Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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Physicochemical properties and mechanisms of temperature- and pressure-induced phase transitions in multiferroic metal-organic frameworks (MOFs)

2011/03/B/ST5/01019

Keywords:

multiferroics phase transitions Raman scattering infrared spectroscopy

Descriptors:

  • ST5_8: Metals, alloys
  • ST4_3: Molecular architecture and structure
  • ST3_18:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Instytut Niskich Temperatur i Badań Strukturalnych im. Włodzimierza Trzebiatowskiego PAN

woj. dolnośląskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Mirosław Mączka 

Number of co-investigators in the project: 7

Call: OPUS 2 - announced on 2011-09-15

Amount awarded: 414 900 PLN

Project start date (Y-m-d): 2012-08-30

Project end date (Y-m-d): 2015-06-29

Project duration:: 34 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. komora do badań widm Ramana w funkcji ciśnienia - mScopeDAC HT(S) firmy Diacell, wyposażona w kowadełka diamentowe typu 1a ULF i wewnętrzny grzejnik (53 000 PLN)
  2. rozbudowa mikroskopu konfokalnego firmy Renishow o możliwość pomiaru w zakresie niskich częstości (filtr NExT) (112 000 PLN)

Information in the final report

  • Publication in academic press/journals (13)
  1. Unusual Electronic Behavior in the Polycrystalline Metal Organic Framework [(CH3)2NH2][Na0.5Fe0.5(HCOO)3]
    Authors:
    Adam Sieradzki, Justyna Trzmiel, Maciej Ptak, and Mirosław Mączka
    Academic press:
    Electronic Materials Letters (rok: 2015, tom: 11, strony: 1033-1039), Wydawca: Springer
    Status:
    Published
    DOI:
    10.1007/s13391-015-5105-y - link to the publication
  2. Infrared and Raman studies of phase transitions in metal-organic frameworks of [(CH3)2NH2][M(HCOO)3] with M=Zn, Fe
    Authors:
    M. Mączka, M. Ptak, L. Macalik
    Academic press:
    Vibrational Spectroscopy (rok: 2014, tom: 71, strony: 98-104), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.vibspec.2014.01.013 - link to the publication
  3. Order−Disorder Transition and Weak Ferromagnetism in the Perovskite Metal Formate Frameworks of [(CH3)2NH2][M(HCOO)3] and [(CH3)2ND2][M(HCOO)3] (M = Ni, Mn)
    Authors:
    Mirosław Mączka, Anna Gągor, Bogusław Macalik, Adam Pikul, Maciej Ptak, and Jerzy Hanuza
    Academic press:
    Inorganic Chemistry (rok: 2014, tom: 53, strony: 457-467), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/ic402425n - link to the publication
  4. Structure, Phonon Properties, and Order–Disorder Transition in the Metal Formate Framework of [NH4][Mg(HCOO)3]
    Authors:
    Mirosław Mączka, Adam Pietraszko, Bogusław Macalik, and Krzysztof Hermanowicz
    Academic press:
    Inorganic Chemistry (rok: 2014, tom: 53, strony: 787-794), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/ic4020702 - link to the publication
  5. Synthesis and order–disorder transition in a novel metal formate framework of [(CH3)2NH2]- Na0.5Fe0.5(HCOO)3]
    Authors:
    Mirosław Mączka, Adam Pietraszko, Lucyna Macalik, Adam Sieradzki, Justyna Trzmiel and Adam Pikul
    Academic press:
    Dalton Transactions (rok: 2014, tom: 43, strony: 17075-17084), Wydawca: Royal Chemical Society
    Status:
    Published
    DOI:
    10.1039/c4dt02586e - link to the publication
  6. Vibrational properties and DFT calculations of formamidine-templated Co and Fe formates
    Authors:
    E. Kucharska, J. Hanuza, A. Ciupa, M. Mączka, L. Macalik
    Academic press:
    Vibrational Spectroscopy (rok: 2014, tom: 75, strony: 45-50), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.vibspec.2014.09.001 - link to the publication
  7. Brillouin scattering study of ferroelectric transition mechanism in multiferroic metalorganic frameworks of [NH4][Mn(HCOO)3] and [NH4][Zn(HCOO)3]
    Authors:
    Mirosław Mączka, Maciej Ptak,Seiji Kojima
    Academic press:
    Applied Physics Letters (rok: 2014, tom: 104, strony: 222903), Wydawca: American Institute of Physics
    Status:
    Published
    DOI:
    10.1063/1.4880815 - link to the publication
  8. Comparative studies of vibrational properties and phase transitions in metal-organic frameworks of [NH4][M(HCOO)3] with M = Mg, Zn, Ni, Fe, Mn
    Authors:
    M. Mączka, K. Szymborska-Małek, A. Ciupa, J. Hanuza
    Academic press:
    Vibrational Spectroscopy (rok: 2015, tom: 77, strony: 17-24), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.vibspec.2015.02.003 - link to the publication
  9. Perovskite Metal Formate Framework of [NH2‑CH+‑NH2]Mn(HCOO)3]: Phase Transition, Magnetic, Dielectric, and Phonon Properties
    Authors:
    Mirosław Mączka, Aneta Ciupa, Anna Gągor, Adam Sieradzki, Adam Pikul, Bogusław Macalik, and Marek Drozd
    Academic press:
    Inorganic Chemistry (rok: 2014, tom: 53, strony: 5260-5268), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/ic500479e - link to the publication
  10. Temperature- and Pressure-Induced Phase Transitions in the Metal Formate Framework of [ND4][Zn(DCOO)3] and [NH4][Zn(HCOO)3]
    Authors:
    Mirosław Mączka, Paweł Kadłubański, Paulo Tarso Cavalcante Freire, Bogusław Macalik, Waldeci Paraguassu, Krysztof Hermanowicz, and Jerzy Hanuza
    Academic press:
    Inorganic Chemistry (rok: 2014, tom: 53, strony: 9615-9624), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/ic501074x - link to the publication
  11. Vibrational properties and DFT calculations of the perovskite metal formate framework of [(CH3)2NH2][Ni(HCOO3)] system
    Authors:
    M. Mączka, D. Michalska, W. Zierkiewicz, and J. Hanuza
    Academic press:
    Spectrochimica Acta A (rok: 2014, tom: 128, strony: 674-680), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.saa.2014.03.006 - link to the publication
  12. Synthesis and characterization of [(CH3)2NH2][Na0.5Cr0.5(HCOO)3]: a rare example of luminescent metal–organic frameworks based on Cr(III) ions
    Authors:
    Mirosław Mączka, Bartosz Bondzior, Przemysław Dereń, Adam Sieradzki, Justyna Trzmiel, Adam Pietraszko and J. Hanuza
    Academic press:
    Dalton Transactions (rok: 2015, tom: 44, strony: 6871-6879), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c5dt00060b - link to the publication
  13. Synthesis, crystal structure, magnetic and vibrational properties of formamidine-templated Co and Fe formates
    Authors:
    Aneta Ciupa, Mirosław Mączka, Anna Gągor, Adam Pikul, Edyta Kucharska, Jerzy Hanuza, Adam Sieradzki
    Academic press:
    Polyhedron (rok: 2015, tom: 85, strony: 137-143), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.poly.2014.08.008 - link to the publication

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