J. Lewiński
    Academic press:
    Advanced Synthesis & Catalysis (rok: 2016, tom: 358, strony: 864-868), Wydawca: WILEY
    Status:
    Published
    DOI:
    10.1002/adsc.201500764 - link to the publication
  13. Structural Diversity of Ethylzinc Carboxylates
    Authors:
    A. Grala, M. Wolska-Pietkiewicz, A. Wojewódzka, M. Dabergut, I. Justyniak, J. Lewiński
    Academic press:
    Organometallics (rok: 2015, tom: 34, strony: 4959), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.organomet.5b00557 - link to the publication
  14. Development of zinc alkyl/O2 systems as radical initiators for organic reactions
    Authors:
    M. Kubisiak, K. Zelga, W. Bury, I. Justyniak, K. Budny-Godlewski, Z. Ochal, J. Lewiński
    Academic press:
    Chemical Science (rok: 2015, tom: 6, strony: 3102), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/C5SC00600G - link to the publication
  15. Oxygenation Chemistry of Magnesium Alkyls Incorporating beta-Diketiminate Ligands Revisited.
    Authors:
    T. Pietrzak, M. Kubisiak, I. Justyniak, K. Zelga, E. Bojarski, E. Tratkiewicz, Z. Ochal, J. Lewiński
    Academic press:
    Chemistry – a European Journal (rok: 2016, tom: 22, strony: 17776-17783), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201603931 - link to the publication
  16. Structural diversity of alkylzinc complexes with pyrrole-based N,O-ligands: from molecular complexes to coordination polymers
    Authors:
    Z. Wróbel, I. Justyniak, I. Dranka, J. Lewiński
    Academic press:
    Dalton Transactions (rok: 2016, tom: 45, strony: 7240–7243), Wydawca: The Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c6dt00674d - link to the publication
  17. Probing the Role of π Interactions in the Reactivity of Oxygen Species: A Case of Ethylzinc Aryloxides with Different Dispositions of Aromatic Rings Toward the Metal Center
    Authors:
    Ł. Mąkolski, K. Zelga, R. Petrus, D. Kubicki, P. Zarzycki, P. Sobota, J. Lewiński
    Academic press:
    Chemistry – a European Journal (rok: 2014, tom: 20, strony: 14790–14799), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201403851 - link to the publication
  18. Toward Factors Affecting the Degree of Zinc Alkyls Oxygenation: A Case of Organozinc Guanidinate Complexes.
    Authors:
    M.K. Leszczyński, I. Justyniak, J. Lewiński
    Academic press:
    Organometallics (rok: 2017, tom: 36 (13), strony: 2377–2380), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.organomet.7b00287 - link to the publication

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