Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Design and functionalization of hybrid coordination polymers

2011/01/B/ST5/00716

Keywords:

multifunctional materials crystal engineering structure-properties correlations

Descriptors:

  • ST5_12: Methods of nanomaterials/materials synthesis
  • ST5_8: Metals, alloys
  • ST5_2: Solid-state materials

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Jagielloński, Wydział Chemii

woj. małopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Barbara Sieklucka 

Number of co-investigators in the project: 16

Call: OPUS 1 - announced on 2011-03-15

Amount awarded: 976 500 PLN

Project start date (Y-m-d): 2011-12-12

Project end date (Y-m-d): 2014-12-11

Project duration:: 36 months (the same as in the proposal)

Project status: Project settled

Equipment purchased [PL]

  1. Mikroskop stereoskopowy z oświetleniem przechodzącym i odbitym (8 000 PLN)
  2. autoklaw ciśnieniowy do syntez w układzie zamkniętym w temperaturze pokojowej (2 406 PLN)
  3. uzupełnienie wyposażenia komory rękawicowej typu Glove-box: śluza cylindryczna mała oraz detektor wilgoci (40 000 PLN)
  4. pompa próżniowa membranowa odporna na chemikalia.
  5. Przystawka cisnieniowa przeznaczona do współpracy z magnetometrem SQUID (HMD pressure cell for MPMS) (45 000 PLN)
  6. diody laserowe 405 i 488 nm z elementami adaptacyjnymi (30 000 PLN)
  7. wagi laboratoryjne (2 szt.) (8 000 PLN)
  8. Zestaw do syntez solwotermalnych: dwa reaktory wysokociśnieniowe oraz oporowy piec muflowy (20 000 PLN)

Information in the final report

  • Publication in academic press/journals (29)
  1. "Co-NC-W and Fe-NC-W Electron-Transfer Channels for Thermal Bistability in Trimetallic {Fe6Co3[W(CN)8]6} Cyanido-Bridged Cluster"
    Authors:
    R. Podgajny, S. Chorazy, W. Nitek, M. Rams, A. M. Majcher, B. Marszałek, J. Żukrowski, C. Kapusta, B. Sieklucka
    Academic press:
    Angew. Chem. Int. Ed. (rok: 2013, tom: 52, strony: 896-900), Wydawca: Wiley & Sons
    Status:
    Published
    DOI:
    10.1002/anie.201208023 - link to the publication
  2. "Magnetic Systems at Criticality: Different Signatures of Scaling"
    Authors:
    R. Pełka, P. Konieczny, M. Fitta, M. Czapla, P. M. Zieliński, M. Bałanda, T. Wasiutyński, Y. Miyazaki, A. Inaba, D. Pinkowicz, B. Sieklucka
    Academic press:
    Acta Physica Polonica A (rok: 2013, tom: 124, strony: 977-989), Wydawca: Institut of Physics, Polish Academy of Sciences/Instytut Fizyki Polskiej Akademii Nauk
    Status:
    Published
    DOI:
    10.12693/APhysPolA.124.977 - link to the publication
  3. "Magnetic anisotropy of CoII-WV ferromagnet: single crystal and ab initio study"
    Authors:
    S. Chorazy, R. Podgajny, A. M. Majcher, W. Nitek, M. Rams, E. A. Suturina, L. Ungur, L. F. Chibotaru, B. Sieklucka
    Academic press:
    Cryst. Eng. Comm. (rok: 2013, tom: 15, strony: 2378-2385), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c2ce26387d - link to the publication
  4. "Magnetocaloric effect and critical behaviour in Mn2-pyridazine-[Nb(CN)8] molecular compound under pressure"
    Authors:
    M. Fitta, M. Bałanda, R. Pełka, P. Konieczny, D. Pinkowicz, B. Sieklucka
    Academic press:
    J. Phys.: Condens. Matter (rok: 2013, tom: 25, strony: 496012(1-6)), Wydawca: IOP Publishing Ltd
    Status:
    Published
    DOI:
    10.1088/0953-8984/25/49/496012 - link to the publication
  5. "Source of magnetic anisotropy in quasi-two-dimensional XY {Cu4(tetrenH5)W(CN)8]4•7.2H2O)}n bilayer molecular magnet"
    Authors:
    O. Zaharko, M. Pregelj, A. Zorko, R. Podgajny, A. Gukasov, J. van Tol, S. I. Klokishner, S. Ostrovsky, B. Delley
    Academic press:
    Phys. Rev. B (rok: 2013, tom: 87, strony: 024406(1-6)), Wydawca: American Physical Society
    Status:
    Published
    DOI:
    10.1103/PhysRevB.87.024406 - link to the publication
  6. "Supramolecular Chains and Coordination Nanowires Constructed of High-Spin CoII9WV6 Clusters and 4,4'-bpdo Linkers"
    Authors:
    S. Chorazy, R. Podgajny, W. Nitek, M. Rams, S. Ohkoshi, B. Sieklucka
    Academic press:
    Cryst. Growth Des. (rok: 2013, tom: 13, strony: 3036-3045), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/cg400448x - link to the publication
  7. A single chain magnet involving hexacyanoosmate
    Authors:
    E. V. Peresypkina, A. M. Majcher, M. Rams, K. E. Vostrikova
    Academic press:
    Chemical Communications (rok: 2014, tom: 50, strony: 7150-7153), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c3cc48972h - link to the publication
  8. Cyclams with varied degree of protonation in the assemblies with cyano complexes of Mo and W
    Authors:
    Beata Nowicka, Mateusz Reczyński, Wojciech Nitek, Barbara Sieklucka
    Academic press:
    Polyhedron (rok: 2012, tom: 47 (1), strony: 73-78), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.poly.2012.08.020 - link to the publication
  9. Magnetic clusters based on octacyanidometallates
    Authors:
    Dawid Pinkowicz, Robert Podgajny, Beata Nowicka, Szymon Chorazy, Mateusz Reczyński and Barbara Sieklucka
    Academic press:
    Inorganic Chemistry Frontiers (rok: 2015, tom: 2, strony: 45592), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c4qi00189c - link to the publication
  10. Role of pyrazine- N,N'-dioxide in [W(CN)8]n--based hybrid networks: Anion-π interactions
    Authors:
    R. Podgajny, D. Pinkowicz, B. Czarnecki, M. Kozieł, S. Chorazy, M. Wis, W. Nitek, M. Rams, B. Sieklucka
    Academic press:
    Crystal Growth & Design (rok: 2014, tom: 14, strony: 4030-4040), Wydawca: The American Chemical Society
    Status:
    Published
    DOI:
    10.1021/cg500636m - link to the publication
  11. Magnetocaloric effect in M-pyrazole-[Nb(CN)8] (M = Ni, Mn) molecular compounds
    Authors:
    Magdalena Fitta, Maria Bałanda, Marian Mihalik, Robert Pełka, Dawid Pinkowicz, Barbara Sieklucka, Maria Zentkova
    Academic press:
    Journal of Physics: Condensed Matter (rok: 2012, tom: 24, strony: 506002), Wydawca: IOP Publishing
    Status:
    Published
    DOI:
    10.1088/0953-8984/24/50/506002 - link to the publication
  12. Charge Transfer Phase Transition with Reversed Thermal Hysteresis Loop in the Mixed-Valence Fe9[W(CN)8]6•xMeOH Cluster
    Authors:
    S. Chorazy, R. Podgajny, W. Nogaś, W. Nitek, M. Kozieł, M. Rams, E. Juszyńska-Gałązka, J. Żukrowski, Cz. Kapusta, K. Nakabayashi, T. Fujimoto, S. Ohkoshi, B. Sieklucka
    Academic press:
    Chemical Communications (rok: 2014, tom: 49, strony: 3484-3487), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c3cc48029a - link to the publication
  13. Chiral (LH)2L2Cu3 Trinuclear Paramagnetic Nodes in Octacyanidometalate-Bridged Helical Chains
    Authors:
    O. Stefańczyk, M. Rams, A. M. Majcher, C. Mathoniere, B. Sieklucka
    Academic press:
    Inorganic Chemistry (rok: 2014, tom: 53, strony: 3874-3879), Wydawca: The American Chemical Society
    Status:
    Published
    DOI:
    10.1021/ic500271f - link to the publication
  14. Geometrical isomerism in pentadecanuclear high-spin Ni9W6 clusters with symmetrical bidentate ligands detected
    Authors:
    Beata Nowicka, Katarzyna Stadnicka, Wojciech Nitek, Michał Rams, Barbara Sieklucka
    Academic press:
    CrystEngComm (rok: 2012, tom: 14, strony: 6559-6564), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C2CE25537E - link to the publication
  15. High-pressure single-crystal XRD and magnetic study of the octacyanoniobate-based magnetic sponge
    Authors:
    Dawid Pinkowicz, Katarzyna Kurpiewska, Krzysztof Lewiński, Maria Bałanda, Marian Mihalik, Maria Zentková, Barbara Sieklucka
    Academic press:
    CrystEngComm (rok: 2012, tom: 14, strony: 5224-5229), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C2CE25387A - link to the publication
  16. X-ray Absorption Spectroscopy Study of Novel Inorganic-organic Hybrid Ferromagnetic Cu-pyz-[M(CN)8]3- Assemblies
    Authors:
    Olaf Stefanczyk, Robert Podgajny, Tomasz Korzeniak, Michał Rams, Marcin Kozieł, Wiesław Łasocha, Dariusz A. Zając, Barbara Sieklucka
    Academic press:
    Inorganic Chemistry (rok: 2012, tom: 51, strony: 11722–11729), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/ic301634m - link to the publication
  17. Critical behavior of the Mn2[Nb(CN)8] molecular magnet
    Authors:
    Robert Pełka, Mariusz Czapla, Piotr M. Zieliński, Magdalena Fitta, Maria Bałanda, Dawid Pinkowicz, Francis L. Pratt, Marian Mihalik, Janusz Przewoźnik, Alex Amato, Barbara Sieklucka, Tadeusz Wasiutyński
    Academic press:
    Physical Review B (rok: 2012, tom: 85, strony: Nr 224427), Wydawca: American Physical Society
    Status:
    Published
    DOI:
    10.1103/PhysRevB.85.224427 - link to the publication
  18. Multifunctionality in Bimetallic LnIII[WV(CN)8]3- (Ln=Gd, Nd) Coordination Helices: Optical Activity, Luminescence, and Magnetic Coupling
    Authors:
    S. Chorazy, K. Nakabayashi, M. Arczyński, R. Pełka, S. Ohkoshi, B. Sieklucka
    Academic press:
    Chemistry - A European Journal (rok: 2014, tom: 20, strony: 7144-7159), Wydawca: Wiley & Sons
    Status:
    Published
    DOI:
    10.1002/chem.201304772 - link to the publication
  19. "A water sensitive ferromagnetic [Ni(cyclam)]2[Nb(CN)8] network"
    Authors:
    B. Nowicka, M. Bałanda, M. Reczyński, A. M. Majcher, M. Kozieł, W. Nitek, W. Łasocha, B. Sieklucka
    Academic press:
    Dalton Trans. (rok: 2013, tom: 42, strony: 2616-2621), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c2dt32299d - link to the publication
  20. "Incorporation of guanidinium ions in CuII-[MV(CN)8]3- double-layered magnetic systems"
    Authors:
    Olaf Stefańczyk, Anna M. Majcher, Michał Rams, Wojciech Nitek, Marcin Kozieł, Wiesław Łasocha, Barbara Sieklucka
    Academic press:
    Dalton Trans. (rok: 2013, tom: 42, strony: 5042-5046), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c2dt32397d - link to the publication
  21. "Natural and Magnetic Optical Acitivity of 2-D Chiral Cyanido-Bridged MnII-NbIV Molecular Ferrimagnets"
    Authors:
    S. Chorazy, R. Podgajny, W. Nitek, T. Fic, E. Goerlich, M. Rams, B. Sieklucka
    Academic press:
    Chem.Commun. (rok: 2013, tom: 49, strony: 6731-6733), Wydawca: Royal Society Chemistry
    Status:
    Published
    DOI:
    10.1039/c3dt51727f - link to the publication
  22. "Thermal switching between blue and red luminescence in magnetic chiral cyanido-bridged EuIII-WV coordination helices"
    Authors:
    S. Chorazy, K. Nakabayashi, N. Ozaki, R. Pełka, T. Fic, J. Mlynarski, B. Sieklucka, S. Ohkoshi
    Academic press:
    RSC Adv. (rok: 2013, tom: 3, strony: 1065-1068), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/c2ra23033j - link to the publication
  23. Cesium Cyano-Bridged Co(II) - M(V) (M = Mo, W) Layered Frameworks Exhibitng High Thermal Durability and Metamagnetism
    Authors:
    K. Nakabayashi, S. Chorazy, D. Takahashi, T. Kinoshita, B. Sieklucka, S. Ohkoshi
    Academic press:
    Crystal Growth & Design (rok: 2014, tom: 14, strony: 6093−6100), Wydawca: The American Chemical Society
    Status:
    Published
    DOI:
    10.1021/cg501250p - link to the publication
  24. Conjunction of Chirality and Slow Magnetic Relaxation in the Supramolecular Network Constructed of Crossed Cyano-Bridged CoII-WV Molecular Chains
    Authors:
    Szymon Chorazy, Koji Nakabayashi, Kenta Imoto, Jacek Mlynarski, Barbara Sieklucka, Shin-ichi Ohkoshi
    Academic press:
    Journal of the American Chemical Society (rok: 2012, tom: 134, strony: 16151–16154), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/ja307520k - link to the publication
  25. Construction of CN--bridged molecular squares employing penta-, hexa- and octa- coordinated metal ions
    Authors:
    Tomasz Korzeniak, Beata Nowicka, Katarzyna Stadnicka, Wojciech Nitek, Anna M. Majcher, Barbara Sieklucka
    Academic press:
    Polyhedron (rok: 2013, tom: 52, strony: 442-447), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.poly.2012.08.053 - link to the publication
  26. Evidence for magnetic anisotropy of [NbIV(CN)8]4- in pillared-layered Mn2Nb framework showing spin-flop transition
    Authors:
    Dawid Pinkowicz, Michał Rams, Wojciech Nitek, Bernard Czarnecki, Barbara Sieklucka
    Academic press:
    Chemical Communications (rok: 2012, tom: 48, strony: 8323-8325), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C2CC32234J - link to the publication
  27. Green to Red Luminescence Switchable by Excitation Light in Cyanido-Bridged TbIII-WV Ferromagnet
    Authors:
    S. Chorazy, K. Nakabayashi, S. Ohkoshi, B. Sieklucka
    Academic press:
    Chemistry of Materials (rok: 2014, tom: 26, strony: 4072-4075), Wydawca: The American Chemical Society
    Status:
    Published
    DOI:
    10.1021/cm501954e - link to the publication
  28. Magnetocaloric effect in Mn2-pyridazine-[Nb(CN)8] molecular magnetic sponge
    Authors:
    Magdalena Fitta, Robert Pełka, Maria Bałanda, Mariusz Czapla, Marian Mihalik, Dawid Pinkowicz, Barbara Sieklucka, Tadeusz Wasiutyński, Maria Zentková
    Academic press:
    European Journal of Inorganic Chemistry (rok: 2012, tom: 14, strony: 3830-3834), Wydawca: Wiley
    Status:
    Published
    DOI:
    0.1002/ejic.201200374 - link to the publication
  29. The impact of ligands upon topology and functionality of octacyanidometallate-based assemblies
    Authors:
    Beata Nowicka, Tomasz Korzeniak, Olaf Stefańczyk, Dawid Pinkowicz, Szymon Chorąży, Robert Podgajny, Barbara Sieklucka
    Academic press:
    Coordination Chemistry Reviews (rok: 2012, tom: 256, strony: 1946-1971), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.ccr.2012.04.008 - link to the publication

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