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The phospho-Friedel-Crafts/Bradsher reaction - a new member of a heteroatom family.

2019/33/B/ST4/02843

Keywords:

aromatic electrophilic cyclization the Friedel-Crafts/Bradsher reaction acenes heteroacenes phosphines and their O,S,Se-derivatives phosphonates and their O,S-derivatives phosphonic acids phosphoranes phosphonic salts optical and thermal properties development of new synthetic methodologies

Descriptors:

  • ST4_008:

Panel:

ST4 - Chemistry: physical chemistry/chemical physics, theoretical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, method development

Host institution :

Centrum Badań Molekularnych i Makromolekularnych Polskiej Akademii Nauk

woj. łódzkie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Piotr Michał Bałczewski 

Number of co-investigators in the project: 6

Call: OPUS 17 - announced on 2019-03-15

Amount awarded: 1 584 700 PLN

Project start date (Y-m-d): 2020-02-28

Project end date (Y-m-d): 2025-08-27

Project duration:: 66 months (the same as in the proposal)

Project status: Project completed

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Information in the final report

  • Publication in academic press/journals (4)
  • Book publications / chapters in book publications (5)
  1. The First Example of the Friedel–Crafts Cyclization Leading to (10-Hydroxy-9,10- dihydroanthr-9-yl)phosphonium Salts without the Expected Bradsher Dehydration
    Authors:
    K. Owsianik, E. Różycka-Sokołowska, M. Koprowski, M. Turek, Ł. Knopik, V. Vivek, B. Dudziński, P. Bałczewski
    Academic press:
    International Journal of Molecular Sciences (rok: 2024, tom: 25, strony: 1741), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/ijms25031741 - link to the publication
  2. The hetero-Friedel-Crafts-Bradsher cyclizations with formation of ring carbon-heteroatom (P, S) bonds, leading to organic functional materials
    Authors:
    J. Skalik, M. Koprowski, E. Różycka-Sokołowska, P. Bałczewski
    Academic press:
    Materials (rok: 2020, tom: 13, strony: 4751), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/ma13214751 - link to the publication
  3. Comprehensive Review on Synthesis, Properties and Applications of Phosphorus (PIII, PIV, PV) Substituted Acenes with More than Two Fused Benzene Rings
    Authors:
    M. Koprowski, K. Owsianik, Ł. Knopik, V. Vivek, A. Romaniuk, E. Różycka-Sokołowska, P. Bałczewski
    Academic press:
    Molecules (rok: 2022, tom: 27, strony: 6611), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules27196611 - link to the publication
  4. Comprehensive Review of Synthesis, Optical Properties and Applications of Heteroarylphosphonates and Their Derivatives
    Authors:
    Krzysztof Owsianik, Adrian Romaniuk, Marika Turek, Piotr Bałczewski
    Academic press:
    Molecules (rok: 2024, tom: 29, strony: 3691), Wydawca: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules29153691 - link to the publication
  1. Quinquevalent phosphorus acids
    Authors:
    P. Bałczewski, K. Owsianik, M. Turek
    Book:
    Organophosphorus Chemistry; Editors: David W. Allen, David Loakes, Lee J. Higham, John C. Tebby (rok: 2022, tom: 51, strony: 181-327), Wydawca: The Royal Society of Chemistry Publishing
    Status:
    Published
    DOI:
    10.1039/9781839166198 - link to the publication
  2. Quinquevalent phosphorus acids
    Authors:
    P.Bałczewski, J.Wilk
    Book:
    Organophosphorus Chemistry; Editors: David W Allen, David Loakes, Lee J Higham, John C Tebby (rok: 2020, tom: 49, strony: 198-331), Wydawca: The Royal Society of Chemistry Publishing
    Status:
    Published
    DOI:
    10.1039/9781788019491 - link to the publication
  3. Quinquevalent phosphorus acids
    Authors:
    P.Bałczewski, J.Wilk
    Book:
    Organophosphorus Chemistry; Editors: David W Allen, David Loakes, Lee J Higham, John C Tebby (rok: 2020, tom: 49, strony: 198-331), Wydawca: The Royal Society of Chemistry Publishing
    Status:
    Published
    DOI:
    10.1039/9781788019491 - link to the publication
  4. Quinquevalent phosphorus acids
    Authors:
    P.Bałczewski, K.Owsianik
    Book:
    Organophosporus Chemistry (rok: 2021, tom: 50, strony: 271- 408), Wydawca: The Royal Society of Chemistry Publishing
    Status:
    Published
    DOI:
    10.1039/9781839163814-00271 - link to the publication
  5. Quinquevalent phosphorus acids
    Authors:
    P. Bałczewski, K. Owsianik
    Book:
    Organophosphorus Chemistry (rok: 2024, tom: 52, strony: 109-231), Wydawca: The Royal Society of Chemistry Publishing
    Status:
    Published
    DOI:
    10.1039/BK9781837672738-00109 - link to the publication