Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

Equipment

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Monomeric and oligomeric porphyrinoids with several redox centers: synthesis and characterization of highly charged organic systems with high spin-multiplicity

2018/29/B/ST5/00280

Keywords:

porphyrinoids oligomers radicals diradicals metal complexes aromaticity

Descriptors:

  • ST5_14: Other related subjects
  • ST5_23:

Panel:

ST5 - Materials: materials synthesis, structure-properties relations, advanced and functional materials with designed properties, (macro)molecular architecture, material engineering

Host institution :

Uniwersytet Wrocławski, Wydział Chemii

woj. dolnośląskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

prof. Piotr Chmielewski 

Number of co-investigators in the project: 6

Call: OPUS 15 - announced on 2018-03-15

Amount awarded: 1 635 600 PLN

Project start date (Y-m-d): 2019-01-24

Project end date (Y-m-d): 2023-01-23

Project duration:: 48 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Chromatograf cieczowy typu flash z możliwością przełączania na preparatywny HPLC (210 000 PLN)
  2. Oprogramowanie: EndNote9 (1 800 PLN)
  3. Oprogramowanie MESTReNOVA (19 347 PLN)
  4. Pompa próżniowa membranowa z regulatorem próżni (10 000 PLN)
  5. Cyrkulator termostatujący z chłodziarką (15 000 PLN)
  6. Mieszadło magnetyczne z termostatem i kontrolerem temperatury (5 000 PLN)
  7. Oprogramowanie: OriginPro2018 (3 400 PLN)
  8. Wyparka próżniowa (10 000 PLN)
  9. Zestaw wyparny wraz z chłodnicą do membranowych pomp próżniowych, w skład którego wchodzą dwa urządzenia z wykazu planowanej aparatury: pompa próżniowa i wyparka próżniowa..

Information in the final report

  • Publication in academic press/journals (7)
  • Book publications / chapters in book publications (1)
  1. 1,3-Dipolar cycloaddition of polycyclic azomethine ylide tonorcorroles: towards dibenzoullazine-fused derivatives
    Authors:
    S. Li, Y. Sun, X. Li, O. Smaga, S. Koniarz, M. Stępień, P. J. Chmielewski
    Academic press:
    Chemical Communications (rok: 2022, tom: 58, strony: 6510-6513), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/D2CC02071H - link to the publication
  2. Oxidative insertion of amines into conjugated macrocycles: transformation of antiaromatic norcorrole into aromatic azacorrole
    Authors:
    S. Li, Y. Sun, X. Li, O. Smaga, S.Koniarz, M. Pawlicki, P. J. Chmielewski
    Academic press:
    Chemical Communications (rok: 2023, tom: 59, strony: 45295), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/d2cc06648c - link to the publication
  3. First imidazole-fused carbaporphyrinoid and its conversion to N heterocyclic carbene precursor
    Authors:
    Demin Ren Sebastian Koniarz, Xiaofang Li, Piotr J. Chmielewski
    Academic press:
    Chemical Communication (rok: 2020, tom: 56, strony: 4856-4839), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/D0CC01013H - link to the publication
  4. Friedel-Crafts acylation of antiaromatic norcorrole: electronic and steric modulation of the paratropic current
    Authors:
    S. Li, O. Smaga, Y. Sun, X. Li, M. Pawlicki, M. Sukniewicz, P. J. Chmielewski
    Academic press:
    Organic Chemistry Frontiers (rok: 2021, tom: 8, strony: 3639-3652), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/D1QO00621E - link to the publication
  5. From Antiaromatic Norcorrolatonickel(II) to Aromatic and Nonaromatic Zwitterions: Innocent Ligands with Unbalanced Charge of the Core
    Authors:
    D. Ren, O. Smaga, X. Fu, X. Li, M. Pawlicki, S. Koniarz, and P. J. Chmielewski
    Academic press:
    Organic Letters (rok: 2021, tom: 23, strony: 1032-1037), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.orglett.0c04227 - link to the publication
  6. Reactions of 2-Aza-21-carbaporphyrin with Aniline Derivatives
    Authors:
    D. Ren, B. Liu, X. Li, S. Koniarz, M. Pawlicki and P. J. Chmielewski
    Academic press:
    Organic Chemistry Frontiers (rok: 2019, tom: 6, strony: 908-918), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/C9QO00024K - link to the publication
  7. Reaction of Antiaromatic Porphyrinoid with Active Methylene Compounds
    Authors:
    D. Ren, X. Fu, X. Li, S. Koniarz, P. J. Chmielewski
    Academic press:
    Organic Chemistry Frontiers (rok: 2019, tom: 6, strony: 2924-2933), Wydawca: RSC
    Status:
    Published
    DOI:
    10.1039/ - link to the publication
  1. 2-Aza-21-carbaporphyrin in Construction of Chiral Supramolecular Assemblies
    Authors:
    Sebastian Koniarz, Piotr J. Chmielewski
    Book:
    Chiral Building Blocks in Asymmetric Synthesis. Synthesis and Application (rok: 2022, tom: Chapter 18, strony: 583-621), Wydawca: Wiley-VCH
    Status:
    Published

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