Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Olefin metathesis and more. Development of new catalysts and methodology.

2012/04/A/ST5/00594

Keywords:

catalysis metathesis organometalic chemistry carbenes

Descriptors:

  • ST5_18:
  • ST5_23:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Warszawski, Wydział Chemii

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Karol Grela 

Number of co-investigators in the project: 6

Call: MAESTRO 2 - announced on 2011-12-15

Amount awarded: 2 796 500 PLN

Project start date (Y-m-d): 2012-10-16

Project end date (Y-m-d): 2017-10-15

Project duration:: 60 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. autoklaw (20 000 PLN)
  2. drukarka.
  3. komputer stacjonarny do wykonywania obliczeń (7 000 PLN)
  4. mieszadło magnetyczne z oprzyrządowaniem (15 000 PLN)
  5. chromatograf cieczowy z autosamplerem i oprzyrządowaniem.
  6. pompa próżniowa membranowa z oprzyrządowaniem (20 000 PLN)
  7. pompa olejowa RZ6 z oprzyrządowaniem (38 000 PLN)
  8. komputer stacjonarny.
  9. carousel station (20 000 PLN)
  10. chromatograf gazowy (200 000 PLN)

Information in the final report

  • Publication in academic press/journals (20)
  1. Azoliniums, Adducts, NHCs and Azomethine Ylides: Divergence in Wanzlick Equilibrium and Olefin Metathesis Catalyst Formation
    Authors:
    Phillip Iain Jolly, Anna Marczyk, Paweł Małecki, Osman Ablialimov, Damian Trzybiński, Krzysztof Woźniak, Silvio Osella, Bartosz Trzaskowski, Karol Grela
    Academic press:
    Chemistry—A European Journal (rok: 2018, tom: 24, strony: 4785-4789), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201706036 - link to the publication
  2. Ruthenium Amide Complexes – Synthesis and Catalytic Activity in Olefin Metathesis and in Ring‐Opening Polymerisation
    Authors:
    Anna Gawin, Eva Pum, Christian Slugovc, Anna Kajetanowicz, Karol Grela
    Academic press:
    European Journal of Inorganic Chemistry (rok: 2018, tom: 16, strony: 1766-1774), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejic.201800251 - link to the publication
  3. In quest for selectivity paired with activity: a ruthenium olefin metathesis catalyst bearing unsymmetrical phenanthrene based NHC
    Authors:
    Michał Dąbrowski, Przemysław Wyrębek, Damian Trzybiński, Krzysztof Woźniak, Karol Grela*
    Academic press:
    Chemistry - A European Journal (rok: 2020, ), Wydawca: Wiley-VCH
    Status:
    Accepted for publication
    DOI:
    brak - link to the publication
  4. Formation of tetrasubstituted C–C double bonds via olefin metathesis: challenges, catalysts, and applications in natural product synthesis (Przegląd)
    Authors:
    Nirmalya Mukherjee, Sebastian Planer, Karol Grela
    Academic press:
    Organic Chemistry Frontiers (rok: 2018, tom: 5, strony: 494-516), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C7QO00800G - link to the publication
  5. Hoveyda – Grubbs catalyst analogues bearing the derivatives of N -phenylpyrrol in the carbene ligand – structure, stability, activity and unique ruthenium – phenyl interactions
    Authors:
    Krzysztof Grudzień, Bartosz Trzaskowski, Michał Smoleń, Roman Gajda, Krzysztof Woźniak, Karol Grela
    Academic press:
    Dalton Transactions (rok: 2017, tom: 46, strony: 11790-11799), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C7DT02180A - link to the publication
  6. Phenanthrene based NHC, ruthenium complex as effective olefin metathesis catalyst (w rewizji, z pozytywnymi recenzjami)
    Authors:
    Michał Dąbrowsk, Przemysław Wyrębek, Damian Trzybiński, Krzysztof Woźniak, Karol Grela
    Academic press:
    Chemistry—A European Journal , Wydawca: Wiley
    Status:
    Submitted
    DOI:
    brak - link to the publication
  7. At Long Last: Olefin Metathesis Macrocyclization at High Concentration
    Authors:
    Adrian Sytniczuk, Michał Dąbrowski, Łukasz Banach, Mateusz Urban, Sylwia Czarnocka-Śniadała, Mariusz Milewski, Anna Kajetanowicz, Karol Grela
    Academic press:
    Journal of the American Chemical Society (rok: 2018, tom: 140, strony: 8895-8901), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/jacs.8b04820 - link to the publication
  8. Chelating Ruthenium Phenolate Complexes: Synthesis, General Catalytic Activity, and Applications in Olefin Metathesis Polymerization
    Authors:
    Anna Kozłowska, Maciej Dranka, Janusz Zachara, Eva Pump, Christian Slugovc, Krzysztof Skowerski, Karol Grela
    Academic press:
    Chemistry A European Journal (rok: 2014, tom: 20, strony: 14120-14125), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201403580 - link to the publication
  9. Specialized Ruthenium Olefin Metathesis Catalysts Bearing Bulky Unsymmetrical NHC Ligands: Computations, Synthesis, and Application
    Authors:
    Paweł Małecki, Katarzyna Gajda, Roman Gajda, Krzysztof Woźniak, Bartosz Trzaskowski, Anna Kajetanowicz, Karol Grela
    Academic press:
    ACS Catalysis (rok: 2019, tom: 9, strony: 587-598), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acscatal.8b04783 - link to the publication
  10. 2-Methyltetrahydrofuran as a Solvent of Choice for Spontaneous Metathesis/Isomerization Sequence
    Authors:
    Adam A. Rajkiewicz, Krzysztof Skowerski, Bartosz Trzaskowski, Anna Kajetanowicz, Karol Grela
    Academic press:
    ACS Omega (rok: 2019, tom: 4, strony: 1831-1837), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acsomega.8b03027 - link to the publication
  11. An unexpected formation of a Ru(III) benzylidene complex during activation of a LatMet-type ring-opening polymerisation catalyst
    Authors:
    Anna Gawin, Paweł Małecki, Maciej Dranka, Janusz Zachara, Magdalena Skompska, Anna Kajetanowicz, Karol Grela
    Academic press:
    Journal of Catalysis (rok: 2018, tom: 364, strony: 345-353), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jcat.2018.05.014 - link to the publication
  12. Expanding the Family of Hoveyda−Grubbs Catalysts Containing Unsymmetrical NHC Ligands
    Authors:
    Veronica Paradiso, Valerio Bertolasi, Chiara Costabile, Tonino Caruso, Michał Dąbrowski, Karol Grela, Fabia Grisi
    Academic press:
    Organometallics (rok: 2017, tom: 36, strony: 3692-3708), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.organomet.7b00488 - link to the publication
  13. Gold(I) catalyzed formation of naphthalene/acenaphthene heterocy-clic acetals. Total synethesis of fuliginone.
    Authors:
    Malina Michalska, Krzysztof Grudzień, Paweł Małecki, Karol Grela
    Academic press:
    Organic Letters (rok: 2018, tom: 20, strony: 954-957), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.orglett.7b03856 - link to the publication
  14. Helicenes as chirality inducing groups in transition metal catalysis: the first helically chiral olefin metathesis catalyst
    Authors:
    Manfred Karras, Michał Dąbrowski, Radek Pohl, Jiří Rybáček, Jaroslav Vacek, Lucie Bednárová, Karol Grela, Ivo Starý, Irena G. Stará, Bernd Schmidt
    Academic press:
    Chemistry—A European Journal (rok: 2018, tom: 24, strony: 10994-10998), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201802786 - link to the publication
  15. Hoveyda-Grubbs-type Pre-catalysts with Unsymmetrical NHeterocyclic Carbenes as Effective Catalysts in Olefin Metathesis
    Authors:
    Paweł Małecki, Katarzyna Gajda, Osman Ablialimov, Maura Malińska, Roman Gajda, Krzysztof Woźniak, Anna Kajetanowicz, Karol Grela
    Academic press:
    Organometallics (rok: 2017, tom: 36, strony: 2153−2166), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.organomet.7b00211 - link to the publication
  16. Rational and Then Serendipitous Formation of Aza-Analogues of Hoveyda-type Catalysts Containing a Chelating Ester Group Leading to a HeatMet TM Polymerisation Catalyst
    Authors:
    Stefan J. Czarnocki, Izabela Czeluśniak, Tomasz K. Olszewski, Maura Malinska, Krzysztof Woźniaka i Karol Grela
    Academic press:
    ACS Catalysis (rok: 2017, tom: 7, strony: 4115−4121), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acscatal.7b00843 - link to the publication
  17. Well-Defined Chiral Copper NHC Complex in the Asymmetric Conjugated b-Borylation and One-Pot Metathesis-Asymmetric b-Borylation Reactions
    Authors:
    Anupam Jana, Damian Trzybiński, Krzysztof Woźniak, Karol Grela
    Academic press:
    Chemistry - A European Journal (rok: 2017, tom: 24, strony: 891-897), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/chem.201704335 - link to the publication
  18. Initiation efficacy of halo-chelated cis-dichloro configured ruthenium complexes in Ring-opening Metathesis Polymerization
    Authors:
    Wappel, J.; Grudzień, K.; Barbasiewicz, M.; Michalak, M.; Grela, K.; Slugovc, C.
    Academic press:
    Monatshefte für Chemie (rok: 2015, tom: 146, strony: 1153-1160), Wydawca: Springer
    Status:
    Published
    DOI:
    10.1007/s00706-015-1494-8 - link to the publication
  19. Mild Functionalization of Tetraoxane Derivatives via Olefin Metathesis: Compatibility of Ruthenium Alkylidene Catalysts with Peroxides
    Authors:
    Anupam Jana, Karol Grela
    Academic press:
    Organic Letters (rok: 2017, tom: 19, strony: 520-523), Wydawca: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.orglett.6b03688 - link to the publication
  20. Unexpected formation of nitroso-chelated cyclic η1-acylruthenium(II) complex, an effective catalysts for transfer hydrogenation reaction
    Authors:
    Nirmalya Mukherjee, Rafał Gawin, Stefan Czarnocki, Roman Gajda, Maura Malińska, Krzysztof Woźniak, Anna Kajetanowicz, Karol Grela
    Academic press:
    Journal of Organometallic Chemistry (rok: 2018, tom: 867, strony: 359-366), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jorganchem.2018.01.035 - link to the publication

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