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Ambiphilic phosphorus compounds: synthesis, structure and application in activation of small molecules.

2019/35/N/ST4/03168

Keywords:

Lewis acids Lewis bases phosphorus activation of small molecules synthesis reactivity

Descriptors:

  • ST4_020:

Panel:

ST4 - Chemistry: physical chemistry/chemical physics, theoretical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, method development

Host institution :

Politechnika Gdańska

woj. pomorskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

Natalia Maria Szynkiewicz 

Number of co-investigators in the project: 2

Call: PRELUDIUM 18 - announced on 2019-09-16

Amount awarded: 139 200 PLN

Project start date (Y-m-d): 2020-06-25

Project end date (Y-m-d): 2022-06-24

Project duration:: 24 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Information in the final report

  • Publication in academic press/journals (4)
  1. Exploring the Reactivity of Unsymmetrical Diphosphanes toward Heterocumulenes: Access to Phosphanyl and Phosphoryl Derivatives of Amides, Imines, and Iminoamides
    Authors:
    Natalia Szynkiewicz, Jarosław Chojnacki, Rafał Grubba
    Academic press:
    Inorganic Chemistry (rok: 2022, tom: 61(25), strony: 9523–9532), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.2c00589 - link to the publication
  2. Exploring the reactivity of unsymmetrical diphosphanes towards heterocumulenes: access to phosphanyl and phosphoryl derivatives of amides, imines, and iminoamides
    Authors:
    Natalia Szynkiewicz, Jarosław Chojnacki, Rafał Grubba
    Academic press:
    Inorganic Chemistry (rok: 2022, ), Wydawca: American Chemical Society
    Status:
    Submitted
  3. Phosphinophosphoranes: Mixed-Valent Phosphorus Compounds with Ambiphilic Properties
    Authors:
    Natalia Szynkiewicz, Jarosław Chojnacki, Rafał Grubba
    Academic press:
    Inorganic Chemistry (rok: 2022, tom: 61(49), strony: 19925 - 19932), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.inorgchem.2c03166 - link to the publication
  4. Exploring the reactivity of unsymmetrical diphosphanes towards heterocumulenes: access to phosphanyl and phosphoryl derivatives of amides, imines, and iminoamides
    Authors:
    Natalia Szynkiewicz, Jarosław Chojnacki, Rafał Grubba
    Academic press:
    Inorganic Chemistry (rok: 2022, ), Wydawca: American Chemical Society
    Status:
    Submitted

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