Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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The application of cobalt pincer complexes in the synthesis of organometalloidal compounds

2018/30/E/ST5/00045

Keywords:

homogeneous catalysis organometallic compounds cobalt complexes coupling reaction addition reaction

Descriptors:

  • ST5_14: Other related subjects
  • ST5_18:
  • ST5_24:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet im. Adama Mickiewicza w Poznaniu, Wydział Chemii

woj. wielkopolskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr hab. Grzegorz Hreczycho 

Number of co-investigators in the project: 10

Call: SONATA BIS 8 - announced on 2018-06-15

Amount awarded: 2 258 920 PLN

Project start date (Y-m-d): 2019-03-29

Project end date (Y-m-d): 2025-03-28

Project duration:: 60 months (the same as in the proposal)

Project status: Pending project

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Information in the final report

  • Publication in academic press/journals (19)
  • Articles in post-conference publications (1)
  1. Potassium Fluoride-Catalyzed Hydroboration of Aldehydes and Ketones: Facile Reduction to Primary and Secondary Alcohols
    Authors:
    Krzysztof Kuciński, Grzegorz Hreczycho
    Academic press:
    European Journal of Organic Chemistry (rok: 2020, tom: 2020(5), strony: 552-555), Wydawca: ChemPubSoc
    Status:
    Published
    DOI:
    10.1002/ejoc.201901514 - link to the publication
  2. Silylation of Silanols with Hydrosilanes via Main-Group Catalysis: The Synthesis of Unsymmetrical Siloxanes and Hydrosiloxanes
    Authors:
    Krzysztof Kuciński, Hanna Stachowiak, Grzegorz Hreczycho
    Academic press:
    Inorganic Chemistry Frontiers (rok: 2020, tom: 7, strony: 4190-4196), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d0qi00904k - link to the publication
  3. A review of the R3Si–NH–SiR3–type disilazanes: From synthesis to applications
    Authors:
    Krzysztof Kuciński, Hanna Stachowiak, dariusz lewandowski, Marcin Gruszczyński, Paulina Lampasiak, Grzegorz Hreczycho
    Academic press:
    Journal of Organometallic Chemistry (rok: 2022, tom: 961, strony: 122127), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jorganchem.2021.122127 - link to the publication
  4. Cobalt-Catalyzed Dehydrogenative C H Silylation of Alkynylsilane
    Authors:
    Hanna Stachowiak, Krzysztof Kucińśki, Fabian Kallmeier, Rhett Kempe, Grzegorz Hreczycho
    Academic press:
    Chemistry - A European Journal (rok: 2022, tom: 28, strony: e2021036 (1-6)), Wydawca: Wiley VCH
    Status:
    Published
    DOI:
    10.1002/chem.2021 - link to the publication
  5. Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species
    Authors:
    Hanna Stachowiak-Dłużyńska, Krzysztof Kuciński, Konstancja Broniarz, Ewelina Szafoni, Marcin Gruszczyński, Giuseppe Consiglio, G. Hreczycho
    Academic press:
    Scientific Reports (rok: 2023, tom: 13, strony: 5618), Wydawca: Springer Nature
    Status:
    Published
    DOI:
    10.1038/s41598-023-32172-9 - link to the publication
  6. Catalytic silylation of O–nucleophiles via Si–H or Si–C bond cleavage: A route to silyl ethers, silanols and siloxanes
    Authors:
    Krzysztof Kuciński, Hanna Stachowiak-Dłużyńska, Grzegorz Hreczycho
    Academic press:
    Coordination Chemistry Reviews (rok: 2022, tom: 459, strony: 214456), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.ccr.2022.214456 - link to the publication
  7. Co-catalyzed Selective syn-Hydrosilylation of Internal Alkynes
    Authors:
    Hanna Stachowiak-Dluzyńska, Krzysztof Kuciński, Bożena Wyrzykiewicz, Rhett Kempe, Grzegorz Hreczycho
    Academic press:
    ChemCatChem (rok: 2023, tom: 15, strony: e202300592), Wydawca: European Chemical Societies Publishing
    Status:
    Published
    DOI:
    10.1002/cctc.202300592 - link to the publication
  8. Co-catalyzed hydrosilylation of ketones under base-free conditions: a convenient route to silyl ethers or secondary alcohols
    Authors:
    Hanna Stachowiak-Dłużyńska, Grzegorz Hreczycho
    Academic press:
    ChemCatChem (rok: 2023, tom: 15, strony: e202300781), Wydawca: European Chemical Societies Publishing
    Status:
    Published
    DOI:
    10.1002/cctc.202300781 - link to the publication
  9. Cobalt-catalyzed synthesis of silyl ethers via crossdehydrogenative coupling between alcohols and hydrosilanes
    Authors:
    Ewelina Szafoni, Krzysztof Kuciński, Grzegorz Hreczycho
    Academic press:
    Green Chemistry Letters and Reviews (rok: 2022, tom: 0,627083333333333, strony: 757-764), Wydawca: Taylor & Francis
    Status:
    Published
    DOI:
    10.1080/17518253.2022.2133554 - link to the publication
  10. Hydrosilylation and hydroboration in a sustainable manner: from Earth-abundant catalysts to catalyst-free solutions
    Authors:
    Krzysztof Kuciński
    Academic press:
    Green Chemistry (rok: 2020, tom: 22, strony: 5210-5224), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d0gc01430c - link to the publication
  11. Catalytic and non-catalytic hydroboration of carbonyls: quantum-chemical studies
    Authors:
    Mateusz Nowicki, Krzysztof Kuciński, Grzegorz Hreczycho, Marcin Hoffmann
    Academic press:
    Organic and Biomolecular Chemistry (rok: 2021, tom: 19, strony: 3004-3015), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/d1ob00037c - link to the publication
  12. Cobalt-Catalyzed Dehydrogenative Cross-Coupling Reaction: Selective Access to Dihydrosiloxanes, Hydrosiloxanes and Functionalized Silsesquioxanes
    Authors:
    Ewelina Szafoni, Krzysztof Kuciński, Grzegorz Hreczycho
    Academic press:
    Journal of Catalysis (rok: 2023, tom: 423, strony: 45300), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jcat.2023.04.013 - link to the publication
  13. Ligand-controlled Cobalt-Catalyzed formation of Carbon–Boron bonds: Hydroboration vs CAH/B–H dehydrocoupling
    Authors:
    Dariusz Lewandowski, Tomasz Cytlak, Rhett Kempe, Grzegorz Hreczycho
    Academic press:
    Journal of Catalysis (rok: 2022, tom: 413, strony: 728-734), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.jcat.2022.07.037 - link to the publication
  14. Ru-catalyzed Formation of Thiosilanes and Selenosilanes using Dichalcogenides as a User-Friendly Alternative to Thiols and Selenols
    Authors:
    Krzysztof Kuciński, Marcin Gruszczyński, Grzegorz Hreczycho
    Academic press:
    ChemCatChem (rok: 2022, tom: 14(19), strony: e202200961 (1-6)), Wydawca: Wiley-VCH
    Status:
    Published
    DOI:
    10.1002/cctc.202200961 - link to the publication
  15. Silicon–nitrogen bond formation via dealkynative coupling of amines with bis(trimethylsilyl)acetylene mediated by KHMDS
    Authors:
    Krzysztof Kuciński, Grzegorz Hreczycho
    Academic press:
    Chemical Communications (rok: 2022, tom: 58(81), strony: 11386–11389), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/d2cc04413g - link to the publication
  16. Silylation of Alcohols, Phenols, and Silanols with Alkynylsilanes – an Efficient Route to Silyl Ethers and Unsymmetrical Siloxanes
    Authors:
    Krzysztof Kuciński, Hanna Stachowiak, Grzegorz Hreczycho
    Academic press:
    European Journal of Organic Chemistry (rok: 2020, tom: 2020 (26), strony: 4042-4049), Wydawca: Wiley
    Status:
    Published
    DOI:
    10.1002/ejoc.202000573. - link to the publication
  17. Access to Unsaturated Organogermanes via (De)hydrosilylation Mediated by Cobalt Complexes
    Authors:
    Konstancja Broniarz, Grzegorz Hreczycho
    Academic press:
    Organic Letters (rok: 2023, tom: 25, strony: 6528-6533), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.orglett.3c02326 - link to the publication
  18. Cobalt pincer-type complexes demonstrating unique selectivity for hydroboration reaction of olefin under mild conditions
    Authors:
    Dariusz Lewandowski, Grzegorz Hreczycho
    Academic press:
    Inorganic Chemistry Frontiers (rok: 2023, tom: 10, strony: 3656-3663), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/D3QI00478C - link to the publication
  19. TransitionMetal-FreeCatalyticCH Silylationof TerminalAlkyneswith bis(Trimethylsilyl)acetyleneInitiatedbyKHMDS
    Authors:
    Krzysztof Kuciński, Grzegorz Hreczycho
    Academic press:
    ChemCatChem (rok: 2022, tom: 14(18), strony: e202200794(1-6)), Wydawca: Wiley0VCH
    Status:
    Published
    DOI:
    10.1002/cctc.202200794 - link to the publication
  1. Green chemistry for organosilicon and organoboron synthesis
    Authors:
    Krzysztof Kuciński, Grzegorz Hreczycho
    Conference:
    The 18th Asian Chemical Congress (18th ACC) and the 20th General Assembly of the Federation of Asian Chemical Societies (FACS) (rok: 2019, ), Wydawca: National Tsing Hua University, Taiwan
    Data:
    konferencja 2019-12-08-12
    Status:
    Published

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