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Synthesis and physicochemical properties of novel functional metal-organic compounds based on hypophosphite ligands

2018/31/B/ST5/00455

Keywords

Descriptors

  • ST5_8: Nowe materiały: tlenki, stopy, kompozyty, hybrydy organiczno-nieorganiczne, nadprzewodniki
  • ST4_3: Metody spektroskopowe i spektrometryczne
  • ST3_18: Przejścia fazowe, równowaga faz

Panel

ST5 – Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution

Instytut Niskich Temperatur i Badań Strukturalnych im. Włodzimierza Trzebiatowskiego PAN

Voivodeship: dolnośląskie

Other projects carried out by the institution »

Principal investigator (from the host institution)

prof. Mirosław Robert Mączka

Number of co-investigators in the project: 6

Call

OPUS 16 – announced on 2018-09-14

Amount awarded
860 000 PLN
Project start date
2019-06-13
Project end date
2022-12-12
Project duration
42 months (the same as in the proposal)
Project status
Project settled

Project description

Download the project description in a pdf file

Note — project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Analizator elementarny CHN/O FlashSmart. Cost: 260 000 PLN
  2. Dygestorium. Cost: 17 800 PLN
  3. Kompresor tłokowy bezolejowy ES480/100 (11000 pcs). Cost: 11 000 PLN
  4. Optyczne DSC450. Cost: 105 000 PLN
  5. Wertykalna przystawka temperaturowa FTIRSP600. Cost: 42 000 PLN
  6. dygestorium. Cost: 14 139 PLN
  7. komputer dell. Cost: 1 300 PLN

Information in the final report

Publication in academic press/journals (9)

  1. Cadmium and manganese hypophosphite perovskites templated by formamidinium cations: dielectric, optical and magnetic properties

    Authors:
    Mirosław Mączka, Dagmara Stefańska, Maciej Ptak, Anna Gągor, Adam Piku, Adam Sieradzki
    Academic press:
    Dalton Transactions (year: 2021, volume: 50, pages: 2639-2647), Publisher: Royal Chemical Society
    Status:
    Published
    DOI:
    10.1039/d0dt03995k – link to the publication

  2. Evidence of Pressure-Induced Phase Transitions and Negative Linear Compressibility in Formamidinium Manganese-Hypophosphite Hybrid Perovskite

    Authors:
    Mirosław Ma̧czka, Mikołaj Kryś, Szymon Sobczak, Daniel Linhares Militão Vasconcelos, Paulo Tarso Cavalcante Freire, Andrzej Katrusiak
    Academic press:
    Journal of Physical Chemistry C (year: 2021, volume: 125, pages: 26958-26966), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpcc.1c08387 – link to the publication

  3. Structural, magnetic and photoluminescence properties of new hybrid hypophosphites: discovery of the first noncentrosymmetric and two cobalt-based members

    Authors:
    Mirosław Mączka, Anna Gągor, Dagmara Stefańska, Jan K. Zaręba, Adam Pikul
    Academic press:
    Dalton Transactions (year: 2022, volume: 51, pages: 9094-9102), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d2dt01212j – link to the publication

  4. Phonon properties and mechanism of order-disorder phase transition in formamidinium manganese hypophosphite single crystal

    Authors:
    Maciej Ptak, Mirosław Mączka
    Academic press:
    Spectrochimica Acta A (year: 2020, volume: 230, pages: 118010), Publisher: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.saa.2019.118010 – link to the publication

  5. Effect of Organic Cation on Optical Properties of [A]Mn(H2POO)3 Hybrid Perovskites

    Authors:
    Dagmara Stefańska
    Academic press:
    Molecules (year: 2022, volume: 27, pages: 8953), Publisher: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules27248953 – link to the publication

  6. The cation-dependent structural, magnetic and optical properties of a family of hypophosphite hybrid perovskites

    Authors:
    Mirosław Mączka, Dagmara Stefańska, Anna Gągor, Adam Pikul
    Academic press:
    Dalton Transactions (year: 2022, volume: 51, pages: 352-360), Publisher: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d1dt03382d – link to the publication

  7. Vibrational Properties and DFT Calculations of Perovskite-Type Methylhydrazinium Manganese Hypophosphite

    Authors:
    Aneta Ciupa-Litwa, Maciej Ptak, Edyta Kucharska, Jerzy Hanuza, Mirosław Mączka
    Academic press:
    Molecules (year: 2020, volume: 25, pages: 5215), Publisher: MDPI
    Status:
    Published
    DOI:
    10.3390/molecules25215215 – link to the publication

  8. Novel hypophosphite hybrid perovskites of [CH3NH2NH2][Mn(H2POO)3] and [CH3NH2NH2] [Mn(H2POO)2.83(HCOO)0.17] exhibiting antiferromagnetic order and red photoluminescence

    Authors:
    Mirosław Mączka, Anna Gągor, Adam Pikul, Dagmara Stefańska
    Academic press:
    RSC Advances (year: 2020, volume: 10, pages: 19020-19026), Publisher: Royal Chemical Society
    Status:
    Published
    DOI:
    10.1039/d0ra03397a – link to the publication

  9. Mechanism of Pressure-Induced Phase Transitions and Structure− Property Relations in Methylhydrazinium Manganese Hypophosphite Perovskites

    Authors:
    Mirosław Mączka, Szymon Sobczak, Mikołaj Kryś, Fabio Furtado Leite, Waldeci Paraguassu, Andrzej Katrusiak
    Academic press:
    Journal of Physical Chemistry C (year: 2021, volume: 125, pages: 10121-10129), Publisher: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpcc.1c01998 – link to the publication

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Graphic design and implementation: Jakub Piotrowski