Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

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Design of new cross-coupling methods using earth-abundant metals - an effective way for sustainable synthesis

2019/35/D/ST4/00806

Keywords:

cross-coupling iron palladium 3d metals medicinal chemistry materials science

Descriptors:

  • ST4_014:
  • ST4_008:

Panel:

ST4 - Chemistry: physical chemistry/chemical physics, theoretical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, method development

Host institution :

Uniwersytet Opolski, Wydział Chemii

woj. opolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Elwira Maria Bisz 

Number of co-investigators in the project: 3

Call: SONATA 15 - announced on 2019-09-16

Amount awarded: 783 600 PLN

Project start date (Y-m-d): 2020-06-19

Project end date (Y-m-d): 2024-06-18

Project duration:: 48 months (the same as in the proposal)

Project status: Project completed

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Information in the final report

  • Publication in academic press/journals (12)
  1. CAAC–IPr*: easily accessible, highly sterically-hindered cyclic (alkyl)(amino)carbenes
    Authors:
    Wenchao Chu, Tongliang Zhou, Elwira Bisz, Błażej Dziuk, Roger Lalancette, Roman Szostak, Michal Szostak
    Academic press:
    Chemical Communications (), Wydawca: ROYAL SOC CHEMISTRY
    Status:
    Published
    DOI:
    10.1039/D2CC05668B - link to the publication
  2. Sequential iron catalyzed C(sp2)–C(sp3) cross-coupling of chlorobenzamides/chemoselective amide reduction and reductive deuteration to benzylic alcohols
    Authors:
    Elwira Bisz, Pamela Podchorodecka, Hengzhao Li, Wioletta Ochędzan-Siodłak, Jie An, Michal Szostak
    Academic press:
    Molecules (), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules28010223 - link to the publication
  3. Enhanced activity of bulky N-heterocyclic carbenes in nickel–NHC catalyzed Kumada–Corriu cross-coupling of aryl tosylates
    Authors:
    Marlena Kardela, Katarzyna Halikowska-Tarasek, Michal Szostak, Elwira Bisz
    Academic press:
    Catalysis Science & Technology (), Wydawca: ROYAL SOC CHEMISTRY
    Status:
    Published
    DOI:
    10.1039/D2CY01805E - link to the publication
  4. Cobalt−NHC catalyzed C(sp2)−C(sp3) and C(sp2)−C(sp2) Kumada cross-coupling of aryl tosylates with alkyl and aryl Grignard reagents
    Authors:
    Aleksandra Piontek, Wioletta Ochędzan Siodłak, Elwira Bisz, Michal Szostak
    Academic press:
    ChemCatChem (), Wydawca: WILEY-VCH VERLAG GMBH
    Status:
    Published
    DOI:
    10.1002/cctc.202001347 - link to the publication
  5. ItOct (ItOctyl) – pushing the limits of ItBu: highly hindered electron-rich N-aliphatic N-heterocyclic carbenes
    Authors:
    Md. Mahbubur Rahman, Guangrong Meng, Elwira Bisz, Błażej Dziuk, Roger Lalancette, Roman Szostak, Michal Szostak
    Academic press:
    Chemical Science (), Wydawca: ROYAL SOC CHEMISTRY
    Status:
    Published
    DOI:
    10.1039/D3SC01006F - link to the publication
  6. Palladium-NHC (NHC = N-heterocyclic Carbene)-Catalyzed Suzuki-Miyaura Cross-Coupling of Alkyl Amides
    Authors:
    Chang-An Wang, Md. Mahbubur Rahman, Elwira Bisz, Błażej Dziuk, Roman Szostak, Michal Szostak
    Academic press:
    ACS Catalysis (), Wydawca: AMERICAN CHEMICAL SOCIETY
    Status:
    Published
    DOI:
    10.1021/acscatal.1c05738 - link to the publication
  7. N -Butylpyrrolidone (NBP) as a non-toxic substitute for NMP in iron-catalyzed C(sp2)-C(sp3) cross-coupling of aryl chlorides
    Authors:
    Elwira Bisz, Martina Koston, Michal Szostak
    Academic press:
    Green Chemistry (), Wydawca: ROYAL SOC CHEMISTRY
    Status:
    Published
    DOI:
    10.1039/D1GC02377B - link to the publication
  8. Iron-catalyzed cross-coupling reactions of alkyl grignards with aryl chlorobenzenesulfonates
    Authors:
    Elwira Bisz
    Academic press:
    Molecules (), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules26195895 - link to the publication
  9. Well-defined, air- and moisture-stable palladium–imidazo[1,5-a]pyridin-3-ylidene complexes: a versatile catalyst platform for cross-coupling reactions by L-shaped NHC ligands
    Authors:
    Tongliang Zhou, Pengcheng Gao, Elwira Bisz, Błażej Dziuk, Roger Lalancette, Roman Szostak, Michal Szostak
    Academic press:
    Catalysis Science & Technology (), Wydawca: ROYAL SOC CHEMISTRY
    Status:
    Published
    DOI:
    10.1039/D2CY01136K - link to the publication
  10. N-Heterocyclic Carbene Complexes of Nickel(II) from Caffeine and Theophylline: Sustainable Alternative to Imidazol-2-ylidenes
    Authors:
    Jin Zhang, Md. Mahbubur Rahman, Qun Zhao, Jessica Feliciano, Elwira Bisz, Błażej Dziuk, Roger Lalancette, Roman Szostak, Michal Szostak
    Academic press:
    Organometallics (), Wydawca: AMERICAN CHEMICAL SOCIETY
    Status:
    Published
    DOI:
    10.1021/acs.organomet.2c00019 - link to the publication
  11. IPr*Oxa – a new class of sterically-hindered, wingtip-flexible N,C-chelating oxazole-donor N-heterocyclic carbene ligands
    Authors:
    Pamela Podchorodecka, Błażej Dziuk, Roman Szostak, Michal Szostak, Elwira Bisz
    Academic press:
    Dalton Transactions (), Wydawca: ROYAL SOC CHEMISTRY
    Status:
    Published
    DOI:
    10.1039/D3DT02255B - link to the publication
  12. Pd-PEPPSI N-Heterocyclic Carbene Complexes from Caffeine: Application in Suzuki, Heck, and Sonogashira Reactions
    Authors:
    Md. Mahbubur Rahman, Jin Zhang, Qun Zhao, Jessica Feliciano, Elwira Bisz, Błażej Dziuk, Roger Lalancette, Roman Szostak, Michal Szostak
    Academic press:
    Organometallics (), Wydawca: AMERICAN CHEMICAL SOCIETY
    Status:
    Published
    DOI:
    10.1021/acs.organomet.2c00262 - link to the publication

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