Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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AgCENT: novel unique magnetic and electronic materials based on the compounds of divalent silver

2011/01/B/ST5/06673

Keywords:

silver fluorine magnetism electronic structure oxidizers

Descriptors:

  • ST5_2: Solid-state materials
  • ST5_8: Metals, alloys
  • ST5_24:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Warszawski, Centrum Nowych Technologii

woj. mazowieckie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Wojciech Grochala 

Number of co-investigators in the project: 21

Call: OPUS 1 - announced on 2011-03-15

Amount awarded: 931 900 PLN

Project start date (Y-m-d): 2011-12-27

Project end date (Y-m-d): 2015-12-26

Project duration:: 48 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. laptop Apple, DELL (34 000 PLN)
  2. licencje.
  3. działo jonowe.
  4. mieszadło z płytą grzejną.
  5. oprogramowanie MS Office Std, MS Office for Mac 2011.
  6. wózek na butle.
  7. zestaw wejściowy gazu do działa jonowego.
  8. generator ozonu (36 000 PLN)

Information in the final report

  • Publication in academic press/journals (14)
  • Book publications / chapters in book publications (1)
  1. Anomalous Chemical Shifts in X-ray Photoelectron Spectra of Sulfur-Containing Compounds of Silver (I) and (II)
    Authors:
    Grzelak A, Jaroń T, Mazej Z, Michałowski T, Szarek P, Grochala W
    Academic press:
    J ELECTR SPECTR REL PHENOM (rok: 2015, tom: 202, strony: 38-45), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.elspec.2015.02.013 - link to the publication
  2. Stabilization and strong oxidizing properties of Ag(II) in a fluorine-free solvent
    Authors:
    Połczyński P, Jurczakowski R, Grochala W
    Academic press:
    CHEM COMMUN (rok: 2013, tom: 49(68), strony: 7480-7482), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/C3CC43072C - link to the publication
  3. The first example of a mixed valence ternary compound of silver with random distribution of Ag(I) and Ag(II) cations
    Authors:
    Mazej Z, Michałowski T, Goreshnik E, Jagličić Z, Arčon I, Szydłowska J, Grochala W
    Academic press:
    DALTON TRANS (rok: 2015, tom: 44(24), strony: 10957-10968), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/C5DT00740B - link to the publication
  4. Ag(I)S2O6CF3: the first trifluoromethylsulfonylsulfate(VI)
    Authors:
    Malinowski P, Derzsi M, Grochala W
    Academic press:
    DALTON TRANS (rok: 2013, tom: 42(29), strony: 10417-10423), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/c3dt50473e - link to the publication
  5. New Ag(F1–xClx)y phases for energy storage applications
    Authors:
    Adamczyk W, Połczyński P, Mika A, Jaroń T, Mazej Z, Fijałkowski KJ, Jurczakowski R, Grochala W
    Academic press:
    J FLUOR CHEM (rok: 2015, tom: 174, strony: 22-29), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jfluchem.2014.09.004 - link to the publication
  6. Redetermination of crystal structure of Ag(II)SO4 and its high pressure behavior up to 30 GPa
    Authors:
    Derzsi M, Budzianowski A, Struzhkin VV, Malinowski PJ, Leszczyński PJ, Mazej Z, Grochala W
    Academic press:
    CRYSTENGCOMM (rok: 2013, tom: 15(1), strony: 192-198), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/C2CE26282G - link to the publication
  7. Strong cationic oxidizers: thermal decomposition, electronic structure and magnetism of their compounds
    Authors:
    Leszczyński PJ, Grochala W
    Academic press:
    ACTA CHIM SLOVEN (rok: 2013, tom: 60(3), strony: 455-470), Wydawca: Slow. Tow. Chem.
    Status:
    Published
    DOI:
    brak - link to the publication
  8. Structural transition and unusually strong 1D antiferromagnetic superexchange coupling in perovskite KAgF3
    Authors:
    Kurzydłowski D, Mazej Z, Jagličić Z, Filinchuk Y, Grochala W
    Academic press:
    CHEM COMMUN (rok: 2013, tom: 49(56), strony: 6262-6264), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/C3CC41521J - link to the publication
  9. Chemistry of Ag(II): a cornucopia of peculiarities
    Authors:
    Grochala W, Mazej Z
    Academic press:
    PHIL TRANS A (rok: 2015, tom: 373(3), strony: 20140179 1-12), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1098/rsta.2014.0179 - link to the publication
  10. Strong and long-lived free-radical oxidizer based on silver(II). Mechanism of Ag(I) electrooxidation in concentrated H2SO4
    Authors:
    Połczyński P, Jurczakowski R, Grochala W
    Academic press:
    J PHYS CHEM C (rok: 2013, tom: 117(40), strony: 20689-20696), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/jp406442j - link to the publication
  11. The missing crystal structures of fluorosulfates of monovalent cations: M(I)SO3F, M=Na, Rb and Tl
    Authors:
    Michałowski T, Leszczyński PJ, Cyrański M, Dobrzycki Ł, Budzianowski A, Grochala W
    Academic press:
    J FLUOR CHEM (rok: 2012, tom: 140, strony: 116-120), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jfluchem.2012.05.004 - link to the publication
  12. AgPO2F2 and Ag9(PO2F2)14 – the first Ag(I) and Ag(I)/Ag(II) difluorophosphates with complex crystal structures
    Authors:
    Malinowski PJ, Kurzydłowski D, Grochala W
    Academic press:
    DALTON TRANS (rok: 2015, tom: 44(45), strony: 19395–19734), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/C5DT02004B - link to the publication
  13. The close relationships between the crystal structures of MO and MSO4 compounds (M= Group 10, 11 or 12 metal), and predicted structures for AuO and PtSO4
    Authors:
    Derzsi M, Hermann A, Hoffmann R, Grochala W
    Academic press:
    EUR J INORG CHEM (rok: 2013, tom: -29, strony: 5095-5102), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejic.201300769 - link to the publication
  14. Unexpectedly complex crystalline phases in the MSO3F–Ag(SO3F)2 phase diagram (M=Na, K, Rb, Cs)
    Authors:
    Michałowski T, Mazej Z, Budzianowski A, Jagličić Z, Leszczyński PJ, Grochala W
    Academic press:
    EUR J INORG CHEM (rok: 2015, tom: 215(2), strony: 324-332), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejic.201402948 - link to the publication
  1. Unique silver(II) fluorides: the emerging electronic and magnetic materials
    Authors:
    Mazej Z, Kurzydłowski D, Grochala W
    Book:
    Photonic and Electronic Properties of Fluoride Materials (rok: 2015, ), Wydawca: Elsevier, Eds. A. Tressaud & K. Poeppelmeier
    Status:
    Accepted for publication

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