Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

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Continuous flow hydrosilylation in SILP/scCO2 systems - an innovative approach to reduction and functionalization of alkynes, imines and carbonyl compounds

2018/31/G/ST4/04012

Keywords:

Catalysis Flow Chemistry Hydrosilylation Ionic Liquids Supercritical carbon dioxide Green Chemistry

Descriptors:

  • ST4_11: Coordination and supramolecular chemistry
  • ST4_12: Photochemistry
  • ST4_14: Catalysis

Panel:

ST4 - Chemistry: physical chemistry/chemical physics, theoretical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, method development

Host institution :

Uniwersytet im. Adama Mickiewicza w Poznaniu, Centrum Zaawansowanych Technologii

woj. wielkopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Jędrzej Walkowiak 

Number of co-investigators in the project: 8

Call: BEETHOVEN 3 - announced on 2018-09-14

Amount awarded: 1 749 000 PLN

Project start date (Y-m-d): 2020-08-31

Project end date (Y-m-d): 2025-02-27

Project duration:: 36 months (the same as in the proposal)

Project status: Pending project

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Information in the final report

  • Publication in academic press/journals (8)
  • Book publications / chapters in book publications (1)
  1. Synthesis of unsymmetrically and symmetrically functionalized disiloxanes via subsequent hydrosilylation of C≡C bonds
    Authors:
    Jakub Szyling, Jędrzej Walkowiak, Agnieszka Czapik, Adrian Franczyk
    Academic press:
    Scientific Reports (rok: 2023, tom: 13, strony: 10244), Wydawca: Springer Nature
    Status:
    Published
    DOI:
    10.1038/s41598-023-37375-8 - link to the publication
  2. Functionalization of octaspherosilicate (HSiMe2O)8Si8O12 with buta‐1,3‐diynes by hydrosilylation
    Authors:
    Kinga Stefanowska, Jakub Nagórny, Jakub Szyling, Adrian Franczyk
    Academic press:
    Scientific Reports (rok: 2023, tom: 13, strony: 14314), Wydawca: Springer Nature
    Status:
    Published
    DOI:
    10.1038/s41598-023-41461-2 - link to the publication
  3. Synthesis of bifunctional disiloxanes via subsequent hydrosilylation of alkenes and alkynes
    Authors:
    Jalub Szyling, Rafał Januszewski, Kamila Jankowska, Jędrzej Walkowiak, Ireneusz Kownacki, Adrian Franczyk
    Academic press:
    Chemical Communications (rok: 2021, tom: 57, strony: 4504-4507), Wydawca: Royal Chemical Society
    Status:
    Published
    DOI:
    10.1039/d1cc01253c - link to the publication
  4. Hydrosilylation of Carbonyl Compounds Catalyzed by Iridium(I) Complexes with (-)-Menthol-Based Phosphorus(III) Ligands
    Authors:
    Konrad Stęsik, Adrian Franczyk, Agnieszka Czapik, Ireneusz Kownacki, Jędrzej Walkowiak
    Academic press:
    ChemCatChem (rok: 2023, tom: 15, strony: e202201510), Wydawca: Wiley-VCH GmbH, Weinheim
    Status:
    Published
    DOI:
    10.1002/cctc.202201510 - link to the publication
  5. Directed cis-hydrosilylation of borylalkynes to borylsilylalkenes
    Authors:
    Kinga Stefanowska, Tomasz Sokolnicki, Jędrzej Walkowiak, Agnieszka Czapik, Adrian Franczyk
    Academic press:
    Chemical Communications (rok: 2022, tom: 58, strony: 12046-12049), Wydawca: Royal Chemical Society
    Status:
    Published
    DOI:
    10.1039/D2CC04318A - link to the publication
  6. Synthesis of Bio-Based Silane Coupling Agents by the Modification of Eugenol
    Authors:
    Tomasz Sokolnicki, Adrian Franczyk, Bartłomiej Janowski, Jędrzej Walkowiak
    Academic press:
    Advanced Synthesis and Catalysis (rok: 2021, tom: 363, strony: 5493-5500), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/adsc.202101178 - link to the publication
  7. Coupling agents with 2,4,6,8-tetramethylcyclotetrasiloxane core – synthesis and application in styrene–butadiene rubber production
    Authors:
    Tomasz Sokolnicki, Adrian Franczyk, Radosław Kozak, Jędrzej Walkowiak
    Academic press:
    Inorganic Chemistry Frontiers (rok: 2023, tom: 10, strony: 5897-5907), Wydawca: Royal Chemical Society
    Status:
    Published
    DOI:
    10.1039/D3QI00619K - link to the publication
  8. Hydroelementation of diynes
    Authors:
    Jedrzej Walkowiak, Jakub Szyling, Adrian Franczyk, Rebecca Melen
    Academic press:
    Chemical Society Reviews (rok: 2022, tom: 51, strony: 869-994), Wydawca: Royal Chemical Society
    Status:
    Published
    DOI:
    10.1039/D1CS00485A - link to the publication
  1. Hydrometallation of conjugated 1,3-diynes
    Authors:
    Jędrzej Walkowiak, Adrian Franczyk, Jakub Szyling, Kinga Stefanowska
    Book:
    Encyclopedia of Inorganic and Bioinorganic Chemistry (rok: 2023, tom: -, strony: -), Wydawca: John Wiley & Sons, Ltd.
    Status:
    Published

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