Projects funded by the NCN

Information on the principal investigator and host institution

Information of the project and the call

Keywords

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Nano-confinement in one and two dimensions and its impact on the molecular dynamics and crystallization behavior of glass-forming materials

2017/27/B/ST3/00402

Keywords:

glass transition crystallization molecular dynamics glass-forming materials geometrical confinement in one and two dimensions nanoporous materials thin films dielectric spectroscopy

Descriptors:

  • ST3_15: Statistical physics of condensed matter, phase transitions, noise and fluctuations, etc.
  • ST4_1: Physical chemistry, chemical physics
  • ST5_4: Thin films

Panel:

ST3 - Condensed matter physics: structure, electronic properties, fluids, nanosciences, biological physics

Host institution :

Uniwersytet Śląski w Katowicach, Wydział Nauk Ścisłych i Technicznych

woj. śląskie

Other projects carried out by the institution 

Principal investigator (from the host institution):

dr Karolina Adrjanowicz 

Number of co-investigators in the project: 5

Call: OPUS 14 - announced on 2017-09-15

Amount awarded: 1 297 320 PLN

Project start date (Y-m-d): 2018-10-01

Project end date (Y-m-d): 2022-06-30

Project duration:: 45 months (the same as in the proposal)

Project status: Project settled

Project description

Download the project description in a pdf file

Note - project descriptions were prepared by the authors of the applications themselves and placed in the system in an unchanged form.

Equipment purchased [PL]

  1. Myjka ultradźwiękowa.
  2. Powlekacz obrotowy.
  3. System do osadzania próżniowego cienkich warstw metali i materiałów organicznych (320 000 PLN)
  4. Cieplarka labolatoryjna (4 197 PLN)
  5. Zestaw próżniowy do napełniania membran nanoporowatych (55 000 PLN)

Information in the final report

  • Publication in academic press/journals (15)
  1. Effect of Surface Chemistry on the Glass-Transition Dynamics of Poly(phenyl methyl siloxane) Confined in Alumina Nanopores
    Authors:
    Roksana Winkler, Wenkang Tu, Lukasz Laskowski, Karolina Adrjanowicz
    Academic press:
    Langmuir (rok: 2020, tom: 36, strony: 7553−7565), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.langmuir.0c01194 - link to the publication
  2. On the Segmental Dynamics and the Glass Transition Behavior of Poly(2-vinylpyridine) in One- and Two-Dimensional Nanometric Confinement
    Authors:
    Roksana Winkler, Aparna Beena Unni, Wenkang Tu, Katarzyna Chat, Karolina Adrjanowicz
    Academic press:
    J. Phys. Chem. B (rok: 2021, tom: 125, strony: 5991−6003), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.jpcb.1c01245 - link to the publication
  3. Study of Increasing Pressure and Nanopore Confinement Effect on the Segmental, Chain, and Secondary Dynamics of Poly(methylphenylsiloxane)
    Authors:
    K. Adrjanowicz, R. Winkler, K. Chat, D. M. Duarte, W. Tu, A. B. Unni, M. Paluch, K. L. Ngai
    Academic press:
    Maromolecules (rok: 2019, tom: 52, strony: 3763-3774), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.macromol.9b00473 - link to the publication
  4. Testing density scaling in nanopore-confinement for hydrogen-bonded liquid dipropylene glycol
    Authors:
    Katarzyna Chat, Grzegorz Szklarz, Karolina Adrjanowicz
    Academic press:
    RSC Advances (rok: 2109, tom: 9, strony: 20954), Wydawca: Royal Society of Chemistry
    Status:
    Published
    DOI:
    10.1039/C9RA02289A - link to the publication
  5. Discharge of the Nanopore Confinement Effect on the Glass Transition Dynamics via Viscous Flow
    Authors:
    Karolina Adrjanowicz, Marian Paluch
    Academic press:
    Physical Review Letters (rok: 2019, tom: 122, strony: 176101), Wydawca: American Physical Society
    Status:
    Published
    DOI:
    10.1103/PhysRevLett.122.176101 - link to the publication
  6. Experimental evidence on the effect of substrate roughness on segmental dynamics of confined polymer films
    Authors:
    Aparna Beena Unni, Katarzyna Chat, Daniel Marques Duarte, Marcin Wojtyniak, Monika Geppert-Rybczynska, Jerzy Kubacki, Roman Wrzalik, Ranko Richert, Karolina Adrjanowicz
    Academic press:
    Polymer (rok: 2020, tom: 199 (122501), strony: 7), Wydawca: Elsevier Ltd
    Status:
    Published
    DOI:
    10.1016/j.polymer.2020.122501 - link to the publication
  7. Glass Transition Dynamics of Poly(phenylmethylsiloxane) Confined within Alumina Nanopores with Different Atomic Layer Deposition (ALD) Coatings
    Authors:
    Roksana Winkler, Katarzyna Chat, Aparna Beena Unni, Mateusz Dulski, Magdalena Laskowska, Lukasz Laskowski, Karolina Adrjanowicz
    Academic press:
    Macromolecules (rok: 2022, tom: 55(8), strony: 3208-3220), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.macromol.2c00311 - link to the publication
  8. Connecting 1D and 2D Confined Polymer Dynamics to Its Bulk Behavior via Density Scaling
    Authors:
    Karolina Adrjanowicz, Roksana Winkler,Andrzej Dzienia,Marian Paluch, Simone Napolitano
    Academic press:
    ACS Macro Lett. (rok: 2019, tom: 8, strony: 304−309), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acsmacrolett.8b01006 - link to the publication
  9. Connecting the density distribution and segmental dynamics of confined polymer films
    Authors:
    Aparna Beena Unni, Katarzyna Chat, Katarzyna Balin, Karolina Adrjanowicz
    Academic press:
    Nano-Structures & Nano-Objects (rok: 2020, tom: 23 (100519), strony: 6), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.nanoso.2020.100519 - link to the publication
  10. Effect of the Surface Polarity, Through Employing Nonpolar Spacer Groups, on the Glass-Transition Dynamics of Poly(phenyl methylsiloxane) Confined in Alumina Nanopores
    Authors:
    Roksana Winkler, Wenkang Tu, Mateusz Dulski, Lukasz Laskowski, Karolina Adrjanowicz
    Academic press:
    Macromolecules (rok: 2021, tom: 54, strony: 10951−10968), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.macromol.1c02145 - link to the publication
  11. Study on the glass transition dynamics and crystallization kinetics of molecular liquid, dimethyl phthalate, confined in Anodized Aluminum Oxide (AAO) nanopores with Atomic Layer Deposition (ALD) coatings
    Authors:
    Katarzyna Chat, Wenkang Tu, Aparna Beena Unni, Monika Geppert-Rybczyńska, Karolina Adrjanowicz
    Academic press:
    Journal of Molecular Liquids (rok: 2020, tom: 311 (113296), strony: 11), Wydawca: Elsevier
    Status:
    Published
    DOI:
    10.1016/j.molliq.2020.113296 - link to the publication
  12. Vapor-Deposited Thin Films: Studying Crystallization and α-relaxation Dynamics of the Molecular Drug Celecoxib
    Authors:
    Unni Aparna Beena, Winkler Roksana, Marques Duarte Daniel, Tu Wenkang, Chat Katarzyna, Adrjanowicz Karolina
    Academic press:
    The Journal of Physical Chemistry B (rok: 2022, tom: 126 (20), strony: 3789–3798), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.jpcb.2c01284 - link to the publication
  13. Effect of Surface Modification on the Glass Transition Dynamics of Highly Polar Molecular Liquid S-Methoxy-PC Confined in Anodic Aluminum Oxide Nanopores
    Authors:
    Katarzyna Chat, Wenkang Tu, Lukasz Laskowski, Karolina Adrjanowicz
    Academic press:
    J. Phys. Chem. C (rok: 2019, tom: 123 (21), strony: 13365-13376), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpcc.9b02059 - link to the publication
  14. Influence of Tacticity on the Glass-Transition Dynamics of Poly(methyl methacrylate) (PMMA) under Elevated Pressure and Geometrical Nanoconfinement
    Authors:
    Katarzyna Chat, Wenkang Tu, Aparna Beena Unni, Karolina Adrjanowicz
    Academic press:
    Macromolecules (rok: 2021, tom: 54, strony: 8526−8537), Wydawca: ACS
    Status:
    Published
    DOI:
    10.1021/acs.macromol.1c01341 - link to the publication
  15. The Impact of the Molecular Weight on the Nonequilibrium Glass Transition Dynamics of Poly(Phenylmethyl Siloxane) in Cylindrical Nanopores
    Authors:
    Katarzyna Chat, Karolina Adrjanowicz
    Academic press:
    J. Phys. Chem. C (rok: 2020, tom: 124, strony: 22321−22330), Wydawca: American Chemical Society
    Status:
    Published
    DOI:
    10.1021/acs.jpcc.0c07053 - link to the publication

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