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Nanoengineering of multivariate flexible metal-organic frameworks (flexMOFs) for separation processes: versatile experimental and theoretical approach

2020/36/C/ST4/00534

Keywords

Descriptors

  • ST4_011: Chemia koordynacyjna, supramolekularna
  • ST5_011: Materiały "inteligentne" – materiały samoorganizujące się, materiały reagujące na bodźce zewnętrzne
  • ST4_020: Chemia nieorganiczna

Panel

ST4 – Chemistry: physical chemistry/chemical physics, theoretical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, method development

Host institution

Uniwersytet im. Adama Mickiewicza w Poznaniu, Wydział Chemii

Voivodeship: wielkopolskie

Other projects carried out by the institution »

Principal investigator (from the host institution)

dr Kornel Roztocki

Number of co-investigators in the project: 8

Call

SONATINA 4 – announced on 2019-12-16

Amount awarded
759 792 PLN
Project start date
2020-11-05
Project end date
2025-05-04
Project duration
54 months (the same as in the proposal)
Project status
Project completed

Project description

Download the project description in a pdf file

Note — project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Information in the final report

Publication in academic press/journals (12)

  1. Combining In Situ Techniques (XRD, IR, and 13C NMR) and Gas Adsorption Measurements Reveals CO2-Induced Structural Transitions and High CO2/CH4 Selectivity for a Flexible Metal–Organic Framework JUK-8

    Authors:
    Kornel Roztocki*, Marcus Rauche, Volodymyr Bon, Stefan Kaskel, Eike Brunner, and Dariusz Matoga*
    Academic press:
    CS Appl. Mater. Interfaces (year: 2021, volume: 24, pages: 28503–28513), Publisher: ACS
    Status:
    Published
    DOI:
    10.1021/acsami.1c07268 – link to the publication

  2. Modulation of the Dynamics of a Two-Dimensional Interweaving Metal–Organic Framework through Induced Hydrogen Bonding

    Authors:
    Pilar Fernández-Seriñán, Kornel Roztocki, Vahid Safarifard, Vincent Guillerm, Sabina Rodríguez-Hermida, Judith Juanhuix, Inhar Imaz, Ali Morsali, Daniel Maspoch
    Academic press:
    Inorganic Chemistry (year: 2024, volume: XXXX, pages: XXXX), Publisher: ACS
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.3c04522 – link to the publication

  3. Tuning the guest-induced spatiotemporal response of isostructural dynamic frameworks towards efficient gas separation and storage

    Authors:
    Kornel Roztocki, Szymon Sobczak, Arkadiusz Smaruj, Anna Walczak, Mateusz Gołdyn, Volodymyr Bon, Stefan Kaskel, Artur R Stefankiewicz
    Academic press:
    Journal of Materials Chemistry A (year: 2023, volume: 11, pages: 18646-18650), Publisher: RSC
    Status:
    Published
    DOI:
    10.1039/D3TA02167J – link to the publication

  4. Multivariate Flexible Metal–Organic Frameworks and Covalent Organic Frameworks

    Authors:
    SK Sobczak, J Drwęska, W Gromelska, K Roztocki*, AM Janiak*,
    Academic press:
    Small (year: 2024, volume: 51, pages: 2402486), Publisher: Willey
    Status:
    Published
    DOI:
    10.1002/smll.202402486 – link to the publication

  5. Unveiling Temperature-Induced Structural Phase Transformations and CO2 Binding Sites in CALF-20

    Authors:
    H.2J Drwęska, F Formalik, K Roztocki*, RQ Snurr, LJ Barbour, AM Janiak*
    Academic press:
    Inorganic Chemistry (year: 2024, volume: 63 (41), pages: 19277-19286), Publisher: ACS
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.4c02952 – link to the publication

  6. * Advances in chemistry of CALF-20, a metal–organic framework for industrial gas applications

    Authors:
    J. Drwęska, K. Roztocki*, A.M. Janiak*
    Academic press:
    Chemical Communications (year: 2024, volume: 61 (6), pages: 1032-1047), Publisher: RSC
    Status:
    Published
    DOI:
    10.1039/D4CC05744A – link to the publication

  7. Shape-memory effect triggered by π-π interactions in a flexible terpyridine metal-organic framework

    Authors:
    Kornel Roztocki*, Wiktoria Gromelska, Filip Formalik, Alessia Giordana, Luca Andreo, Ghodrat Mahmoudi*, Volodymyr Bon, Stefan Kaskel, Leonard J. Barbour, Agnieszka Janiak, Emanuele Priola
    Academic press:
    ACS Materials Letters (year: 2023, volume: 0, pages: 0), Publisher: ACS
    Status:
    Published
    DOI:
    10.1021/acsmaterialslett.3c00068 – link to the publication

  8. A Logic Gate Based on a Flexible Metal–Organic Framework (JUK-8) for the Concomitant Detection of Hydrogen and Oxygen

    Authors:
    Kornel Roztocki,Volodymyr Bon, Irena Senkovska, Dariusz Matoga, Stefan Kaskel
    Academic press:
    Chemistry - A European Journal (year: 2022, volume: 28, pages: e202202255), Publisher: Willey
    Status:
    Published
    DOI:
    10.1002/chem.202202255 – link to the publication

  9. Quasicontinuous Cooperative Adsorption Mechanism in Crystalline Nanoporous Materials

    Authors:
    Bartosz Mazur, Filip Formalik, Kornel Roztocki, Volodymyr Bon, Stefan Kaskel, Alexander V. Neimark, Lucyna Firlej, and Bogdan Kuchta
    Academic press:
    The Journal of Physical Chemistry Letters (year: 2022, volume: 13, pages: 6961−6965), Publisher: ACS
    Status:
    Published
    DOI:
    10.1021/acs.jpclett.2c01752 – link to the publication

  10. Post‐Synthetic Modification of Aerogels Made of Covalent Cross‐linked Metal‐Organic Polyhedra

    Authors:
    Akim Khobotov‐Bakishev, Partha Samanta, Kornel Roztocki, Jorge Albalad, Sergio Royuela, Shuhei Furukawa, Félix Zamora, Arnau Carné‐Sánchez, Daniel Maspoch
    Academic press:
    Advanced Functional Materials (year: 2024, volume: 34, pages: 2312166), Publisher: Wiley
    Status:
    Published
    DOI:
    10.1002/adfm.202312166 – link to the publication

  11. Theoretical and Experimental Insights into the Spatial Distribution of Functional Groups in a Multivariate Flexible Metal–Organic Framework

    Authors:
    H.8K. Roztocki*, F. Formalik, V. Bon, A. Krawczuk, P. Goszczycki, B. Kuchta, S. Kaskel, and D. Matoga*
    Academic press:
    Chemistry of Materials (year: 2024, volume: 24, pages: 28503–28513), Publisher: ACS
    Status:
    Published
    DOI:
    10.1021/acs.chemmater.4c00406 – link to the publication

  12. Tuning adsorption-induced responsiveness of a flexible metal-organic framework JUK-8 by linker halogenation

    Authors:
    Kornel Roztocki[a,b]*, Filip Formalik[c,d], Volodymyr Bon[e], Anna Krawczuk[f,g], Piotr Goszczycki[g], Bogdan Kuchta,[c,h] Stefan Kaskel[e] , Dariusz Matoga[g]*
    Status:
    Accepted for publication

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Graphic design and implementation: Jakub Piotrowski