Making the Impossible Possible: Macrocyclisation of UnbiasedDienes at High Concentration by Ring-Closing Metathesis

2019/33/B/ST4/00874

Keywords

Descriptors

  • ST4_014: Kataliza
  • ST4_008: Chemia organiczna

Panel

ST4 – Chemistry: physical chemistry/chemical physics, theoretical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, method development

Host institution

Uniwersytet Warszawski, Centrum Nauk Biologiczno-Chemicznych

Voivodeship: mazowieckie

Other projects carried out by the institution »

Principal investigator (from the host institution)

prof. Karol Lesław Grela

Number of co-investigators in the project: 9

Call

OPUS 17 – announced on 2019-03-15

Amount awarded
1 896 500 PLN
Project start date
2020-02-27
Project end date
2023-10-26
Project duration
44 months (the same as in the proposal)
Project status
Project settled

Project description

Download the project description in a pdf file

Note — project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Information in the final report

Publication in academic press/journals (4)

  1. Unexpected Latency of Z-Stereoretentive Ruthenium Olefin Metathesis Catalysts Bearing Unsymmetrical N-heterocyclic Carbene or Cyclic(alkyl)(amino)carbene Ligands

    Authors:
    Łukasz Grzesiński, Mariusz Milewski, Maryana Nadirova, Anna Kajetanowicz, Karol Grela
    Academic press:
    Organometallics (year: 2022, volume: 42, pages: 2453–2459), Publisher: ACS Publications
    Status:
    Published
    DOI:
    10.1021/acs.organomet.2c00428 – link to the publication
  2. Preserving Precise Choreography of Bonds in Stereoretentive Olefin Metathesis: New Type of Ligand Allows High Z-Selectivity Even at High Temperature

    Authors:
    Łukasz Grzesiński, Mariana Nadirova, Jannick Guschlbauer, Artur Brotons Rufes, Albert Poater Teixidor, Anna Kajetanowicz, Karol Grela
    Academic press:
    Nature Communications (year: 2024, volume: 15, pages: 8981), Publisher: Springer Nature Group
    Status:
    Published
    DOI:
    10.1038/S41467-024-52876-4 – link to the publication
  3. Ruthenium Olefin Metathesis Catalysts Bearing Two Bulky and Unsymmetrical NHC Ligands

    Authors:
    Adrian Sytniczuk, Paweł Małecki, Anna Kajetanowicz, Karol Grela
    Academic press:
    Applied Organometallic Chemistry (year: 2024, volume: 38, pages: e6780), Publisher: Wiley
    Status:
    Published
    DOI:
    10.1002/aoc.6780 – link to the publication
  4. Schrock molybdenum alkylidene catalyst enables selective formation of macrocyclic unsaturated lactones by ring-closing metathesis at high-concentration

    Authors:
    Adrian Sytniczuk, Mariusz Milewski, Michał Dąbrowski, Karol Grela, Anna Kajetanowicz
    Academic press:
    Green Chemistry (year: 2023, volume: 25, pages: 2299–2304), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/D2GC02988J – link to the publication

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Graphic design and implementation: Jakub Piotrowski